Colloidal Ni2-: XCoxP nanocrystals for the hydrogen evolution reaction
A cost-effective and scalable approach was developed to produce monodisperse Ni2-xCoxP nanocrystals (NCs) with composition tuned over the entire range (0 = x = 2). Ni2-xCoxP NCs were synthesized using low-cost, stable and low-toxicity triphenyl phosphite (TPP) as a phosphorus source, metal chlorides...
| Autores: | , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2018 |
| País: | España |
| Institución: | Universitat Politècnica de Catalunya (UPC) |
| Repositorio: | UPCommons. Portal del coneixement obert de la UPC |
| Idioma: | inglés |
| OAI Identifier: | oai:upcommons.upc.edu:2117/119655 |
| Acceso en línea: | https://hdl.handle.net/2117/119655 https://dx.doi.org/10.1039/c8ta03485k |
| Access Level: | acceso abierto |
| Palabra clave: | Nanocrystals Hydrogen Nanocristalls Hidrogen Àrees temàtiques de la UPC::Enginyeria química |
| Sumario: | A cost-effective and scalable approach was developed to produce monodisperse Ni2-xCoxP nanocrystals (NCs) with composition tuned over the entire range (0 = x = 2). Ni2-xCoxP NCs were synthesized using low-cost, stable and low-toxicity triphenyl phosphite (TPP) as a phosphorus source, metal chlorides as metal precursors and hexadecylamine (HDA) as a ligand. The synthesis involved the nucleation of amorphous Ni–P and its posterior crystallization and simultaneous incorporation of Co. The composition, size and morphology of the Ni2-xCoxP NCs could be controlled simply by varying the ratio of Ni and Co precursors and the amounts of TPP and HDA. Ternary Ni2-xCoxP-based electrocatalysts exhibited enhanced electrocatalytic activity toward the hydrogen evolution reaction (HER) compared to binary phosphides. In particular, NiCoP electrocatalysts displayed the lowest overpotential of 97 mV at J = 10 mA cm-2 and an excellent long-term stability. DFT calculations of the Gibbs free energy for hydrogen adsorption at the surface of Ni2-xCoxP NCs showed NiCoP to have the most appropriate composition to optimize this parameter within the whole Ni2-xCoxP series. However, the hydrogen adsorption energy was demonstrated not to be the only parameter controlling the HER activity in Ni2-xCoxP. |
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