Optimised room temperature, water-based synthesis of CPO-27-M metal-organic frameworks with high space-time yields

The exceptional porosity of Metal-Organic Frameworks (MOFs) could be harnessed for countless practical applications. However, one of the challenges currently precluding the industrial exploitation of these materials is a lack of green methods for their synthesis. Since green synthetic methods obviat...

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Autores: Garzon-Tovar, Luis|||0000-0003-0253-4041, Carné-Sánchez, Arnau|||0000-0002-8569-6208, Carbonell Fernández, Carlos, Imaz, Inhar|||0000-0002-0278-1141, Maspoch Comamala, Daniel|||0000-0003-1325-9161
Tipo de recurso: artículo
Fecha de publicación:2015
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:216227
Acceso en línea:https://ddd.uab.cat/record/216227
https://dx.doi.org/urn:doi:10.1039/c5ta04923g
Access Level:acceso abierto
Palabra clave:BET surface area
Metal organic framework
Metalorganic frameworks (MOFs)
Reaction parameters
Reagent concentration
Space time yield
Synthetic methods
Water based synthesis
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spelling Optimised room temperature, water-based synthesis of CPO-27-M metal-organic frameworks with high space-time yieldsGarzon-Tovar, Luis|||0000-0003-0253-4041Carné-Sánchez, Arnau|||0000-0002-8569-6208Carbonell Fernández, CarlosImaz, Inhar|||0000-0002-0278-1141Maspoch Comamala, Daniel|||0000-0003-1325-9161BET surface areaMetal organic frameworkMetalorganic frameworks (MOFs)Reaction parametersReagent concentrationSpace time yieldSynthetic methodsWater based synthesisThe exceptional porosity of Metal-Organic Frameworks (MOFs) could be harnessed for countless practical applications. However, one of the challenges currently precluding the industrial exploitation of these materials is a lack of green methods for their synthesis. Since green synthetic methods obviate the use of organic solvents, they are expected to reduce the production costs, safety hazards and environmental impact typically associated with MOF fabrication. Herein we describe the stepwise optimisation of reaction parameters (pH, reagent concentrations and reaction time) for the room temperature, water-based synthesis of several members of the CPO-27/MOF-74-M series of MOFs, including ones made from Mg(ii), Ni(ii), Co(ii) and Zn(ii) ions. Using this method, we built MOFs with excellent BET surface areas and unprecedented Space-Time Yields (STYs). Employing this approach, we have synthesised CPO-27-M MOFs with record BET surface areas, including 1279 m g (CPO-27-Zn), 1351 m g (CPO-27-Ni), 1572 m g (CPO-27-Co), and 1603 m g (CPO-27-Mg). We anticipate that our method could be applied to produce CPO-27-Ni, -Mg, -Co and -Zn with STYs of 44 kg m per day, 191 kg m per day, 1462 kg m per day and a record 18720 kg m per day, respectively. 22015-01-0120152015-01-01Articlehttp://purl.org/coar/resource_type/c_6501AMhttp://purl.org/coar/version/c_ab4af688f83e57aainfo:eu-repo/semantics/articleapplication/pdfhttps://ddd.uab.cat/record/216227https://dx.doi.org/urn:doi:10.1039/c5ta04923greponame:Dipòsit Digital de Documents de la UABinstname:Universitat Autònoma de BarcelonaInglésengMinisterio de Economía y Competitividad https://doi.org/10.13039/501100003329 MAT2012-30994European Commission https://doi.org/10.13039/501100000780 615954Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 SEV-2013-0295open accesshttp://purl.org/coar/access_right/c_abf2Aquest material està protegit per drets d'autor i/o drets afins. Podeu utilitzar aquest material en funció del que permet la legislació de drets d'autor i drets afins d'aplicació al vostre cas. Per a d'altres usos heu d'obtenir permís del(s) titular(s) de drets.https://rightsstatements.org/vocab/InC/1.0/info:eu-repo/semantics/openAccessoai:ddd.uab.cat:2162272026-06-06T12:50:31Z
dc.title.none.fl_str_mv Optimised room temperature, water-based synthesis of CPO-27-M metal-organic frameworks with high space-time yields
title Optimised room temperature, water-based synthesis of CPO-27-M metal-organic frameworks with high space-time yields
spellingShingle Optimised room temperature, water-based synthesis of CPO-27-M metal-organic frameworks with high space-time yields
Garzon-Tovar, Luis|||0000-0003-0253-4041
