Recyclable Chiral Bifunctional Thioureas Derived from [60]Fullerene and Their Use as Highly Efficient Organocatalysts for the Asymmetric Nitro-Michael Reaction

Producción Científica

Bibliographic Details
Authors: Andrés García, José María, González Pérez, Miguel, Maestro Fernández, Alicia, Naharro, Daniel, Pedrosa Sáez, Rafael
Format: article
Publication Date:2017
Country:España
Institution:Universidad de Valladolid
Repository:UVaDOC. Repositorio Documental de la Universidad de Valladolid
OAI Identifier:oai:uvadoc.uva.es:10324/28947
Online Access:https://doi.org/10.1002/ejoc.201601640
http://uvadoc.uva.es/handle/10324/28947
Access Level:Open access
Keyword:Catálisis
Química orgánica
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spelling Recyclable Chiral Bifunctional Thioureas Derived from [60]Fullerene and Their Use as Highly Efficient Organocatalysts for the Asymmetric Nitro-Michael ReactionAndrés García, José MaríaGonzález Pérez, MiguelMaestro Fernández, AliciaNaharro, DanielPedrosa Sáez, RafaelCatálisisQuímica orgánicaProducción CientíficaThree novel fullerothioureas derived from natural valine, phenylalanine, and tert-leucine have been prepared by Prato's reaction of [60]fullerene and the corresponding aldehydes. These hybrids have been used as organocatalysts in a typical stereoselective nitro-Michael addition reaction under homogeneous and neat conditions. The catalysts are easily recoverable by filtration, and are recyclable for at least five times. The addition products were obtained in excellent yields and stereoselectivities by using catalyst loadings of as low as 0.5 mol-%.2018-07-07Ministerio de Economía, Industria y Competitividad (Project CTQ2014-59870-P)Wiley2017info:eu-repo/semantics/articleapplication/pdfhttps://doi.org/10.1002/ejoc.201601640http://uvadoc.uva.es/handle/10324/28947reponame:UVaDOC. Repositorio Documental de la Universidad de Valladolidinstname:Universidad de ValladolidIngléshttp://onlinelibrary.wiley.com/doi/10.1002/ejoc.201601640/fullinfo:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/4.0/oai:uvadoc.uva.es:10324/289472026-06-13T12:44:47Z
dc.title.none.fl_str_mv Recyclable Chiral Bifunctional Thioureas Derived from [60]Fullerene and Their Use as Highly Efficient Organocatalysts for the Asymmetric Nitro-Michael Reaction
title Recyclable Chiral Bifunctional Thioureas Derived from [60]Fullerene and Their Use as Highly Efficient Organocatalysts for the Asymmetric Nitro-Michael Reaction
spellingShingle Recyclable Chiral Bifunctional Thioureas Derived from [60]Fullerene and Their Use as Highly Efficient Organocatalysts for the Asymmetric Nitro-Michael Reaction
Andrés García, José María
Catálisis
Química orgánica
title_short Recyclable Chiral Bifunctional Thioureas Derived from [60]Fullerene and Their Use as Highly Efficient Organocatalysts for the Asymmetric Nitro-Michael Reaction
title_full Recyclable Chiral Bifunctional Thioureas Derived from [60]Fullerene and Their Use as Highly Efficient Organocatalysts for the Asymmetric Nitro-Michael Reaction
title_fullStr Recyclable Chiral Bifunctional Thioureas Derived from [60]Fullerene and Their Use as Highly Efficient Organocatalysts for the Asymmetric Nitro-Michael Reaction
title_full_unstemmed Recyclable Chiral Bifunctional Thioureas Derived from [60]Fullerene and Their Use as Highly Efficient Organocatalysts for the Asymmetric Nitro-Michael Reaction
title_sort Recyclable Chiral Bifunctional Thioureas Derived from [60]Fullerene and Their Use as Highly Efficient Organocatalysts for the Asymmetric Nitro-Michael Reaction
dc.creator.none.fl_str_mv Andrés García, José María
González Pérez, Miguel
Maestro Fernández, Alicia
Naharro, Daniel
Pedrosa Sáez, Rafael
author Andrés García, José María
author_facet Andrés García, José María
González Pérez, Miguel
Maestro Fernández, Alicia
Naharro, Daniel
Pedrosa Sáez, Rafael
author_role author
author2 González Pérez, Miguel
Maestro Fernández, Alicia
Naharro, Daniel
Pedrosa Sáez, Rafael
author2_role author
author
author
author
dc.subject.none.fl_str_mv Catálisis
Química orgánica
topic Catálisis
Química orgánica
description Producción Científica
publishDate 2017
dc.date.none.fl_str_mv 2017
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://doi.org/10.1002/ejoc.201601640
http://uvadoc.uva.es/handle/10324/28947
url https://doi.org/10.1002/ejoc.201601640
http://uvadoc.uva.es/handle/10324/28947
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv http://onlinelibrary.wiley.com/doi/10.1002/ejoc.201601640/full
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:UVaDOC. Repositorio Documental de la Universidad de Valladolid
instname:Universidad de Valladolid
instname_str Universidad de Valladolid
reponame_str UVaDOC. Repositorio Documental de la Universidad de Valladolid
collection UVaDOC. Repositorio Documental de la Universidad de Valladolid
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,300719

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