New fabrication method for producing reduced graphene oxide flexible electrodes by using a low-power visible laser diode engraving system

The fabrication of bendable electronic devices is a scientific-technological area of very rapid advance in which new materials and fabrication techniques are being continuously developed. In these kinds of devices, the fabrication of flexible conductive electrodes adherent to the substrate is a key...

Descripción completa

Detalles Bibliográficos
Autores: Chuquitarqui, Alex, Cotet, Liviu Cosmin, Baia, M., Gyorgy, Eniko, Magyari, K., Barbu-Tudoran, L., Baia, L., Díaz-González, M., Fernández Sánchez, César, Pérez del Pino, Ángel
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2020
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/230597
Acceso en línea:http://hdl.handle.net/10261/230597
Access Level:acceso abierto
Palabra clave:Laser-reduced graphene oxide
Flexible electrode
Graphene electrode
Laser fabrication
Descripción
Sumario:The fabrication of bendable electronic devices is a scientific-technological area of very rapid advance in which new materials and fabrication techniques are being continuously developed. In these kinds of devices, the fabrication of flexible conductive electrodes adherent to the substrate is a key factor. Further, eco-friendliness, low cost and fast production are essential requirements for the successful progress of new technologies. In this work, a novel method for obtaining graphene-based flexible electrodes is presented. Conductive films were obtained by means of the visible laser irradiation of graphene oxide layers deposited on polyethylene terephthalate substrates and self-standing membranes sandwiched between glass slides. Despite the low power of the laser system, the numerical simulations indicate the development of temperatures over 1000 K throughout the irradiated material. The laser-induced spatially confined heating leads to the reduction of the graphene oxide material, whereas the glass-based sandwich assembly avoids reoxidation from the surrounding air. By scanning and pixelated modes, reduced graphene oxide electrodes, up to 100 μm in thickness, and with a resistivity as low as 6 × 10−4 Ωm, were obtained in an easy and versatile way. Proof-of-concept microsupercapacitors and electrochemical sensors were fabricated with this technique, showing promising performance.