Promotion of tribological and hydrophobic properties 1 of a coating on TPE substrates by atmospheric plasma-polymerization

Thermoplastic elastomers (TPE) are used in the automotive sealing industry with the objective of producing anti-friction and hydrophobic components. At present, the anti-friction property is achieved by the electrostatic flocking, which sometimes produces an irregular coating. Therefore, this paper&...

Descripción completa

Detalles Bibliográficos
Autores: Sainz-Garciá, E. [0000-0001-5776-0455], Alba-Eliás, F. [0000-0002-3918-0155], Múgica-Vidal, R. [0000-0003-2150-4032], Pantoja-Ruiz, M. [0000-0003-0950-2827]
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2016
País:España
Institución:Universidad de La Rioja (UR)
Repositorio:RIUR. Repositorio Institucional de la Universidad de La Rioja
OAI Identifier:oai:portal.dialnet.es:doc/5bbc685bb750603269e80764
Acceso en línea:https://investigacion.unirioja.es/documentos/5bbc685bb750603269e80764
Access Level:acceso abierto
Palabra clave:Adhesion
Aminopropyltriethoxysilane
Friction coefficient
Hydrophobicity
Perfluorohexene
Plasma-polymerization
Descripción
Sumario:Thermoplastic elastomers (TPE) are used in the automotive sealing industry with the objective of producing anti-friction and hydrophobic components. At present, the anti-friction property is achieved by the electrostatic flocking, which sometimes produces an irregular coating. Therefore, this paper's objective is the promotion of adhesion of an anti-friction (based on the silane aminopropyltriethoxysilane-APTES-) and hydrophobic (based on the fluorinated precursor 1-perfluorohexene-PFH-) coating by the adhesion promoter, APTES. Different mixtures of APTES and PFH have been applied to a TPE substrate by an Atmospheric Pressure Plasma Jet (APPJ) system with Dielectric Barrier Discharge (DBD) in order to determine the optimal mixture of precursors. The main difficulty in this work lies in the hydrophilic character of APTES and the low adhesion of the fluorinated coatings. The sample coated with a mixture of 50% APTES and 50% PFH (A50P50) was found to be the best one to satisfy both properties at the same time, despite not having the highest dynamic water contact angle (WCA) or the lowest friction coefficient. © 2016 Elsevier B.V. All rights reserved.