Slow Magnetic Relaxation and Modulated Photoluminescent Emission of Coordination Polymer Based on 3-Amino-4-hydroxybenzoate Zn and Co Metal Ions

As a starting point, a new 3D porous framework with the {[CoL]·0.5DMF·HO} chemical formula (where L = 3-amino-4-hydroxybenzoate) is described. Its performance as a single molecule magnet was explored. The study of magnetic properties reveals that Co-MOF shows no frequency-fdependant alternating curr...

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Autores: Echenique-Errandonea, Estitxu, Rojas, Sara, Cepeda, Javier, Choquesillo-Lazarte, Duane, Rodríguez-Diéguez, Antonio, Seco, José M.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2023
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/347645
Acceso en línea:http://hdl.handle.net/10261/347645
Access Level:acceso abierto
Palabra clave:Metal-organic framework
Cobalt-zinc bifunctionality
Induced molecular magnetism
Photoluminescent properties
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spelling Slow Magnetic Relaxation and Modulated Photoluminescent Emission of Coordination Polymer Based on 3-Amino-4-hydroxybenzoate Zn and Co Metal IonsEchenique-Errandonea, EstitxuRojas, SaraCepeda, JavierChoquesillo-Lazarte, DuaneRodríguez-Diéguez, AntonioSeco, José M.Metal-organic frameworkCobalt-zinc bifunctionalityInduced molecular magnetismPhotoluminescent propertiesAs a starting point, a new 3D porous framework with the {[CoL]·0.5DMF·HO} chemical formula (where L = 3-amino-4-hydroxybenzoate) is described. Its performance as a single molecule magnet was explored. The study of magnetic properties reveals that Co-MOF shows no frequency-fdependant alternating current (ac) signals under zero direct current (dc) magnetic field, whereas single-molecule magnet behaviour is achieved when Co ions are diluted in a Zn based matrix. Interestingly, this strategy renders a bifunctional [CoZnL] material that is also characterized by a strong photoluminescent emitting capacity.Financial support was given by Junta de Andalucía (Spain) (B-FQM-734-UGR20, ProyExcel_00386 and FQM-394), University of the Basque Country (GIU20/028), Gobierno Vasco/Eusko Jaurlaritza (IT1755-22), and the Spanish Ministry of Science, Innovation and Universities (MCIU/AEI/FEDER, UE) (PGC2018-102052-A-C22 and PGC2018-102052-B-C21). .R. acknowledge the FEDER/MCIU/AEI for their Ramón y Cajal (RYC2021-032522-I) fellowship.Multidisciplinary Digital Publishing InstituteMinisterio de Ciencia, Innovación y Universidades (España)Junta de AndalucíaAgencia Estatal de Investigación (España)Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2024202420232024info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/347645reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PGC2018-102052-A-C22info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PGC2018-102052-B-C21http://dx.doi.org/10.3390/molecules28041846Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3476452026-05-22T06:33:51Z
dc.title.none.fl_str_mv Slow Magnetic Relaxation and Modulated Photoluminescent Emission of Coordination Polymer Based on 3-Amino-4-hydroxybenzoate Zn and Co Metal Ions
title Slow Magnetic Relaxation and Modulated Photoluminescent Emission of Coordination Polymer Based on 3-Amino-4-hydroxybenzoate Zn and Co Metal Ions
spellingShingle Slow Magnetic Relaxation and Modulated Photoluminescent Emission of Coordination Polymer Based on 3-Amino-4-hydroxybenzoate Zn and Co Metal Ions
Echenique-Errandonea, Estitxu
Metal-organic framework
Cobalt-zinc bifunctionality
Induced molecular magnetism
Photoluminescent properties
title_short Slow Magnetic Relaxation and Modulated Photoluminescent Emission of Coordination Polymer Based on 3-Amino-4-hydroxybenzoate Zn and Co Metal Ions
title_full Slow Magnetic Relaxation and Modulated Photoluminescent Emission of Coordination Polymer Based on 3-Amino-4-hydroxybenzoate Zn and Co Metal Ions
title_fullStr Slow Magnetic Relaxation and Modulated Photoluminescent Emission of Coordination Polymer Based on 3-Amino-4-hydroxybenzoate Zn and Co Metal Ions
title_full_unstemmed Slow Magnetic Relaxation and Modulated Photoluminescent Emission of Coordination Polymer Based on 3-Amino-4-hydroxybenzoate Zn and Co Metal Ions
title_sort Slow Magnetic Relaxation and Modulated Photoluminescent Emission of Coordination Polymer Based on 3-Amino-4-hydroxybenzoate Zn and Co Metal Ions
dc.creator.none.fl_str_mv Echenique-Errandonea, Estitxu
Rojas, Sara
Cepeda, Javier
Choquesillo-Lazarte, Duane
Rodríguez-Diéguez, Antonio
Seco, José M.
author Echenique-Errandonea, Estitxu
author_facet Echenique-Errandonea, Estitxu
Rojas, Sara
Cepeda, Javier
Choquesillo-Lazarte, Duane
Rodríguez-Diéguez, Antonio
Seco, José M.
author_role author
author2 Rojas, Sara
Cepeda, Javier
Choquesillo-Lazarte, Duane
Rodríguez-Diéguez, Antonio
Seco, José M.
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Ministerio de Ciencia, Innovación y Universidades (España)
Junta de Andalucía
Agencia Estatal de Investigación (España)
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Metal-organic framework
Cobalt-zinc bifunctionality
Induced molecular magnetism
Photoluminescent properties
topic Metal-organic framework
Cobalt-zinc bifunctionality
Induced molecular magnetism
Photoluminescent properties
description As a starting point, a new 3D porous framework with the {[CoL]·0.5DMF·HO} chemical formula (where L = 3-amino-4-hydroxybenzoate) is described. Its performance as a single molecule magnet was explored. The study of magnetic properties reveals that Co-MOF shows no frequency-fdependant alternating current (ac) signals under zero direct current (dc) magnetic field, whereas single-molecule magnet behaviour is achieved when Co ions are diluted in a Zn based matrix. Interestingly, this strategy renders a bifunctional [CoZnL] material that is also characterized by a strong photoluminescent emitting capacity.
publishDate 2023
dc.date.none.fl_str_mv 2023
2024
2024
2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/347645
url http://hdl.handle.net/10261/347645
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PGC2018-102052-A-C22
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PGC2018-102052-B-C21
http://dx.doi.org/10.3390/molecules28041846
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,811543

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