The Role of Peridotite and Serpentinite in the Deep Carbon Cycle: Constraints from Ophiolites and Exhumed Metamorphic Terranes

The main aim of the present Ph.D. thesis is to improve our understanding of carbonation processes of serpentinized peridotite and the fate of serpentinite-hosted carbon during highpressure metamorphism, in order to better constrain their role in the deep carbon cycle of subduction zones. To advance...

Descripción completa

Detalles Bibliográficos
Autor: Menzel, Manuel D.
Tipo de recurso: tesis doctoral
Estado:Versión publicada
Fecha de publicación:2019
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/206776
Acceso en línea:http://hdl.handle.net/10261/206776
Access Level:acceso abierto
Palabra clave:Petrología ígnea
Petrología metamórfica
Geoquímica
id ES_c3f9cda78b89af16a67f3b7254a2a152
oai_identifier_str oai:digital.csic.es:10261/206776
network_acronym_str ES
network_name_str España
repository_id_str
dc.title.none.fl_str_mv The Role of Peridotite and Serpentinite in the Deep Carbon Cycle: Constraints from Ophiolites and Exhumed Metamorphic Terranes
title The Role of Peridotite and Serpentinite in the Deep Carbon Cycle: Constraints from Ophiolites and Exhumed Metamorphic Terranes
spellingShingle The Role of Peridotite and Serpentinite in the Deep Carbon Cycle: Constraints from Ophiolites and Exhumed Metamorphic Terranes
Menzel, Manuel D.
Petrología ígnea
Petrología metamórfica
Geoquímica
title_short The Role of Peridotite and Serpentinite in the Deep Carbon Cycle: Constraints from Ophiolites and Exhumed Metamorphic Terranes
title_full The Role of Peridotite and Serpentinite in the Deep Carbon Cycle: Constraints from Ophiolites and Exhumed Metamorphic Terranes
title_fullStr The Role of Peridotite and Serpentinite in the Deep Carbon Cycle: Constraints from Ophiolites and Exhumed Metamorphic Terranes
title_full_unstemmed The Role of Peridotite and Serpentinite in the Deep Carbon Cycle: Constraints from Ophiolites and Exhumed Metamorphic Terranes
title_sort The Role of Peridotite and Serpentinite in the Deep Carbon Cycle: Constraints from Ophiolites and Exhumed Metamorphic Terranes
dc.creator.none.fl_str_mv Menzel, Manuel D.
author Menzel, Manuel D.
author_facet Menzel, Manuel D.
author_role author
dc.contributor.none.fl_str_mv Garrido, C. J.
López Sánchez-Vizcaíno, V.
European Commission
Agencia Estatal de Investigación (España)
Ministerio de Economía y Competitividad (España)
Junta de Andalucía
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Petrología ígnea
Petrología metamórfica
Geoquímica
topic Petrología ígnea
Petrología metamórfica
Geoquímica
description The main aim of the present Ph.D. thesis is to improve our understanding of carbonation processes of serpentinized peridotite and the fate of serpentinite-hosted carbon during highpressure metamorphism, in order to better constrain their role in the deep carbon cycle of subduction zones. To advance in this overall research goal, this Ph.D. thesis presents the results of two natural case studies of key processes of carbon transfer during fluid-rock interaction in subduction zones: (i) listvenites from the Baie Verte ophiolite (Newfoundland, Canada), a natural analogue for carbon storage in the forearc mantle of subduction zones by carbonation of peridotites; and (ii) meta-ophicarbonates from the Nevado-Filábride Complex (Spain), which provide unprecedented insights into the stability of carbonates during antigorite-serpentinite dehydration in a paleo-subduction terrane. The combination of field, (micro) structural, petrological and geochemical data with thermodynamic modelling sheds new light on the interaction of fluids with the hydrated mantle, which regulates the carbon mobility at forearc and subarc depths of subduction zones. By means of thermodynamic models of prograde and high-pressure infiltration-driven devolatilization reactions in serpentinite-hosted meta-carbonate rocks, this thesis further investigates the effects of electrolytic fluids and the role of open-system flux by serpentinite dehydration fluids on the fluid-mediated release of carbon in subduction zones.
publishDate 2019
dc.date.none.fl_str_mv 2019
2020
2020
2020
dc.type.none.fl_str_mv info:eu-repo/semantics/doctoralThesis
http://purl.org/coar/resource_type/c_db06
Publisher's version
info:eu-repo/semantics/publishedVersion
format doctoralThesis
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/206776
url http://hdl.handle.net/10261/206776
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/EC/FP7/608001
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CGL2016-81085-R
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CGL2016-75224-R

dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Universidad de Granada
publisher.none.fl_str_mv Universidad de Granada
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869418841774227456
spelling The Role of Peridotite and Serpentinite in the Deep Carbon Cycle: Constraints from Ophiolites and Exhumed Metamorphic TerranesMenzel, Manuel D.Petrología ígneaPetrología metamórficaGeoquímicaThe main aim of the present Ph.D. thesis is to improve our understanding of carbonation processes of serpentinized peridotite and the fate of serpentinite-hosted carbon during highpressure metamorphism, in order to better constrain their role in the deep carbon cycle of subduction zones. To advance in this overall research goal, this Ph.D. thesis presents the results of two natural case studies of key processes of carbon transfer during fluid-rock interaction in subduction zones: (i) listvenites from the Baie Verte ophiolite (Newfoundland, Canada), a natural analogue for carbon storage in the forearc mantle of subduction zones by carbonation of peridotites; and (ii) meta-ophicarbonates from the Nevado-Filábride Complex (Spain), which provide unprecedented insights into the stability of carbonates during antigorite-serpentinite dehydration in a paleo-subduction terrane. The combination of field, (micro) structural, petrological and geochemical data with thermodynamic modelling sheds new light on the interaction of fluids with the hydrated mantle, which regulates the carbon mobility at forearc and subarc depths of subduction zones. By means of thermodynamic models of prograde and high-pressure infiltration-driven devolatilization reactions in serpentinite-hosted meta-carbonate rocks, this thesis further investigates the effects of electrolytic fluids and the role of open-system flux by serpentinite dehydration fluids on the fluid-mediated release of carbon in subduction zones.[ES] El principal objetivo de la presente tesis doctoral es el de mejorar nuestra comprensión de los procesos de carbonatación de peridotitas serpentinizadas y el destino del carbono alojado en las serpentinitas durante el metamorfismo de alta presión; la finalidad ultima de este estudio es contribuir a un mejor entendimiento del papel que juegan estos procesos en el ciclo profundo del carbono en las zonas de subducción. Para avanzar en este objetivo general de investigación, en esta tesis se presentan los resultados de estudios de afloramientos naturales fósiles en los que se registran dos procesos clave de transferencia de carbono durante la interacción fluido-roca en zonas de subducción: (i) las listvenitas de la ofiolita de Baie Verte (Terranova, Canadá), que constituye un análogo natural del almacenamiento de carbono por carbonatación de peridotitas del manto de antearco de una zona de subducción; y (ii) los meta-oficarbonatos del complejo Nevado-Filábride (Cordillera Bética, España), que proporcionan información unica sobre la estabilidad de los carbonatos durante la deshidratación de serpentinitas con antigorita en un terreno metamórfico de paleosubducción. La combinación de datos de campo, (micro) estructurales, petrológicos y geoquímicos con modelos termodinámicos ha proporcionado una mejor comprensión de la interacción de los fluidos con el manto hidratado, que regula la movilidad del carbono en las profundidades del antearco y arco volcánico de las zonas de subducción. Mediante modelos termodinámicos de las reacciones de devolatilización en sistema cerrado y abierto, esta tesis investiga los efectos de los fluidos electrolíticos y el papel de los fluidos de deshidratación de serpentinita en la liberación de carbono en rocas carbonatadas en serpentinitas de la placa que subduce de las zonas de subducción.Thesis has been funded by the People Programme (Marie Curie Actions) of the European Union's Seventh Framework Programme FP7/2007- 2013/ under REA grant agreement n°608001, in the frame of the Marie-Curie Initial Training Network ABYSS; Funding from the Spanish “Agencia Estatal de Investigación” (AEI) under grants no. CGL2016–75224–R, CGL2016–81085–R, and grant nº PCIN–2015–053. The “Junta de Andalucía”; Funding of research groups under grants nº RNM–131, RNM–374, and P12–RNM–3141; This research and the research infrastructure at the IACT have benefitted from (co)funding from the European Social Fund and the European Regional Development FundUniversidad de GranadaGarrido, C. J.López Sánchez-Vizcaíno, V.European CommissionAgencia Estatal de Investigación (España)Ministerio de Economía y Competitividad (España)Junta de AndalucíaConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2020202020192020info:eu-repo/semantics/doctoralThesishttp://purl.org/coar/resource_type/c_db06Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/206776reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/EC/FP7/608001info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CGL2016-81085-Rinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CGL2016-75224-RSíinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/2067762026-05-22T06:33:51Z
score 15.812429