Exploring the determinants of micro- and nanoplastics exposure among adults in Barcelona, Spain

Micro- and nanoplastics (MNPs) are emerging contaminants present in food, water, and air, yet human exposure levels and key predictors remain poorly understood. We quantified MNP polymer concentrations in human biological samples, estimated dietary intake through food and beverages, and explored pot...

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Detalhes bibliográficos
Autores: Calikanzaros, Emma, Donat-Vargas, Carolina, de Cid, Rafael, Iraola-Guzman, Susana, Arjona, Lourdes, Llorca, Marta, Farré, Marinella, Villanueva, Cristina M.
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2026
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/414728
Acesso em linha:http://hdl.handle.net/10261/414728
https://api.elsevier.com/content/abstract/scopus_id/105027214920
Access Level:acceso abierto
Palavra-chave:Urine
cohort
Food
Microplastics
Nanoplastics
Stool
Water
http://metadata.un.org/sdg/3
http://metadata.un.org/sdg/9
http://metadata.un.org/sdg/11
http://metadata.un.org/sdg/12
http://metadata.un.org/sdg/6
Ensure healthy lives and promote well-being for all at all ages
Ensure availability and sustainable management of water and sanitation for all
Build resilient infrastructure, promote inclusive and sustainable industrialization and foster innovation
Make cities and human settlements inclusive, safe, resilient and sustainable
Ensure sustainable consumption and production patterns
Descrição
Resumo:Micro- and nanoplastics (MNPs) are emerging contaminants present in food, water, and air, yet human exposure levels and key predictors remain poorly understood. We quantified MNP polymer concentrations in human biological samples, estimated dietary intake through food and beverages, and explored potential exposure determinants in a population-based cross-sectional study of 50 healthy adults in Barcelona, Spain. Stool, urine, tap water, and food samples were collected along with detailed dietary and lifestyle data. MNPs (size range: 0.7-20µm) were extracted using ultrasonic-assisted toluene extraction and analyzed via high-performance liquid chromatography using a size exclusion chromatography column coupled to high-resolution mass spectrometry (HPLC(SEC)-HRMS). Plastic additives were also screened in urine and tap water to assess their potential as proxies for MNP exposure. MNPs were detected in 52% of stool (median: 1.8 µg/kg) and urine (median: 22.7 µg/L) samples, with polyamide (PA), polyethylene (PE), and polypropylene (PP) as the most frequently identified polymers. Tap water contained MNPs in 26% of samples (median: 1.4 µg/L), primarily PE. Plastic additives were found in all urine and tap water samples, with diethyl phthalate (68%) and hexamethylcyclotrisiloxane (78%) being most prevalent. Plastic additives in urine showed poor concordance with MNPs in urine, suggesting they are poor exposure biomarkers. Estimated MNP intake from food (1.51 µg/kg body weight/day) greatly exceeded that from beverages (0.02 µg/kg bw/day), with animal products as the main contributors. Differences in MNP levels were observed by country of origin, recent consumption of meat, seafood, and eggs, and regular packaged food consumption.