Glass-forming ability and crystallization behavior of Co62−xFexNb6Zr2B30Co62−xFexNb6Zr2B30 (x=0,16)(x=0,16) amorphous alloys with large supercooled liquid region.
The kinetics of the glass transition and the crystallization process of Co 62 2 x Fe x Nb 6 Zr 2 B 30 ( x 5 0,16) amorphous alloys with large supercooled liquid region was investigated by differential scanning calorimetry. The dependence of the glass transition on the heating rate was analyzed in te...
| Autores: | , , , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2002 |
| País: | España |
| Institución: | Universidad de Sevilla (US) |
| Repositorio: | idUS. Depósito de Investigación de la Universidad de Sevilla |
| OAI Identifier: | oai:idus.us.es:11441/33416 |
| Acceso en línea: | http://hdl.handle.net/11441/33416 https://doi.org/10.1063/1.1518768 |
| Access Level: | acceso abierto |
| Palabra clave: | Crystallization Differential scanning calorimetry Glass transition Heating Supercooling X ray diffraction |
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oai:idus.us.es:11441/33416 |
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Glass-forming ability and crystallization behavior of Co62−xFexNb6Zr2B30Co62−xFexNb6Zr2B30 (x=0,16)(x=0,16) amorphous alloys with large supercooled liquid region.Conde Amiano, AlejandroConde Amiano, Clara FranciscaRoth, StefanGrahl, HelgardOstwald, A.Eckert, J.Borrego Moro, Josefa MaríaCrystallizationDifferential scanning calorimetryGlass transitionHeatingSupercoolingX ray diffractionThe kinetics of the glass transition and the crystallization process of Co 62 2 x Fe x Nb 6 Zr 2 B 30 ( x 5 0,16) amorphous alloys with large supercooled liquid region was investigated by differential scanning calorimetry. The dependence of the glass transition on the heating rate was analyzed in terms of the Vogel–Fulcher–Tamman equation. The glass-forming ability of these alloys is discussed with respect to the width of the supercooled liquid region, the reduced glass transition temperature, and the fragility parameter. The studied alloys are found to be rather strong glass formers. The crystalline phases formed after the devitrification are identified by means of x-ray diffraction and thermomagnetic measurements. The complicated crystallization process requiring long-range atomic rearrangements seems to contribute to the high stability of the supercooled liquid against crystallization.AIP PublishingFísica de la Materia Condensada2002info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfapplication/pdfhttp://hdl.handle.net/11441/33416https://doi.org/10.1063/1.1518768reponame:idUS. Depósito de Investigación de la Universidad de Sevillainstname:Universidad de Sevilla (US)InglésJournal of Applied Physics, 92 (11), 6607-661110.1063/1.1518768info:eu-repo/semantics/openAccessoai:idus.us.es:11441/334162026-06-17T12:51:07Z |
| dc.title.none.fl_str_mv |
Glass-forming ability and crystallization behavior of Co62−xFexNb6Zr2B30Co62−xFexNb6Zr2B30 (x=0,16)(x=0,16) amorphous alloys with large supercooled liquid region. |
| title |
Glass-forming ability and crystallization behavior of Co62−xFexNb6Zr2B30Co62−xFexNb6Zr2B30 (x=0,16)(x=0,16) amorphous alloys with large supercooled liquid region. |
| spellingShingle |
Glass-forming ability and crystallization behavior of Co62−xFexNb6Zr2B30Co62−xFexNb6Zr2B30 (x=0,16)(x=0,16) amorphous alloys with large supercooled liquid region. Conde Amiano, Alejandro Crystallization Differential scanning calorimetry Glass transition Heating Supercooling X ray diffraction |
| title_short |
Glass-forming ability and crystallization behavior of Co62−xFexNb6Zr2B30Co62−xFexNb6Zr2B30 (x=0,16)(x=0,16) amorphous alloys with large supercooled liquid region. |
