Post-combustion CO2 capture with a commercial activated carbon: Comparison of different regeneration strategies

A commercial activated carbon supplied by Norit, R2030CO2, was evaluated as CO2 adsorbent under conditions relevant to post-combustion CO2 capture (ambient pressure and diluted CO2). It has been demonstrated that this carbon possesses sufficient CO2/N2 selectivity in order to efficiently separate a...

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Detalles Bibliográficos
Autores: González Plaza, Marta, García López, Susana, Rubiera González, Fernando, Pis Martínez, José Juan, Pevida García, Covadonga
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2010
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/102946
Acceso en línea:http://hdl.handle.net/10261/102946
Access Level:acceso abierto
Palabra clave:CO2 capture
Adsorption cycles
Activated carbon
Descripción
Sumario:A commercial activated carbon supplied by Norit, R2030CO2, was evaluated as CO2 adsorbent under conditions relevant to post-combustion CO2 capture (ambient pressure and diluted CO2). It has been demonstrated that this carbon possesses sufficient CO2/N2 selectivity in order to efficiently separate a binary mixture composed of 17% CO2 in N2. Moreover, this carbon was easily completely regenerated and it did not show capacity decay after 10 consecutive cycles. Three different regeneration strategies were compared in a single-bed adsorption unit: temperature swing adsorption (TSA), vacuum swing adsorption (VSA) and a combination of them, vacuum and temperature swing adsorption (VTSA). Through a simple two step TSA cycle, CO2 was concentrated from 17 to 43 vol%. For the single-bed cycle configurations, the productivity and CO2 recovery followed the sequence: TSA < VSA < VTSA. Values of productivity up to 1.9 mol kg−1 h−1 and a maximum CO2 recovery of 97% were reached.