Evaluating capacitive deionization for water desalination by direct determination of chloride ions

Ionic conductivity and capacitance measurements are widely used methods for evaluating the desalination efficiency in capacity deionization processes. In this study, these methods are revised and several problems associated to them are identified and evaluated. Furthermore, a new method based on the...

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Detalhes bibliográficos
Autores: Díaz Baizán, Patricia, González Arias, Zoraida, Granda Ferreira, Marcos, Menéndez López, Rosa María, Santamaría Ramírez, Ricardo, Blanco Rodríguez, Clara
Formato: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2014
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/113967
Acesso em linha:http://hdl.handle.net/10261/113967
Access Level:acceso abierto
Palavra-chave:Desalination
Capacitive deionization
Ionic conductivity
Capacitance
Chloride selective electrode
Descrição
Resumo:Ionic conductivity and capacitance measurements are widely used methods for evaluating the desalination efficiency in capacity deionization processes. In this study, these methods are revised and several problems associated to them are identified and evaluated. Furthermore, a new method based on the determination of the chloride ion concentration by means of a chloride selective electrode is proposed as a more reliable alternative for evaluating the desalination performance in these systems. This method has been shown not only to be precise in a wide range of salt concentrations but also to be independent of pH, one of the main limitations of the determinations based on ionic conductivity measurements.