Development of a novel epoxy resin based on epoxidized chia oil as matrix and maleinized chia oil as bio-renewable crosslinker

[EN] In this work novel thermosetting resins with high bio-based content have been developed derived from chia seed oil (CO). Epoxidized chia seed oil (ECO) was used as bio-based epoxy matrix with different mixtures of crosslinker agents, that is, methyl nadic anhydride (MNA) as petroleum-derived an...

Descripción completa

Detalles Bibliográficos
Autores: Domínguez-Candela, Iván|||0000-0003-3288-1079, Lora-García, Jaime|||0000-0003-1699-5404, Fombuena, Vicent|||0000-0001-7266-6205, Perez-Nakai, Aina, Torres-Roca, Elena
Tipo de recurso: artículo
Fecha de publicación:2023
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/196003
Acceso en línea:https://riunet.upv.es/handle/10251/196003
Access Level:acceso abierto
Palabra clave:Bio-based epoxy resin
Chia seed oil
Curing time
Ductility
Epoxidized chia seed oil
Maleinized chia seed oil
INGENIERIA QUIMICA
id ES_cb4e3bc66a47e35482412b7add52124a
oai_identifier_str oai:riunet.upv.es:10251/196003
network_acronym_str ES
network_name_str España
repository_id_str
dc.title.none.fl_str_mv Development of a novel epoxy resin based on epoxidized chia oil as matrix and maleinized chia oil as bio-renewable crosslinker
title Development of a novel epoxy resin based on epoxidized chia oil as matrix and maleinized chia oil as bio-renewable crosslinker
spellingShingle Development of a novel epoxy resin based on epoxidized chia oil as matrix and maleinized chia oil as bio-renewable crosslinker
Domínguez-Candela, Iván|||0000-0003-3288-1079
Bio-based epoxy resin
Chia seed oil
Curing time
Ductility
Epoxidized chia seed oil
Maleinized chia seed oil
INGENIERIA QUIMICA
title_short Development of a novel epoxy resin based on epoxidized chia oil as matrix and maleinized chia oil as bio-renewable crosslinker
title_full Development of a novel epoxy resin based on epoxidized chia oil as matrix and maleinized chia oil as bio-renewable crosslinker
title_fullStr Development of a novel epoxy resin based on epoxidized chia oil as matrix and maleinized chia oil as bio-renewable crosslinker
title_full_unstemmed Development of a novel epoxy resin based on epoxidized chia oil as matrix and maleinized chia oil as bio-renewable crosslinker
title_sort Development of a novel epoxy resin based on epoxidized chia oil as matrix and maleinized chia oil as bio-renewable crosslinker
dc.creator.none.fl_str_mv Domínguez-Candela, Iván|||0000-0003-3288-1079
Lora-García, Jaime|||0000-0003-1699-5404
Fombuena, Vicent|||0000-0001-7266-6205
Perez-Nakai, Aina
Torres-Roca, Elena
author Domínguez-Candela, Iván|||0000-0003-3288-1079
author_facet Domínguez-Candela, Iván|||0000-0003-3288-1079
Lora-García, Jaime|||0000-0003-1699-5404
Fombuena, Vicent|||0000-0001-7266-6205
Perez-Nakai, Aina
Torres-Roca, Elena
author_role author
author2 Lora-García, Jaime|||0000-0003-1699-5404
Fombuena, Vicent|||0000-0001-7266-6205
Perez-Nakai, Aina
Torres-Roca, Elena
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Departamento de Ingeniería Química y Nuclear
Instituto Universitario de Seguridad Industrial, Radiofísica y Medioambiental
 Instituto Universitario de Investigación de Tecnología de los Materiales de la UPV
Escuela Politécnica Superior de Alcoy
GENERALITAT VALENCIANA
Agencia Estatal de Investigación
UNIVERSIDAD POLITECNICA DE VALENCIA
Universitat Politècnica de València
Repositorio Institucional de la Universitat Politècnica de València Riunet
dc.subject.none.fl_str_mv Bio-based epoxy resin
Chia seed oil
Curing time
Ductility
Epoxidized chia seed oil
Maleinized chia seed oil
INGENIERIA QUIMICA
topic Bio-based epoxy resin
Chia seed oil
Curing time
Ductility
Epoxidized chia seed oil
Maleinized chia seed oil
INGENIERIA QUIMICA
description [EN] In this work novel thermosetting resins with high bio-based content have been developed derived from chia seed oil (CO). Epoxidized chia seed oil (ECO) was used as bio-based epoxy matrix with different mixtures of crosslinker agents, that is, methyl nadic anhydride (MNA) as petroleum-derived and maleinized chia seed oil (MCO) as bio-based crosslinker. The chemically modified oils from CO, that is, ECO and MCO, and MNA were analyzed by titration and FT-IR. Additional 1H NMR analysis was performed to characterize MCO structure. Two different behaviors were observed using the mixtures of crosslinkers. On one hand, MNA increases the rigidity with bio-based content of 54.2%. On the other hand, the addition of MCO provides higher ductility with bio-based content up to 98%. The same trend was observed by DMTA analysis. The novel cured resins were successfully crosslinked as demonstrated by the mechanical properties, FT-IR analyses, and gel content. Based on the results, it is concluded that MCO presents higher reactivity than MNA, decreasing curing time with possible energy saving at industrial level. In general, the results showed that adding the appropriate amount of MCO, green thermosetting resins with the desired thermal and mechanical properties can be manufactured with high bio-based content.
publishDate 2023
dc.date.none.fl_str_mv 2023
2023-03-10
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://riunet.upv.es/handle/10251/196003
url https://riunet.upv.es/handle/10251/196003
