A modular and convergent synthetic route to supramolecular cyclic dimers based on Amidinium-Carboxylate interactions

We describe herein the optimized design and modular synthetic approach towards supramolecularly programmed monomers that can form discrete macrocyclic species of controllable size and shape through amidinium-carboxylate interactions in apolar and polar media

Detalles Bibliográficos
Autores: López Martín, Isabel, Veiga Herrero, Jacobo, Aparicio Hernández, Fátima, González Rodríguez, David
Tipo de recurso: artículo
Fecha de publicación:2023
País:España
Institución:Universidad Autónoma de Madrid
Repositorio:Biblos-e Archivo. Repositorio Institucional de la UAM
Idioma:inglés
OAI Identifier:oai:repositorio.uam.es:10486/709102
Acceso en línea:http://hdl.handle.net/10486/709102
https://dx.doi.org/10.1002/chem.202302279
Access Level:acceso abierto
Palabra clave:Amidinium-carboxylate Interactions
Hydrogen-bonding
Supramolecular cyclizations
TT-conjugated macrocycles
Química
Descripción
Sumario:We describe herein the optimized design and modular synthetic approach towards supramolecularly programmed monomers that can form discrete macrocyclic species of controllable size and shape through amidinium-carboxylate interactions in apolar and polar media