Influence of the substrate in the on-surface synthesis and air stability of 1D metal-organic oligomers

The development of applicable functional materials currently stands as one of the main challenges in the field of on-surface synthesis. In this direction, it is necessary to understand their stability in real conditions, what it is known as bridging the pressure gap. Interestingly, although it is we...

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Autores: Gómez-Fernández, José María, Martínez, José I., Zamalloa-Serrano, Jorge Manuel, Naranjo, T., López-Calixto, C. G., Schio, L., Floreano, L., Mendieta-Moreno, J. I., Palacio, Irene, Peña O'Shea, Víctor A. de la, Liras, Marta, Martín-Gago, José A., López, María Francisca, Sánchez-Sánchez, Carlos
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2025
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/400911
Acceso en línea:http://hdl.handle.net/10261/400911
https://api.elsevier.com/content/abstract/scopus_id/85219007055
Access Level:acceso abierto
Palabra clave:DFT calculations
Metal-organic oligomers
On-surface synthesis
Photactive materials
Scanning tunneling microscopy
X-ray photoelectron spectroscopy
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dc.title.none.fl_str_mv Influence of the substrate in the on-surface synthesis and air stability of 1D metal-organic oligomers
title Influence of the substrate in the on-surface synthesis and air stability of 1D metal-organic oligomers
spellingShingle Influence of the substrate in the on-surface synthesis and air stability of 1D metal-organic oligomers
Gómez-Fernández, José María
DFT calculations
Metal-organic oligomers
On-surface synthesis
Photactive materials
Scanning tunneling microscopy
X-ray photoelectron spectroscopy
title_short Influence of the substrate in the on-surface synthesis and air stability of 1D metal-organic oligomers
title_full Influence of the substrate in the on-surface synthesis and air stability of 1D metal-organic oligomers
title_fullStr Influence of the substrate in the on-surface synthesis and air stability of 1D metal-organic oligomers
title_full_unstemmed Influence of the substrate in the on-surface synthesis and air stability of 1D metal-organic oligomers
title_sort Influence of the substrate in the on-surface synthesis and air stability of 1D metal-organic oligomers
dc.creator.none.fl_str_mv Gómez-Fernández, José María
Martínez, José I.
Zamalloa-Serrano, Jorge Manuel
Naranjo, T.
López-Calixto, C. G.
Schio, L.
Floreano, L.
Mendieta-Moreno, J. I.
Palacio, Irene
Peña O'Shea, Víctor A. de la
Liras, Marta
Martín-Gago, José A.
López, María Francisca
Sánchez-Sánchez, Carlos
author Gómez-Fernández, José María
author_facet Gómez-Fernández, José María
Martínez, José I.
Zamalloa-Serrano, Jorge Manuel
Naranjo, T.
López-Calixto, C. G.
Schio, L.
Floreano, L.
Mendieta-Moreno, J. I.
Palacio, Irene
Peña O'Shea, Víctor A. de la
Liras, Marta
Martín-Gago, José A.
López, María Francisca
Sánchez-Sánchez, Carlos
author_role author
author2 Martínez, José I.
Zamalloa-Serrano, Jorge Manuel
Naranjo, T.
López-Calixto, C. G.
Schio, L.
Floreano, L.
Mendieta-Moreno, J. I.
Palacio, Irene
Peña O'Shea, Víctor A. de la
Liras, Marta
Martín-Gago, José A.
López, María Francisca
Sánchez-Sánchez, Carlos
author2_role author
author
author
author
author
author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Comunidad de Madrid
Gómez-Fernández, José María [0000-0002-6405-3879]
Martínez, José I. [0000-0002-2086-8603]
Naranjo, T. [0000-0002-2604-3733]
Schio, L. [0000-0001-8101-4022]
Floreano, L. [0000-0002-3654-3408]
Palacio, Irene [0000-0002-3345-4848]
Liras, Marta [0000-0002-1724-1586]
Martín-Gago, José A. [0000-0003-2663-491X]
Sánchez-Sánchez, Carlos [0000-0001-8644-3766]
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv DFT calculations
Metal-organic oligomers
On-surface synthesis
Photactive materials
Scanning tunneling microscopy
X-ray photoelectron spectroscopy
topic DFT calculations
Metal-organic oligomers
On-surface synthesis
Photactive materials
Scanning tunneling microscopy
X-ray photoelectron spectroscopy
description The development of applicable functional materials currently stands as one of the main challenges in the field of on-surface synthesis. In this direction, it is necessary to understand their stability in real conditions, what it is known as bridging the pressure gap. Interestingly, although it is well-established that the on-surface synthesis will be highly influenced by the selected substrate, little is known about the effect of the underlying substrate on the air stability of on-surface synthesized nanostructures. Applying an on-surface synthesis approach, we report a similar behavior in the synthesis of 1D metal–organic nanostructures based on a BOPHY photoactive molecule on two coinage metal surfaces, Au(1 1 1) and Ag(1 1 1), but a distinct air stability of these nanostructures when exposed to the atmospheric pressure due to the different catalytic properties of the substrates. In both cases, important comparative conclusions are extracted thanks to a combination of surface science characterization techniques with theoretical calculations. This study opens a door to the synthesis of low-dimensional photoactive materials with potential applications, emphasizing the critical role of the substrate not only in the synthesis process but also in the air stability of on-surface synthesized nanostructures.
