Recent progress in the application of Ni-based catalysts for the dry reforming of methane
Ni-based catalysts are highly efficient in methane-reforming processes. In the particular case of methane reforming in the presence of carbon dioxide, or dry reforming of methane (DRM), it is necessary to modify and control the initial properties of the catalyst to confer on it resistance to carbon...
| Autores: | , , |
|---|---|
| Tipo de recurso: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2021 |
| País: | España |
| Institución: | Universidad Pública de Navarra |
| Repositorio: | Academica-e. Repositorio Institucional de la Universidad Pública de Navarra |
| OAI Identifier: | oai:academica-e.unavarra.es:2454/42906 |
| Acceso en línea: | https://hdl.handle.net/2454/42906 |
| Access Level: | acceso abierto |
| Palabra clave: | Bimetallic catalyst Catalytic promoter CH4 valorization CO2 utilization Greenhouse gases Heterogeneous catalysts Ni-based catalyst Noble metal catalyst |
| id |
ES_cf340cf383eaefae1e1f846cd66d2fdb |
|---|---|
| oai_identifier_str |
oai:academica-e.unavarra.es:2454/42906 |
| network_acronym_str |
ES |
| network_name_str |
España |
| repository_id_str |
|
| spelling |
Recent progress in the application of Ni-based catalysts for the dry reforming of methaneTorrez Herrera, Jonathan JosuéKorili, Sophia A.Gil Bravo, AntonioBimetallic catalystCatalytic promoterCH4 valorizationCO2 utilizationGreenhouse gasesHeterogeneous catalystsNi-based catalystNoble metal catalystNi-based catalysts are highly efficient in methane-reforming processes. In the particular case of methane reforming in the presence of carbon dioxide, or dry reforming of methane (DRM), it is necessary to modify and control the initial properties of the catalyst to confer on it resistance to carbon deposition in particular, and to sintering of the Ni metal particles. In this regard, catalytic supports and promoters of different natures have been proposed. Likewise, the addition of small amounts of noble metals to avoid oxidation of the Ni active phase during the reforming reaction has been proposed. Catalyst preparation methods have also been identified as being of particular interest, since they can affect the structure of the Ni metal particles. In this review, the thermodynamic and kinetic aspects of the dry reforming of methane reaction are presented first. The most recent developments in synthetic methods (impregnation, sol-gel, co-precipitation, equilibrium deposition filtration, atomic layer deposition, non-thermal glow discharge plasma, multi-bubble sonoluminescence, 'core-shell' structure) aimed at maximizing the dispersion and thermal resistance of Ni particles are then discussed and compared. The catalytic supports used to promote dispersion of the active metallic phase, the oxygen-storage capacity, and the metal/support interaction are also described. The review then addresses the fact that both the nature of the support and the addition of promoters and other metallic phases that modify the surface properties can control the interaction between the metal and the support, the electronic density of the active phase, and the degree of Ni reduction. Finally, new lines of research focused on the DRM process to make the reaction conditions milder and favor the process at low temperatures are also summarized. © 2021 Taylor & Francis.The authors are grateful for financial support from the Spanish Ministry of Science and Innovation (MCIN/AEI/10.13039/501100011033) through project PID2020-112656RB-C21. JJTH thanks Universidad Pública de Navarra for a pre-doctoral grant. AG also thanks Santander Bank for funding via the Research Intensification Program.Taylor & FrancisInstitute for Advanced Materials and Mathematics - INAMAT22021info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersionapplication/pdfhttps://hdl.handle.net/2454/42906reponame:Academica-e. Repositorio Institucional de la Universidad Pública de Navarrainstname:Universidad Pública de NavarraInglésinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-112656RB-C21© 2021 Taylor & Francisinfo:eu-repo/semantics/openAccessoai:academica-e.unavarra.es:2454/429062026-06-17T12:41:47Z |
| dc.title.none.fl_str_mv |
Recent progress in the application of Ni-based catalysts for the dry reforming of methane |
| title |
Recent progress in the application of Ni-based catalysts for the dry reforming of methane |
| spellingShingle |
Recent progress in the application of Ni-based catalysts for the dry reforming of methane Torrez Herrera, Jonathan Josué Bimetallic catalyst Catalytic promoter CH4 valorization CO2 utilization Greenhouse gases Heterogeneous catalysts Ni-based catalyst Noble metal catalyst |