| title_full |
Glass-forming ability and crystallization behavior of Co62−xFexNb6Zr2B30Co62−xFexNb6Zr2B30 (x=0,16)(x=0,16) amorphous alloys with large supercooled liquid region. |
| title_fullStr |
Glass-forming ability and crystallization behavior of Co62−xFexNb6Zr2B30Co62−xFexNb6Zr2B30 (x=0,16)(x=0,16) amorphous alloys with large supercooled liquid region. |
| title_full_unstemmed |
Glass-forming ability and crystallization behavior of Co62−xFexNb6Zr2B30Co62−xFexNb6Zr2B30 (x=0,16)(x=0,16) amorphous alloys with large supercooled liquid region. |
| title_sort |
Glass-forming ability and crystallization behavior of Co62−xFexNb6Zr2B30Co62−xFexNb6Zr2B30 (x=0,16)(x=0,16) amorphous alloys with large supercooled liquid region. |
| dc.creator.none.fl_str_mv |
Conde Amiano, Alejandro Conde Amiano, Clara Francisca Roth, Stefan Grahl, Helgard Ostwald, A. Eckert, J. Borrego Moro, Josefa María |
| author |
Conde Amiano, Alejandro |
| author_facet |
Conde Amiano, Alejandro Conde Amiano, Clara Francisca Roth, Stefan Grahl, Helgard Ostwald, A. Eckert, J. Borrego Moro, Josefa María |
| author_role |
author |
| author2 |
Conde Amiano, Clara Francisca Roth, Stefan Grahl, Helgard Ostwald, A. Eckert, J. Borrego Moro, Josefa María |
| author2_role |
author author author author author author |
| dc.contributor.none.fl_str_mv |
Física de la Materia Condensada |
| dc.subject.none.fl_str_mv |
Crystallization Differential scanning calorimetry Glass transition Heating Supercooling X ray diffraction |
| topic |
Crystallization Differential scanning calorimetry Glass transition Heating Supercooling X ray diffraction |
| description |
The kinetics of the glass transition and the crystallization process of Co 62 2 x Fe x Nb 6 Zr 2 B 30 ( x 5 0,16) amorphous alloys with large supercooled liquid region was investigated by differential scanning calorimetry. The dependence of the glass transition on the heating rate was analyzed in terms of the Vogel–Fulcher–Tamman equation. The glass-forming ability of these alloys is discussed with respect to the width of the supercooled liquid region, the reduced glass transition temperature, and the fragility parameter. The studied alloys are found to be rather strong glass formers. The crystalline phases formed after the devitrification are identified by means of x-ray diffraction and thermomagnetic measurements. The complicated crystallization process requiring long-range atomic rearrangements seems to contribute to the high stability of the supercooled liquid against crystallization. |
| publishDate |
2002 |
| dc.date.none.fl_str_mv |
2002 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11441/33416 https://doi.org/10.1063/1.1518768 |
| url |
http://hdl.handle.net/11441/33416 https://doi.org/10.1063/1.1518768 |
| dc.language.none.fl_str_mv |
Inglés |
| language_invalid_str_mv |
Inglés |
| dc.relation.none.fl_str_mv |
Journal of Applied Physics, 92 (11), 6607-6611 10.1063/1.1518768 |
| dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess |
| eu_rights_str_mv |
openAccess |
| dc.format.none.fl_str_mv |
application/pdf application/pdf |
| dc.publisher.none.fl_str_mv |
AIP Publishing |
| publisher.none.fl_str_mv |
AIP Publishing |
| dc.source.none.fl_str_mv |
reponame:idUS. Depósito de Investigación de la Universidad de Sevilla instname:Universidad de Sevilla (US) |
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Universidad de Sevilla (US) |
| reponame_str |
idUS. Depósito de Investigación de la Universidad de Sevilla |
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idUS. Depósito de Investigación de la Universidad de Sevilla |
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1869419971820388352 |
| score |
15.301629 |