Supersaturation functions in binary solid solution–aqueous solution systems

In this paper, we present a brief review of the thermodynamic equilibrium of binary solid solution–aqueous solution (SS-AS) systems and derive an expression hat allows us to evaluate the supersaturation or undersaturation of a given aqueous solution with respect to the whole range of solid compositi...

Descripción completa

Detalles Bibliográficos
Autores: Astilleros García-Monge, José Manuel, Pina Martínez, Carlos Manuel, Fernández Díaz, María Lourdes, Putnis, Andrew
Tipo de recurso: artículo
Fecha de publicación:2003
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/49792
Acceso en línea:https://hdl.handle.net/20.500.14352/49792
Access Level:acceso abierto
Palabra clave:548
544
Thermodynamic equilibrium
Binary solid solution–aqueous solution
Crystalization
Cristalografía (Geología)
id ES_cd5d36e2d946300688fc2d5c005f6e2d
oai_identifier_str oai:docta.ucm.es:20.500.14352/49792
network_acronym_str ES
network_name_str España
repository_id_str
spelling Supersaturation functions in binary solid solution–aqueous solution systemsAstilleros García-Monge, José ManuelPina Martínez, Carlos ManuelFernández Díaz, María LourdesPutnis, Andrew548544Thermodynamic equilibriumBinary solid solution–aqueous solutionCrystalizationCristalografía (Geología)In this paper, we present a brief review of the thermodynamic equilibrium of binary solid solution–aqueous solution (SS-AS) systems and derive an expression hat allows us to evaluate the supersaturation or undersaturation of a given aqueous solution with respect to the whole range of solid compositions: the δ(x) function. Such an expression is based on the two conditions that define the SS-AS thermodynamic equilibrium. The derivation of the new supersaturation function, δ(x), was made by considering in detail the compositional relationships between solid and aqueous phases. To represent the new formulation on Lippmann diagrams, we have defined a new thermodynamic concept: the “actual activity.” In addition, we show how our supersaturation function behaves for both ideal and subregular solid solutions. The behaviour and applicability of both the δ(x) function and a previous supersaturation function, β(x), defined by Prieto et al. (1993), is discussed.Elsevier Science LtdUniversidad Complutense de Madrid20032003-01-0120032003-01-01journal articlehttp://purl.org/coar/resource_type/c_6501info:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/20.500.14352/49792reponame:Docta Complutenseinstname:Universidad Complutense de Madrid (UCM)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2info:eu-repo/semantics/openAccessoai:docta.ucm.es:20.500.14352/497922026-06-02T12:44:21Z
dc.title.none.fl_str_mv Supersaturation functions in binary solid solution–aqueous solution systems
title Supersaturation functions in binary solid solution–aqueous solution systems
spellingShingle Supersaturation functions in binary solid solution–aqueous solution systems
Astilleros García-Monge, José Manuel
548
544
Thermodynamic equilibrium
Binary solid solution–aqueous solution
Crystalization
Cristalografía (Geología)
title_short Supersaturation functions in binary solid solution–aqueous solution systems
title_full Supersaturation functions in binary solid solution–aqueous solution systems
title_fullStr Supersaturation functions in binary solid solution–aqueous solution systems
title_full_unstemmed Supersaturation functions in binary solid solution–aqueous solution systems
title_sort Supersaturation functions in binary solid solution–aqueous solution systems
dc.creator.none.fl_str_mv Astilleros García-Monge, José Manuel
Pina Martínez, Carlos Manuel
Fernández Díaz, María Lourdes
Putnis, Andrew
author Astilleros García-Monge, José Manuel
author_facet Astilleros García-Monge, José Manuel
Pina Martínez, Carlos Manuel
Fernández Díaz, María Lourdes
Putnis, Andrew
author_role author
author2 Pina Martínez, Carlos Manuel
Fernández Díaz, María Lourdes
Putnis, Andrew
author2_role author
author
author
dc.contributor.none.fl_str_mv Universidad Complutense de Madrid
dc.subject.none.fl_str_mv 548
544
Thermodynamic equilibrium
Binary solid solution–aqueous solution
Crystalization
Cristalografía (Geología)
topic 548
544
Thermodynamic equilibrium
Binary solid solution–aqueous solution
Crystalization
Cristalografía (Geología)
description In this paper, we present a brief review of the thermodynamic equilibrium of binary solid solution–aqueous solution (SS-AS) systems and derive an expression hat allows us to evaluate the supersaturation or undersaturation of a given aqueous solution with respect to the whole range of solid compositions: the δ(x) function. Such an expression is based on the two conditions that define the SS-AS thermodynamic equilibrium. The derivation of the new supersaturation function, δ(x), was made by considering in detail the compositional relationships between solid and aqueous phases. To represent the new formulation on Lippmann diagrams, we have defined a new thermodynamic concept: the “actual activity.” In addition, we show how our supersaturation function behaves for both ideal and subregular solid solutions. The behaviour and applicability of both the δ(x) function and a previous supersaturation function, β(x), defined by Prieto et al. (1993), is discussed.
publishDate 2003
dc.date.none.fl_str_mv 2003
2003-01-01
2003
2003-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/20.500.14352/49792
url https://hdl.handle.net/20.500.14352/49792
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier Science Ltd
publisher.none.fl_str_mv Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:Docta Complutense
instname:Universidad Complutense de Madrid (UCM)
instname_str Universidad Complutense de Madrid (UCM)
reponame_str Docta Complutense
collection Docta Complutense
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869419825790451712
score 15.300719

Similares en LA Referencia