Chemical Leslie effect in Langmuir monolayers: a complete experimental characterization

We propose a complete characterization of the chemical Leslie effect in a Langmuir monolayer of a chiral liquid crystal. To reach this goal, we developed new experimental techniques using an electric field and a humidifier to prepare large monodomains in which the molecules can freely rotate. We als...

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Detalhes bibliográficos
Autores: Bunel, Felix, Ignés i Mullol, Jordi, Sagués i Mestre, Francesc, Oswald, Patrick
Formato: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2018
País:España
Recursos:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2445/127830
Acesso em linha:https://hdl.handle.net/2445/127830
Access Level:acceso abierto
Palavra-chave:Química de superfícies
Quiralitat
Cristalls líquids
Surface chemistry
Chirality
Liquid crystals
Descrição
Resumo:We propose a complete characterization of the chemical Leslie effect in a Langmuir monolayer of a chiral liquid crystal. To reach this goal, we developed new experimental techniques using an electric field and a humidifier to prepare large monodomains in which the molecules can freely rotate. We also designed six independent experiments to precisely measure the four material constants involved in the dynamics of the monolayer, namely the Leslie coefficient, the rotational viscosity, the curvature elasticity constant and the surface polarization. The relevance of the inverse Leslie effect is also discussed.