Towards nanostructured ITO-based electrochemical sensors: Fabrication, characterization and functionalization

The need for miniaturized, low-cost and ultrasensitive electrochemical sensors has motivated the search and study of new nanostructured materials. We propose nanostructured indium tin oxide (ITO) electrodes as a promising platform due to their good electrical conductivity, transparency to visible wa...

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Detalles Bibliográficos
Autores: Pruna Morales, Raquel, Palacio Bonet, Francisco, López de Miguel, Manuel
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2017
País:España
Institución:Universidad de Barcelona
Repositorio:Dipòsit Digital de la UB
OAI Identifier:oai:diposit.ub.edu:2445/152741
Acceso en línea:https://hdl.handle.net/2445/152741
Access Level:acceso abierto
Palabra clave:Detectors químics
Òxids
Silicones
Espectroscòpia d'infraroigs per transformada de Fourier
Chemical detectors
Oxides
Fourier transform infrared spectroscopy
Descripción
Sumario:The need for miniaturized, low-cost and ultrasensitive electrochemical sensors has motivated the search and study of new nanostructured materials. We propose nanostructured indium tin oxide (ITO) electrodes as a promising platform due to their good electrical conductivity, transparency to visible wavelengths and high surface-to-volume ratio. The nanostructured electrodes were fabricated by electron beam evaporation, and electrochemical techniques were used to quantify more than a 40% increase in electrochemical surface area compared to thin ITO films. The electrodes were derivatized with organosilanes and coated with a molecule providing redox activity. Indeed, an increase in detectability of more than 400% was observed with respect to thin films, indicating the potential viability of nanostructured ITO-based electrochemical biosensors.