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Agencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020 PID2020-119142RA-I00 EVAPORACION NATURAL ASISTIDA CON MATERIALES ABSORBENTES DE BAJO COSTE PARA EL TRATAMIENTO DE EFLUENTES CONCENTRADOS DE GESTION COMPLEJA
Generalitat Valenciana https://doi.org/10.13039/501100003359 ACIF%2F2020%2F233 AYUDA PREDOCTORAL GVA-DOMINGUEZ CANDELA. PROYECTO: MODIFICACIONES QUIMICAS DEL ACEITE DE SEMILLA DE CHIA COMO RECURSO RENOVABLE FUNCIONAL PARA APLICACIONES EN EL SECTOR DE LOS BIOPOLIMEROS
Universitat Politècnica de València https://doi.org/10.13039/501100004233 PAID-01-19-11 Modificaciones quimicas del aceite de la semilla de chia como recurso renovable funcional para aplicaciones en el sector de los biopolimeros.
Universitat Politècnica de València https://doi.org/10.13039/501100004233 SP20190013
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reconocimiento - No comercial - Sin obra derivada (by-nc-nd)
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reconocimiento - No comercial - Sin obra derivada (by-nc-nd)
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons
publisher.none.fl_str_mv John Wiley & Sons
dc.source.none.fl_str_mv reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname:Universitat Politècnica de València (UPV)
instname_str Universitat Politècnica de València (UPV)
reponame_str RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
collection RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869419576791400448
spelling Development of a novel epoxy resin based on epoxidized chia oil as matrix and maleinized chia oil as bio-renewable crosslinkerDomínguez-Candela, Iván|||0000-0003-3288-1079Lora-García, Jaime|||0000-0003-1699-5404Fombuena, Vicent|||0000-0001-7266-6205Perez-Nakai, AinaTorres-Roca, ElenaBio-based epoxy resinChia seed oilCuring timeDuctilityEpoxidized chia seed oilMaleinized chia seed oilINGENIERIA QUIMICA[EN] In this work novel thermosetting resins with high bio-based content have been developed derived from chia seed oil (CO). Epoxidized chia seed oil (ECO) was used as bio-based epoxy matrix with different mixtures of crosslinker agents, that is, methyl nadic anhydride (MNA) as petroleum-derived and maleinized chia seed oil (MCO) as bio-based crosslinker. The chemically modified oils from CO, that is, ECO and MCO, and MNA were analyzed by titration and FT-IR. Additional 1H NMR analysis was performed to characterize MCO structure. Two different behaviors were observed using the mixtures of crosslinkers. On one hand, MNA increases the rigidity with bio-based content of 54.2%. On the other hand, the addition of MCO provides higher ductility with bio-based content up to 98%. The same trend was observed by DMTA analysis. The novel cured resins were successfully crosslinked as demonstrated by the mechanical properties, FT-IR analyses, and gel content. Based on the results, it is concluded that MCO presents higher reactivity than MNA, decreasing curing time with possible energy saving at industrial level. In general, the results showed that adding the appropriate amount of MCO, green thermosetting resins with the desired thermal and mechanical properties can be manufactured with high bio-based content.Ministry of Science and Innovation,Grant/Award Number: PID2020-119142RA-I00; Universitat Politecnica de Valencia, Grant/Award Number: PAID-2019-SP20190013; Generalitat Valenciana,Grant/Award Number: ACIF/2020/233. This research work was funded by the Ministry of Science and Innovation-¿Retos de la Sociedad¿. Project references: PID2020-119142RA-I00. I. Dominguez-Candela wants to thank Universitat Politècnica de València for his FPI grant (PAID-2019-SP20190013) and Generalitat Valenciana-GVA (ACIF/2020/233). Funding for open access charge: CRUE-Universitat Politècnica de València.John Wiley & SonsDepartamento de Ingeniería Química y NuclearInstituto Universitario de Seguridad Industrial, Radiofísica y Medioambiental Instituto Universitario de Investigación de Tecnología de los Materiales de la UPVEscuela Politécnica Superior de AlcoyGENERALITAT VALENCIANAAgencia Estatal de InvestigaciónUNIVERSIDAD POLITECNICA DE VALENCIAUniversitat Politècnica de ValènciaRepositorio Institucional de la Universitat Politècnica de València Riunet20232023-03-10journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://riunet.upv.es/handle/10251/196003reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valénciainstname:Universitat Politècnica de València (UPV)InglésengAgencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020 PID2020-119142RA-I00 EVAPORACION NATURAL ASISTIDA CON MATERIALES ABSORBENTES DE BAJO COSTE PARA EL TRATAMIENTO DE EFLUENTES CONCENTRADOS DE GESTION COMPLEJAGeneralitat Valenciana https://doi.org/10.13039/501100003359 ACIF%2F2020%2F233 AYUDA PREDOCTORAL GVA-DOMINGUEZ CANDELA. PROYECTO: MODIFICACIONES QUIMICAS DEL ACEITE DE SEMILLA DE CHIA COMO RECURSO RENOVABLE FUNCIONAL PARA APLICACIONES EN EL SECTOR DE LOS BIOPOLIMEROSUniversitat Politècnica de València https://doi.org/10.13039/501100004233 PAID-01-19-11 Modificaciones quimicas del aceite de la semilla de chia como recurso renovable funcional para aplicaciones en el sector de los biopolimeros.Universitat Politècnica de València https://doi.org/10.13039/501100004233 SP20190013open accesshttp://purl.org/coar/access_right/c_abf2Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) http://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:riunet.upv.es:10251/1960032026-06-13T07:49:27Z
score 15,301603

Similares en LA Referencia