Nomenclature for boranes and related species (IUPAC Recommendations 2019)

An appraisal of the current IUPAC recommendations for the nomenclature of boranes and related systems has been undertaken. New developments in the field have been investigated and existing nomenclature systems have been adapted to accommodate these new developments. The principal areas considered ar...

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Detalles Bibliográficos
Autores: Beckett, Michael A., Brellochs, Bernd, Chizhevsky, Igor T., Damhus, Ture, Hellwich, Karl-Heinz, Kennedy, John D., Laitinen, Risto, Powell, Warren H., Rabinovich, Daniel, Viñas, Clara, Yerin, Andrey
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2020
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/213230
Acceso en línea:http://hdl.handle.net/10261/213230
Access Level:acceso abierto
Palabra clave:Boranes
Boron hydrides
Carbaboranes
Heteroboranes
IUPAC Chemical Nomenclature and Structural Representation Division
IUPAC Inorganic Chemistry Division
Metallaboranes
Descripción
Sumario:An appraisal of the current IUPAC recommendations for the nomenclature of boranes and related systems has been undertaken. New developments in the field have been investigated and existing nomenclature systems have been adapted to accommodate these new developments. The principal areas considered are stoichiometric and structural nomenclature (including heteroatom and metal-atom subrogation, as well as substitution of hydrogen), conjoined-cage species, supra-icosahedral systems, and sub-icosahedral non-standard structures. Elements of substitutive, additive, and replacement nomenclature systems have been integrated into individual names to address contentious problems in boron nomenclature that have been around for a long time.