Cyclododecene isomeric separation by (supported) rhodium(i)-catalysed selective dehydrogenative borylation reaction
Cyclododecene, commercially available as a cis/trans mixture, reacts with dipinacolborane (BPin) only through the cis isomer, during the Rh(i)-XantPhos-catalyzed dehydrogenative monoborylation reaction, leaving the starting trans-cyclododecene untouched. In this way, both diastereoisomers can now be...
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Detalhes bibliográficos
| Autores: |
Singh, Amravati S.,
Leyva, Antonio |
| Formato: | artículo
|
| Estado: | Versión publicada |
| Fecha de publicación: | 2023 |
| País: | España |
| Recursos: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/357243 |
| Acesso em linha: | http://hdl.handle.net/10261/357243
|
| Access Level: | acceso abierto |