UV-Light-Driven Photocatalytic Dye Degradation and Antibacterial Potentials of Biosynthesized SiO2 Nanoparticles

The present work shows the obtainment of biosynthesized SiO2 with the aid of Jasminum grandiflorum plant extract and the study of its photocatalytic ability in dye degradation and antibacterial activity. The obtained biosynthesized SiO2 nanoparticles were characterized using X-ray diffractometer ana...

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Detalles Bibliográficos
Autores: Chelliah, Parvathiraja, Gupta, Jeetendra Kumar, Mohammad Wabaidur, Saikh, Siddiqui, Masoom Raza, Lee, Siaw Foon, Lai, Wen-Cheng
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2023
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/334432
Acceso en línea:http://hdl.handle.net/10261/334432
Access Level:acceso abierto
Palabra clave:SiO2 nanoparticles
Silicon
Green synthesis
Photocatalysis
Jasminum grandiflorum
Descripción
Sumario:The present work shows the obtainment of biosynthesized SiO2 with the aid of Jasminum grandiflorum plant extract and the study of its photocatalytic ability in dye degradation and antibacterial activity. The obtained biosynthesized SiO2 nanoparticles were characterized using X-ray diffractometer analysis, Fourier transform infrared spectroscopy analysis, ultraviolet–visible diffuse reflectance spectroscopy, field-emission scanning electron microscope with energy-dispersive X-ray analysis, transmission electron microscopy and X-ray photoelectron spectroscopy. The UV-light irradiated photocatalytic activity of the biosynthesized SiO2 nanoparticles was examined using methylene blue dye solution. Its reusability efficiency was determined over 20 cycles and compared with the commercial P-25 titanium dioxide. The bacterial resistivity of the biosynthesized SiO2 nanoparticles was examined using S. aureus and E. coli. The biosynthesized SiO2 nanoparticles showed a high level of crystallinity with no impurities, and they had an optimum crystallite size of 23 nm, a bandgap of 4 eV, no Si-OH groups and quasi-spherical shapes with Si-2p at 104 eV and O-1s at 533 eV. Their photocatalytic activity on methylene blue dye solution could reach 90% degradation after 40 min of UV light exposure, and their reusability efficiency was only 4% less than that of commercial P-25 titanium dioxide. At the concentration of 100 μg/mL, the biosynthesized SiO2 nanoparticles could allow the resistivity of E. coli to become borderline to the resistant range of an antibiotic called Amikacin.