Tetrasubstituted Thieno[3,2-<i>b</i>]thiophenes as Hole-Transporting Materials for Perovskite Solar Cells

Three hole-transporting materials (HTMs) were prepared following a straightforward synthetic route by cross-linking arylamine-based ligands with a simple thieno[3,2-b]thiophene (TbT) core. The novel HTMs were fully characterized with standard techniques to gain insight into their optical and electro...

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Detalles Bibliográficos
Autores: Urieta Mora, Javier, García Benito, Inés, Zimmermann, Iwan, Aragó, Juan, Molina Ontoria, Agustín, Ortí, Enrique, Martín León, Nazario, Nazeeruddin, Mohammad Khaja
Tipo de recurso: artículo
Fecha de publicación:2019
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/115916
Acceso en línea:https://hdl.handle.net/20.500.14352/115916
Access Level:acceso abierto
Palabra clave:547
Química orgánica (Química)
2306 Química Orgánica
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spelling Tetrasubstituted Thieno[3,2-<i>b</i>]thiophenes as Hole-Transporting Materials for Perovskite Solar CellsUrieta Mora, JavierGarcía Benito, InésZimmermann, IwanAragó, JuanMolina Ontoria, AgustínOrtí, EnriqueMartín León, NazarioNazeeruddin, Mohammad Khaja547Química orgánica (Química)2306 Química OrgánicaThree hole-transporting materials (HTMs) were prepared following a straightforward synthetic route by cross-linking arylamine-based ligands with a simple thieno[3,2-b]thiophene (TbT) core. The novel HTMs were fully characterized with standard techniques to gain insight into their optical and electrochemical properties and were incorporated in solution-processed mesoporous (FAPbI3)0.85(MAPbBr3)0.15 perovskite-based solar cells. The similar molecular structure of the synthesized HTMs was leveraged to investigate the role that the bridging units between the conjugated TbT core and the peripheral arylamine units plays on their properties and thereby on the photovoltaic response. A remarkable power conversion efficiency exceeding 18% was achieved for one of the TbT derivatives, which was slightly higher than the value measured for the benchmark spiro-OMeTAD.AMERICAN CHEMICAL SOCIETYUniversidad Complutense de Madrid20192019-11-2520192019-11-25journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/20.500.14352/115916reponame:Docta Complutenseinstname:Universidad Complutense de Madrid (UCM)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:docta.ucm.es:20.500.14352/1159162026-06-02T12:44:21Z
dc.title.none.fl_str_mv Tetrasubstituted Thieno[3,2-<i>b</i>]thiophenes as Hole-Transporting Materials for Perovskite Solar Cells
title Tetrasubstituted Thieno[3,2-<i>b</i>]thiophenes as Hole-Transporting Materials for Perovskite Solar Cells
spellingShingle Tetrasubstituted Thieno[3,2-<i>b</i>]thiophenes as Hole-Transporting Materials for Perovskite Solar Cells
Urieta Mora, Javier
547
Química orgánica (Química)
2306 Química Orgánica
title_short Tetrasubstituted Thieno[3,2-<i>b</i>]thiophenes as Hole-Transporting Materials for Perovskite Solar Cells
title_full Tetrasubstituted Thieno[3,2-<i>b</i>]thiophenes as Hole-Transporting Materials for Perovskite Solar Cells
title_fullStr Tetrasubstituted Thieno[3,2-<i>b</i>]thiophenes as Hole-Transporting Materials for Perovskite Solar Cells
title_full_unstemmed Tetrasubstituted Thieno[3,2-<i>b</i>]thiophenes as Hole-Transporting Materials for Perovskite Solar Cells
title_sort Tetrasubstituted Thieno[3,2-<i>b</i>]thiophenes as Hole-Transporting Materials for Perovskite Solar Cells
dc.creator.none.fl_str_mv Urieta Mora, Javier
García Benito, Inés
Zimmermann, Iwan
Aragó, Juan
Molina Ontoria, Agustín
Ortí, Enrique
Martín León, Nazario
Nazeeruddin, Mohammad Khaja
author Urieta Mora, Javier
author_facet Urieta Mora, Javier
García Benito, Inés
Zimmermann, Iwan
Aragó, Juan
Molina Ontoria, Agustín
Ortí, Enrique
Martín León, Nazario
Nazeeruddin, Mohammad Khaja
author_role author
author2 García Benito, Inés
Zimmermann, Iwan
Aragó, Juan
Molina Ontoria, Agustín
Ortí, Enrique
Martín León, Nazario
Nazeeruddin, Mohammad Khaja
author2_role author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Universidad Complutense de Madrid
dc.subject.none.fl_str_mv 547
Química orgánica (Química)
2306 Química Orgánica
topic 547
Química orgánica (Química)
2306 Química Orgánica
description Three hole-transporting materials (HTMs) were prepared following a straightforward synthetic route by cross-linking arylamine-based ligands with a simple thieno[3,2-b]thiophene (TbT) core. The novel HTMs were fully characterized with standard techniques to gain insight into their optical and electrochemical properties and were incorporated in solution-processed mesoporous (FAPbI3)0.85(MAPbBr3)0.15 perovskite-based solar cells. The similar molecular structure of the synthesized HTMs was leveraged to investigate the role that the bridging units between the conjugated TbT core and the peripheral arylamine units plays on their properties and thereby on the photovoltaic response. A remarkable power conversion efficiency exceeding 18% was achieved for one of the TbT derivatives, which was slightly higher than the value measured for the benchmark spiro-OMeTAD.
publishDate 2019
dc.date.none.fl_str_mv 2019
2019-11-25
2019
2019-11-25
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/20.500.14352/115916
url https://hdl.handle.net/20.500.14352/115916
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv AMERICAN CHEMICAL SOCIETY
publisher.none.fl_str_mv AMERICAN CHEMICAL SOCIETY
dc.source.none.fl_str_mv reponame:Docta Complutense
instname:Universidad Complutense de Madrid (UCM)
instname_str Universidad Complutense de Madrid (UCM)
reponame_str Docta Complutense
collection Docta Complutense
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.811543

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