Giant spin and orbital moment anisotropies of a Cu-phthalocyanine monolayer
8 páginas, 4 figuras.-- -- PACS number(s): 75.70.Ak, 75.70.Tj, 78.70.Dm, 81.07.Pr.-- et al.
| Autores: | , , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2010 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/44564 |
| Acceso en línea: | http://hdl.handle.net/10261/44564 |
| Access Level: | acceso abierto |
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Giant spin and orbital moment anisotropies of a Cu-phthalocyanine monolayerStepanow, SebastianMugarza, AitorCeballos, GustavoCarbone, CarloGambardella, Pietro8 páginas, 4 figuras.-- -- PACS number(s): 75.70.Ak, 75.70.Tj, 78.70.Dm, 81.07.Pr.-- et al.The magnetism of a Cu-phthalocyanine (CuPc) monolayer on Ag(100) was investigated using x-ray magnetic circular dichroism (XMCD) and ligand-field multiplet calculations. Contrary to other metal-Pc adsorbed on metals, we show that the local CuPc moment survives the interaction with the electronic states of the substrate and presents enhanced susceptibility with respect to bulk powder samples. Our measurements reveal extraordinary orbital moment anisotropy (500%) and an anisotropic spin dipole moment up to twice the isotropic spin in a metal-organic layer. A complete description of the orbital, spin, and spin-orbit operators is provided based on the XMCD sum rules.Work was supported by the European Research Council (Starting Grant No. 203239 NOMAD), European Science Foundation (EUROCORES SANMAG), the Spanish Ministerio de Ciencia e Innovación (Grant No. MAT2007-62341), the Catalan Agència de Gestió d’Ajuts Universitaris i de Recerca (2009 SGR 695), and Italian MIUR (Grant No. PRIN 20087NX9YT).Peer reviewedAmerican Physical SocietyEuropean Research CouncilEuropean Science FoundationMinisterio de Ciencia e Innovación (España)Generalitat de Catalunya201220122010info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501http://hdl.handle.net/10261/44564reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Ingléshttp://dx.doi.org/10.1103/PhysRevB.82.014405info:eu-repo/semantics/openAccessoai:digital.csic.es:10261/445642026-05-22T06:33:51Z |
| dc.title.none.fl_str_mv |
Giant spin and orbital moment anisotropies of a Cu-phthalocyanine monolayer |
| title |
Giant spin and orbital moment anisotropies of a Cu-phthalocyanine monolayer |
| spellingShingle |
Giant spin and orbital moment anisotropies of a Cu-phthalocyanine monolayer Stepanow, Sebastian |
| title_short |
Giant spin and orbital moment anisotropies of a Cu-phthalocyanine monolayer |
| title_full |
Giant spin and orbital moment anisotropies of a Cu-phthalocyanine monolayer |
| title_fullStr |
Giant spin and orbital moment anisotropies of a Cu-phthalocyanine monolayer |
| title_full_unstemmed |
Giant spin and orbital moment anisotropies of a Cu-phthalocyanine monolayer |
| title_sort |
Giant spin and orbital moment anisotropies of a Cu-phthalocyanine monolayer |
| dc.creator.none.fl_str_mv |
Stepanow, Sebastian Mugarza, Aitor Ceballos, Gustavo Carbone, Carlo Gambardella, Pietro |
| author |
Stepanow, Sebastian |
| author_facet |
Stepanow, Sebastian Mugarza, Aitor Ceballos, Gustavo Carbone, Carlo Gambardella, Pietro |
| author_role |
author |
| author2 |
Mugarza, Aitor Ceballos, Gustavo Carbone, Carlo Gambardella, Pietro |
| author2_role |
author author author author |
| dc.contributor.none.fl_str_mv |
European Research Council European Science Foundation Ministerio de Ciencia e Innovación (España) Generalitat de Catalunya |
| description |
8 páginas, 4 figuras.-- -- PACS number(s): 75.70.Ak, 75.70.Tj, 78.70.Dm, 81.07.Pr.-- et al. |
| publishDate |
2010 |
| dc.date.none.fl_str_mv |
2010 2012 2012 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article http://purl.org/coar/resource_type/c_6501 |
| format |
article |
| dc.identifier.none.fl_str_mv |
http://hdl.handle.net/10261/44564 |
| url |
http://hdl.handle.net/10261/44564 |
| dc.language.none.fl_str_mv |
Inglés |
| language_invalid_str_mv |
Inglés |
| dc.relation.none.fl_str_mv |
http://dx.doi.org/10.1103/PhysRevB.82.014405 |
| dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess |
| eu_rights_str_mv |
openAccess |
| dc.publisher.none.fl_str_mv |
American Physical Society |
| publisher.none.fl_str_mv |
American Physical Society |
| dc.source.none.fl_str_mv |
reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC instname:Consejo Superior de Investigaciones Científicas (CSIC) |
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Consejo Superior de Investigaciones Científicas (CSIC) |
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DIGITAL.CSIC. Repositorio Institucional del CSIC |
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DIGITAL.CSIC. Repositorio Institucional del CSIC |
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1869418720460275712 |
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15,811543 |