Perovskite solid solutions with multiferroic morphotropic phase boundaries and property enhancement
This is an Open Access article published by World Scientific Publishing Company.-- Review.
| Autores: | , , , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2016 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/142787 |
| Acceso en línea: | http://hdl.handle.net/10261/142787 |
| Access Level: | acceso abierto |
| Palabra clave: | Magnetoelectrics Ceramic technologies Morphotrophic phase boundary Perovskite solid solutions Multiferroics |
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Perovskite solid solutions with multiferroic morphotropic phase boundaries and property enhancementAlgueró, MiguelAmorín, HarveyFernández-Posada, Carmen M.Peña, OctavioRamos, PabloVila Pena, EladioCastro, AliciaMagnetoelectricsCeramic technologiesMorphotrophic phase boundaryPerovskite solid solutionsMultiferroicsThis is an Open Access article published by World Scientific Publishing Company.-- Review.Recently, large phase-change magnetoelectric response has been anticipated by a first-principles investigation of phases in the BiFeO-BiCoO perovskite binary system, associated with the existence of a discontinuous morphotropic phase boundary (MPB) between multiferroic polymorphs of rhombohedral and tetragonal symmetries. This might be a general property of multiferroic phase instabilities, and a novel promising approach for room temperature magnetoelectricity. We review here our current investigations on the identification and study of additional material systems, alternative to BiFeO-BiCoO that has only been obtained by high pressure synthesis. Three systems, whose phase diagrams were, in principle, liable to show multiferroic MPBs have been addressed: the BiMnO-PbTiO and BiFeO-PbTiO binary systems, and the BiFeO-BiMnO-PbTiO ternary one. A comprehensive study of multiferroism across different solid solutions was carried out based on electrical and magnetic characterizations, complemented with mechanical and electromechanical measurements. An in-depth structural analysis was also accomplished when necessary.This work has been funded by Spanish MINECO through the MAT2014-58816-R and MAT2011-2370 projects. C.M.F-P. also acknowledges the financial aid of the Spanish FPI Program (BES 2012-053017). Technical support all along the research by Ms. I. Martínez and Ms. M. M. Antón at ICMM-CSIC is recognized.Peer ReviewedWorld Scientific PublishingMinisterio de Economía y Competitividad (España)Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2017201720162017info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Postprintinfo:eu-repo/semantics/acceptedVersionhttp://hdl.handle.net/10261/142787reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2014-58816-Rhttp://dx.doi.org/10.1142/S2010135X16300048Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/1427872026-05-22T06:33:51Z |
| dc.title.none.fl_str_mv |
Perovskite solid solutions with multiferroic morphotropic phase boundaries and property enhancement |
| title |
Perovskite solid solutions with multiferroic morphotropic phase boundaries and property enhancement |
| spellingShingle |
Perovskite solid solutions with multiferroic morphotropic phase boundaries and property enhancement Algueró, Miguel Magnetoelectrics Ceramic technologies Morphotrophic phase boundary Perovskite solid solutions Multiferroics |
| title_short |
Perovskite solid solutions with multiferroic morphotropic phase boundaries and property enhancement |
| title_full |
Perovskite solid solutions with multiferroic morphotropic phase boundaries and property enhancement |
| title_fullStr |
Perovskite solid solutions with multiferroic morphotropic phase boundaries and property enhancement |
| title_full_unstemmed |
Perovskite solid solutions with multiferroic morphotropic phase boundaries and property enhancement |
| title_sort |
Perovskite solid solutions with multiferroic morphotropic phase boundaries and property enhancement |
| dc.creator.none.fl_str_mv |
Algueró, Miguel Amorín, Harvey Fernández-Posada, Carmen M. Peña, Octavio Ramos, Pablo Vila Pena, Eladio Castro, Alicia |
| author |
Algueró, Miguel |
| author_facet |
Algueró, Miguel Amorín, Harvey Fernández-Posada, Carmen M. Peña, Octavio Ramos, Pablo Vila Pena, Eladio Castro, Alicia |
| author_role |
author |
| author2 |
Amorín, Harvey Fernández-Posada, Carmen M. Peña, Octavio Ramos, Pablo Vila Pena, Eladio Castro, Alicia |
| author2_role |
author author author author author author |
| dc.contributor.none.fl_str_mv |
Ministerio de Economía y Competitividad (España) Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72] |
| dc.subject.none.fl_str_mv |
Magnetoelectrics Ceramic technologies Morphotrophic phase boundary Perovskite solid solutions Multiferroics |
| topic |
Magnetoelectrics Ceramic technologies Morphotrophic phase boundary Perovskite solid solutions Multiferroics |
| description |
This is an Open Access article published by World Scientific Publishing Company.-- Review. |
| publishDate |
2016 |
| dc.date.none.fl_str_mv |
2016 2017 2017 2017 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article http://purl.org/coar/resource_type/c_6501 Postprint info:eu-repo/semantics/acceptedVersion |
| format |
article |
| status_str |
acceptedVersion |
| dc.identifier.none.fl_str_mv |
http://hdl.handle.net/10261/142787 |
| url |
http://hdl.handle.net/10261/142787 |
| dc.language.none.fl_str_mv |
Inglés |
| language_invalid_str_mv |
Inglés |
| dc.relation.none.fl_str_mv |
#PLACEHOLDER_PARENT_METADATA_VALUE# info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2014-58816-R http://dx.doi.org/10.1142/S2010135X16300048 Sí |
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info:eu-repo/semantics/openAccess |
| eu_rights_str_mv |
openAccess |
| dc.publisher.none.fl_str_mv |
World Scientific Publishing |
| publisher.none.fl_str_mv |
World Scientific Publishing |
| dc.source.none.fl_str_mv |
reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC instname:Consejo Superior de Investigaciones Científicas (CSIC) |
| instname_str |
Consejo Superior de Investigaciones Científicas (CSIC) |
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DIGITAL.CSIC. Repositorio Institucional del CSIC |
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DIGITAL.CSIC. Repositorio Institucional del CSIC |
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1869419218549604352 |
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15,811543 |