Organic-Inorganic Hybrid Silica Material Derived from a Monosilylated Grubbs-Hoveyda Ruthenium Carbene as a Recyclable Metathesis Catalyst

The synthesis of a monosilylated Grubbs-Hoveyda ruthenium alkylidene complex is described, as well as the preparation and characterization of the corresponding material by sol-gel cogelification with tetraethoxysilane (TEOS) and the assay of this recyclable supported catalyst in ring-closing diene a...

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Autores: Borja Rodríguez, Guadalupe, Pleixats, Roser|||0000-0003-2544-732X, Alibés, Ramon|||0000-0002-7997-2691, Cattoën, Xavier, Wong Chi Man, Michel
Tipo de recurso: artículo
Fecha de publicación:2010
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:167670
Acceso en línea:https://ddd.uab.cat/record/167670
https://dx.doi.org/urn:doi:10.3390/molecules15085756
Access Level:acceso abierto
Palabra clave:Catalyst immobilization
Ring-closing metathesis
Organic-inorganic hybrid material
Ruthenium alkylidene
Sol-gel process
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spelling Organic-Inorganic Hybrid Silica Material Derived from a Monosilylated Grubbs-Hoveyda Ruthenium Carbene as a Recyclable Metathesis CatalystBorja Rodríguez, GuadalupePleixats, Roser|||0000-0003-2544-732XAlibés, Ramon|||0000-0002-7997-2691Cattoën, XavierWong Chi Man, MichelCatalyst immobilizationRing-closing metathesisOrganic-inorganic hybrid materialRuthenium alkylideneSol-gel processThe synthesis of a monosilylated Grubbs-Hoveyda ruthenium alkylidene complex is described, as well as the preparation and characterization of the corresponding material by sol-gel cogelification with tetraethoxysilane (TEOS) and the assay of this recyclable supported catalyst in ring-closing diene and enyne metathesis reactions under thermal and microwave conditions. 22010-01-0120102010-01-01Articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://ddd.uab.cat/record/167670https://dx.doi.org/urn:doi:10.3390/molecules15085756reponame:Dipòsit Digital de Documents de la UABinstname:Universitat Autònoma de BarcelonaInglésengopen accesshttp://purl.org/coar/access_right/c_abf2Aquest document està subjecte a una llicència d'ús Creative Commons. Es permet la reproducció total o parcial, la distribució, la comunicació pública de l'obra i la creació d'obres derivades, fins i tot amb finalitats comercials, sempre i quan es reconegui l'autoria de l'obra original.https://creativecommons.org/licenses/by/3.0/info:eu-repo/semantics/openAccessoai:ddd.uab.cat:1676702026-06-06T12:50:31Z
dc.title.none.fl_str_mv Organic-Inorganic Hybrid Silica Material Derived from a Monosilylated Grubbs-Hoveyda Ruthenium Carbene as a Recyclable Metathesis Catalyst
title Organic-Inorganic Hybrid Silica Material Derived from a Monosilylated Grubbs-Hoveyda Ruthenium Carbene as a Recyclable Metathesis Catalyst
spellingShingle Organic-Inorganic Hybrid Silica Material Derived from a Monosilylated Grubbs-Hoveyda Ruthenium Carbene as a Recyclable Metathesis Catalyst
Borja Rodríguez, Guadalupe
Catalyst immobilization
Ring-closing metathesis
Organic-inorganic hybrid material
Ruthenium alkylidene
Sol-gel process
title_short Organic-Inorganic Hybrid Silica Material Derived from a Monosilylated Grubbs-Hoveyda Ruthenium Carbene as a Recyclable Metathesis Catalyst
title_full Organic-Inorganic Hybrid Silica Material Derived from a Monosilylated Grubbs-Hoveyda Ruthenium Carbene as a Recyclable Metathesis Catalyst
title_fullStr Organic-Inorganic Hybrid Silica Material Derived from a Monosilylated Grubbs-Hoveyda Ruthenium Carbene as a Recyclable Metathesis Catalyst
title_full_unstemmed Organic-Inorganic Hybrid Silica Material Derived from a Monosilylated Grubbs-Hoveyda Ruthenium Carbene as a Recyclable Metathesis Catalyst
title_sort Organic-Inorganic Hybrid Silica Material Derived from a Monosilylated Grubbs-Hoveyda Ruthenium Carbene as a Recyclable Metathesis Catalyst
dc.creator.none.fl_str_mv Borja Rodríguez, Guadalupe
Pleixats, Roser|||0000-0003-2544-732X
Alibés, Ramon|||0000-0002-7997-2691
Cattoën, Xavier
Wong Chi Man, Michel
author Borja Rodríguez, Guadalupe
author_facet Borja Rodríguez, Guadalupe
Pleixats, Roser|||0000-0003-2544-732X
Alibés, Ramon|||0000-0002-7997-2691
Cattoën, Xavier
Wong Chi Man, Michel
author_role author
author2 Pleixats, Roser|||0000-0003-2544-732X
Alibés, Ramon|||0000-0002-7997-2691
Cattoën, Xavier
Wong Chi Man, Michel
author2_role author
author
author
author
dc.subject.none.fl_str_mv Catalyst immobilization
Ring-closing metathesis
Organic-inorganic hybrid material
Ruthenium alkylidene
Sol-gel process
topic Catalyst immobilization
Ring-closing metathesis
Organic-inorganic hybrid material
Ruthenium alkylidene
Sol-gel process
description The synthesis of a monosilylated Grubbs-Hoveyda ruthenium alkylidene complex is described, as well as the preparation and characterization of the corresponding material by sol-gel cogelification with tetraethoxysilane (TEOS) and the assay of this recyclable supported catalyst in ring-closing diene and enyne metathesis reactions under thermal and microwave conditions.
publishDate 2010
dc.date.none.fl_str_mv 2
2010-01-01
2010
2010-01-01
dc.type.none.fl_str_mv Article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://ddd.uab.cat/record/167670
https://dx.doi.org/urn:doi:10.3390/molecules15085756
url https://ddd.uab.cat/record/167670
https://dx.doi.org/urn:doi:10.3390/molecules15085756
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://creativecommons.org/licenses/by/3.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://creativecommons.org/licenses/by/3.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Dipòsit Digital de Documents de la UAB
instname:Universitat Autònoma de Barcelona
instname_str Universitat Autònoma de Barcelona
reponame_str Dipòsit Digital de Documents de la UAB
collection Dipòsit Digital de Documents de la UAB
repository.name.fl_str_mv
repository.mail.fl_str_mv
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