BET surface area
Metal organic framework
Metalorganic frameworks (MOFs)
Reaction parameters
Reagent concentration
Space time yield
Synthetic methods
Water based synthesis
title_short Optimised room temperature, water-based synthesis of CPO-27-M metal-organic frameworks with high space-time yields
title_full Optimised room temperature, water-based synthesis of CPO-27-M metal-organic frameworks with high space-time yields
title_fullStr Optimised room temperature, water-based synthesis of CPO-27-M metal-organic frameworks with high space-time yields
title_full_unstemmed Optimised room temperature, water-based synthesis of CPO-27-M metal-organic frameworks with high space-time yields
title_sort Optimised room temperature, water-based synthesis of CPO-27-M metal-organic frameworks with high space-time yields
dc.creator.none.fl_str_mv Garzon-Tovar, Luis|||0000-0003-0253-4041
Carné-Sánchez, Arnau|||0000-0002-8569-6208
Carbonell Fernández, Carlos
Imaz, Inhar|||0000-0002-0278-1141
Maspoch Comamala, Daniel|||0000-0003-1325-9161
author Garzon-Tovar, Luis|||0000-0003-0253-4041
author_facet Garzon-Tovar, Luis|||0000-0003-0253-4041
Carné-Sánchez, Arnau|||0000-0002-8569-6208
Carbonell Fernández, Carlos
Imaz, Inhar|||0000-0002-0278-1141
Maspoch Comamala, Daniel|||0000-0003-1325-9161
author_role author
author2 Carné-Sánchez, Arnau|||0000-0002-8569-6208
Carbonell Fernández, Carlos
Imaz, Inhar|||0000-0002-0278-1141
Maspoch Comamala, Daniel|||0000-0003-1325-9161
author2_role author
author
author
author
dc.subject.none.fl_str_mv BET surface area
Metal organic framework
Metalorganic frameworks (MOFs)
Reaction parameters
Reagent concentration
Space time yield
Synthetic methods
Water based synthesis
topic BET surface area
Metal organic framework
Metalorganic frameworks (MOFs)
Reaction parameters
Reagent concentration
Space time yield
Synthetic methods
Water based synthesis
description The exceptional porosity of Metal-Organic Frameworks (MOFs) could be harnessed for countless practical applications. However, one of the challenges currently precluding the industrial exploitation of these materials is a lack of green methods for their synthesis. Since green synthetic methods obviate the use of organic solvents, they are expected to reduce the production costs, safety hazards and environmental impact typically associated with MOF fabrication. Herein we describe the stepwise optimisation of reaction parameters (pH, reagent concentrations and reaction time) for the room temperature, water-based synthesis of several members of the CPO-27/MOF-74-M series of MOFs, including ones made from Mg(ii), Ni(ii), Co(ii) and Zn(ii) ions. Using this method, we built MOFs with excellent BET surface areas and unprecedented Space-Time Yields (STYs). Employing this approach, we have synthesised CPO-27-M MOFs with record BET surface areas, including 1279 m g (CPO-27-Zn), 1351 m g (CPO-27-Ni), 1572 m g (CPO-27-Co), and 1603 m g (CPO-27-Mg). We anticipate that our method could be applied to produce CPO-27-Ni, -Mg, -Co and -Zn with STYs of 44 kg m per day, 191 kg m per day, 1462 kg m per day and a record 18720 kg m per day, respectively.
publishDate 2015
dc.date.none.fl_str_mv 2
2015-01-01
2015
2015-01-01
dc.type.none.fl_str_mv Article
http://purl.org/coar/resource_type/c_6501
AM
http://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://ddd.uab.cat/record/216227
https://dx.doi.org/urn:doi:10.1039/c5ta04923g
url https://ddd.uab.cat/record/216227
https://dx.doi.org/urn:doi:10.1039/c5ta04923g
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 MAT2012-30994
European Commission https://doi.org/10.13039/501100000780 615954
Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 SEV-2013-0295
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://rightsstatements.org/vocab/InC/1.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://rightsstatements.org/vocab/InC/1.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Dipòsit Digital de Documents de la UAB
instname:Universitat Autònoma de Barcelona
instname_str Universitat Autònoma de Barcelona
reponame_str Dipòsit Digital de Documents de la UAB
collection Dipòsit Digital de Documents de la UAB
repository.name.fl_str_mv
repository.mail.fl_str_mv
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