| title_short |
Recent progress in the application of Ni-based catalysts for the dry reforming of methane |
| title_full |
Recent progress in the application of Ni-based catalysts for the dry reforming of methane |
| title_fullStr |
Recent progress in the application of Ni-based catalysts for the dry reforming of methane |
| title_full_unstemmed |
Recent progress in the application of Ni-based catalysts for the dry reforming of methane |
| title_sort |
Recent progress in the application of Ni-based catalysts for the dry reforming of methane |
| dc.creator.none.fl_str_mv |
Torrez Herrera, Jonathan Josué Korili, Sophia A. Gil Bravo, Antonio |
| author |
Torrez Herrera, Jonathan Josué |
| author_facet |
Torrez Herrera, Jonathan Josué Korili, Sophia A. Gil Bravo, Antonio |
| author_role |
author |
| author2 |
Korili, Sophia A. Gil Bravo, Antonio |
| author2_role |
author author |
| dc.contributor.none.fl_str_mv |
Institute for Advanced Materials and Mathematics - INAMAT2 |
| dc.subject.none.fl_str_mv |
Bimetallic catalyst Catalytic promoter CH4 valorization CO2 utilization Greenhouse gases Heterogeneous catalysts Ni-based catalyst Noble metal catalyst |
| topic |
Bimetallic catalyst Catalytic promoter CH4 valorization CO2 utilization Greenhouse gases Heterogeneous catalysts Ni-based catalyst Noble metal catalyst |
| description |
Ni-based catalysts are highly efficient in methane-reforming processes. In the particular case of methane reforming in the presence of carbon dioxide, or dry reforming of methane (DRM), it is necessary to modify and control the initial properties of the catalyst to confer on it resistance to carbon deposition in particular, and to sintering of the Ni metal particles. In this regard, catalytic supports and promoters of different natures have been proposed. Likewise, the addition of small amounts of noble metals to avoid oxidation of the Ni active phase during the reforming reaction has been proposed. Catalyst preparation methods have also been identified as being of particular interest, since they can affect the structure of the Ni metal particles. In this review, the thermodynamic and kinetic aspects of the dry reforming of methane reaction are presented first. The most recent developments in synthetic methods (impregnation, sol-gel, co-precipitation, equilibrium deposition filtration, atomic layer deposition, non-thermal glow discharge plasma, multi-bubble sonoluminescence, 'core-shell' structure) aimed at maximizing the dispersion and thermal resistance of Ni particles are then discussed and compared. The catalytic supports used to promote dispersion of the active metallic phase, the oxygen-storage capacity, and the metal/support interaction are also described. The review then addresses the fact that both the nature of the support and the addition of promoters and other metallic phases that modify the surface properties can control the interaction between the metal and the support, the electronic density of the active phase, and the degree of Ni reduction. Finally, new lines of research focused on the DRM process to make the reaction conditions milder and favor the process at low temperatures are also summarized. © 2021 Taylor & Francis. |
| publishDate |
2021 |
| dc.date.none.fl_str_mv |
2021 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion |
| format |
article |
| status_str |
acceptedVersion |
| dc.identifier.none.fl_str_mv |
https://hdl.handle.net/2454/42906 |
| url |
https://hdl.handle.net/2454/42906 |
| dc.language.none.fl_str_mv |
Inglés |
| language_invalid_str_mv |
Inglés |
| dc.relation.none.fl_str_mv |
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-112656RB-C21 |
| dc.rights.none.fl_str_mv |
© 2021 Taylor & Francis info:eu-repo/semantics/openAccess |
| rights_invalid_str_mv |
© 2021 Taylor & Francis |
| eu_rights_str_mv |
openAccess |
| dc.format.none.fl_str_mv |
application/pdf |
| dc.publisher.none.fl_str_mv |
Taylor & Francis |
| publisher.none.fl_str_mv |
Taylor & Francis |
| dc.source.none.fl_str_mv |
reponame:Academica-e. Repositorio Institucional de la Universidad Pública de Navarra instname:Universidad Pública de Navarra |
| instname_str |
Universidad Pública de Navarra |
| reponame_str |
Academica-e. Repositorio Institucional de la Universidad Pública de Navarra |
| collection |
Academica-e. Repositorio Institucional de la Universidad Pública de Navarra |
| repository.name.fl_str_mv |
|
| repository.mail.fl_str_mv |
|
| _version_ |
1869420061445324800 |
| score |
15,811543 |