Highly efficient mixed Li+ transport in ion gel polycationic electrolytes

Outstanding Li conductivity and diffusivity have been achieved in free-standing ion gel electrolytes synthesized by in-situ photopolymerization of 1-(2-methacryloyloxy)ethyl-3-butylimidazolium bis(trifluoromethane sulfonyl)imide (IMMA) and/or poly(ethylene glycol) methacrylate (EGMA), in the presenc...

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Detalles Bibliográficos
Autores: Pablos, Jesús L., García, Nuria, Garrido, Leoncio, Guzmán, J., Catalina, Fernando, Corrales, Teresa, Tiemblo, Pilar
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2018
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/160400
Acceso en línea:http://hdl.handle.net/10261/160400
Access Level:acceso abierto
Palabra clave:Polymerizable ionic liquids
Li-ion transport
Polycationic electrolytes
Ion gel electrolytes
Anion-exchange transport
Descripción
Sumario:Outstanding Li conductivity and diffusivity have been achieved in free-standing ion gel electrolytes synthesized by in-situ photopolymerization of 1-(2-methacryloyloxy)ethyl-3-butylimidazolium bis(trifluoromethane sulfonyl)imide (IMMA) and/or poly(ethylene glycol) methacrylate (EGMA), in the presence of the room temperature ionic liquids 1-ethyl-3-methylimidazolium bis(fluorosulfonyl)imide (EMIFSI), 1-butyl-1-methylpyrrolidinium bis(fluorosulfonyl)imide (BMPFSI) and bis(trifluoromethane)sulfonimide lithium salt (LiTFSI). The membranes are easy to handle and thermally stable up to 200 ºC. Those containing IMMA in the polymer chain present liquid-like ionic conductivities (up to 10 mS cm at 25 ºC), and liquid-like Li diffusivities and conductivities (D≈4 × 10 m s, σ≈1.4 mS cm at 25 ºC) unreported so far in a solid electrolyte. D is not only very high but significantly higher than its counteranions’ diffusivity, D or D, a very rare behavior in electrolytes where transport is, in principle, ruled by viscosity. It is proposed that in these polycationic electrolytes the motion of Li occurs via two different transport mechanisms, the well-known viscosity-governed transport and an additional anion-exchange mechanism that enables very fast Li diffusion. This combination has high practical relevance for Li batteries as it implies a high contribution of σ to the overall electrolyte's conductivity, and it constitutes a breakthrough in the design of polymer-based solid electrolytes for Li.