Microwave assisted synthesis of polynuclear Ni(II) complexes
In this paper we test a solvent-free microwave assisted synthesis method with a known Ni7 complex, [Ni7(chp)12(OH)2(CH3OH)6] (2), and then extended the method to a more complex ligand system. We prepare two new trinuclear Ni(II) complexes ([Ni3(chp)4(tBuSALOH)2(MeOH)5] (4) and [Ni3(chp)4(iPrSALOH)2(...
| Autores: | , |
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| Tipo de recurso: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2019 |
| País: | España |
| Institución: | Universidad de Barcelona |
| Repositorio: | Dipòsit Digital de la UB |
| OAI Identifier: | oai:diposit.ub.edu:2445/139420 |
| Acceso en línea: | https://hdl.handle.net/2445/139420 |
| Access Level: | acceso abierto |
| Palabra clave: | Complexos metàl·lics Propietats magnètiques Metal complexes Magnetic properties |
| Sumario: | In this paper we test a solvent-free microwave assisted synthesis method with a known Ni7 complex, [Ni7(chp)12(OH)2(CH3OH)6] (2), and then extended the method to a more complex ligand system. We prepare two new trinuclear Ni(II) complexes ([Ni3(chp)4(tBuSALOH)2(MeOH)5] (4) and [Ni3(chp)4(iPrSALOH)2(MeOH)6] (5)) and report here their characterization and magnetic properties. |
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