publishDate 2025
dc.date.none.fl_str_mv 2025
2025
2025
dc.type.none.fl_str_mv info:eu-repo/semantics/article
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dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/400911
https://api.elsevier.com/content/abstract/scopus_id/85219007055
url http://hdl.handle.net/10261/400911
https://api.elsevier.com/content/abstract/scopus_id/85219007055
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The underlying dataset has ben published as materials of the article in the publisher platform at DOI 10.1016/j.apsusc.2025.162804
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publisher.none.fl_str_mv Elsevier BV
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instname:Consejo Superior de Investigaciones Científicas (CSIC)
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spelling Influence of the substrate in the on-surface synthesis and air stability of 1D metal-organic oligomersGómez-Fernández, José MaríaMartínez, José I.Zamalloa-Serrano, Jorge ManuelNaranjo, T.López-Calixto, C. G.Schio, L.Floreano, L.Mendieta-Moreno, J. I.Palacio, IrenePeña O'Shea, Víctor A. de laLiras, MartaMartín-Gago, José A.López, María FranciscaSánchez-Sánchez, CarlosDFT calculationsMetal-organic oligomersOn-surface synthesisPhotactive materialsScanning tunneling microscopyX-ray photoelectron spectroscopyThe development of applicable functional materials currently stands as one of the main challenges in the field of on-surface synthesis. In this direction, it is necessary to understand their stability in real conditions, what it is known as bridging the pressure gap. Interestingly, although it is well-established that the on-surface synthesis will be highly influenced by the selected substrate, little is known about the effect of the underlying substrate on the air stability of on-surface synthesized nanostructures. Applying an on-surface synthesis approach, we report a similar behavior in the synthesis of 1D metal–organic nanostructures based on a BOPHY photoactive molecule on two coinage metal surfaces, Au(1 1 1) and Ag(1 1 1), but a distinct air stability of these nanostructures when exposed to the atmospheric pressure due to the different catalytic properties of the substrates. In both cases, important comparative conclusions are extracted thanks to a combination of surface science characterization techniques with theoretical calculations. This study opens a door to the synthesis of low-dimensional photoactive materials with potential applications, emphasizing the critical role of the substrate not only in the synthesis process but also in the air stability of on-surface synthesized nanostructures.This work was supported by the S2018/NMT-4367, Y2020/NMT-6469, TEC-2024/TEC-308 and TEC-2024/TEC-459 projects funded by the “Comunidad de Madrid” and co-financed by European Structural Funds, and by grants PID2020-113142RB-C21, PID2023-146801NB-C33, PID2023-149077OB-C31, PID2021-12509OA-I00, TED2021-129999B-C31, TED2021-129416A-I00, PLEC2021-007906 and RED2022-134503-T funded by MCIN/AEI/10.13039/501100011033 and by “ERDF A way of making Europe”, by “ERDF/EU” and the “European Union NextGenerationEU/ PRTR”.Peer reviewedElsevier BVComunidad de MadridGómez-Fernández, José María [0000-0002-6405-3879]Martínez, José I. [0000-0002-2086-8603]Naranjo, T. [0000-0002-2604-3733]Schio, L. [0000-0001-8101-4022]Floreano, L. [0000-0002-3654-3408]Palacio, Irene [0000-0002-3345-4848]Liras, Marta [0000-0002-1724-1586]Martín-Gago, José A. [0000-0003-2663-491X]Sánchez-Sánchez, Carlos [0000-0001-8644-3766]Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202520252025info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://hdl.handle.net/10261/400911https://api.elsevier.com/content/abstract/scopus_id/85219007055reponame:DIGITAL.CSIC. 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