Engineering molecular aggregate spectra

We show that optical properties of linear molecular aggregates undergo drastic changes when aggregates are deposited on a metal surface. The dipole-dipole interactions of monomers with their images can result in strong re-structuring of both the exciton band and the absorption spectrum, depending on...

Descripción completa

Detalles Bibliográficos
Autor: Malyshev, Andrey
Tipo de recurso: artículo
Fecha de publicación:2009
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/42784
Acceso en línea:https://hdl.handle.net/20.500.14352/42784
Access Level:acceso abierto
Palabra clave:538.9
Absorption-spectra
Gold nanoparticles
Optical-spectra
Superradiant
Física de materiales
Física del estado sólido
2211 Física del Estado Sólido
Descripción
Sumario:We show that optical properties of linear molecular aggregates undergo drastic changes when aggregates are deposited on a metal surface. The dipole-dipole interactions of monomers with their images can result in strong re-structuring of both the exciton band and the absorption spectrum, depending on the arrangement of the monomer transition dipoles with respect to the surface.