Ag+ release inhibition from ZrCN–Ag coatings by surface agglomeration mechanism: structural characterization
New multifunctional materials based on well-established materials to which functional properties are added, such as antibacterial performance, have become a relevant research topic, in order to meet the requirements of today’s technological advances. This paper reports the results of a detailed stru...
| Autores: | , , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2013 |
| País: | España |
| Institución: | Universidad de Sevilla (US) |
| Repositorio: | idUS. Depósito de Investigación de la Universidad de Sevilla |
| OAI Identifier: | oai:idus.us.es:11441/147312 |
| Acceso en línea: | https://hdl.handle.net/11441/147312 https://doi.org/10.1088/0022-3727/46/32/325303 |
| Access Level: | acceso abierto |
| Sumario: | New multifunctional materials based on well-established materials to which functional properties are added, such as antibacterial performance, have become a relevant research topic, in order to meet the requirements of today’s technological advances. This paper reports the results of a detailed structural and chemical characterization study of ZrCN–Ag coatings produced by reactive magnetron sputtering, as well as the release of silver after immersion in a simulated body fluid (Hank’s balanced salt solution), which mimic the material behaviour within the human body. The chemical composition was evaluated by electron probe microanalysis, x-ray photoelectron spectroscopy and Rutherford backscattering spectroscopy, whereas the structure was assessed by Raman spectroscopy and x-ray diffraction. The material exhibits a homogeneous distribution of the elements throughout the films, with a (C + N)/Zr ratio of around 1.3 and 15 at% of silver. A mixture of amorphous (a-C and CNx ) and crystalline phases (ZrCN) was identified. In addition, the silver was detected to be released in less than 0.7% of the total silver in the films, occurring during the first two hours of immersion; no further release was evidenced after this period of time. |
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