Laboratory rotational spectroscopy and astronomical search of ethynyl substituted naphthalene

8 pags., 5 figs, 4 tabs.

Detalhes bibliográficos
Autores: Cabezas, Carlos, Peña, Isabel, Cernicharo, José
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2022
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/332696
Acesso em linha:http://hdl.handle.net/10261/332696
http://arxiv.org/abs/2212.06876v1
Access Level:acceso abierto
Palavra-chave:Astrochemistry
ISM: molecules
Methods: laboratory: molecular
Astro-ph.GA
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spelling Laboratory rotational spectroscopy and astronomical search of ethynyl substituted naphthaleneCabezas, CarlosPeña, IsabelCernicharo, JoséAstrochemistryISM: moleculesMethods: laboratory: molecularAstro-ph.GA8 pags., 5 figs, 4 tabs.The recent interstellar detection of cyanonaphthalenes bring interest in related aromatic molecular species that could be present in similar astronomical environments. In this context, ethynyl derivatives of naphthalene are promising candidates to be observed in the Taurus Molecular Cloud (TMC-1), where cyanonaphthalenes together with cyano- and ethynyl- derivatives of cyclopentadiene and benzene have been detected. To enable the interstellar searches for ethynyl derivatives of naphthalene, their pure rotational spectra need to be investigated in the laboratory. We have observed for the first time the rotational spectra of 1- and 2-ethynylnaphthalene species using a broadband Fourier-transform microwave spectrometer operating in the 2-8 GHz frequency region. Accurate spectroscopic parameters are derived from the analysis of the experimental spectra, allowing for reliable predictions for astronomical searches. Our searches in TMC-1 for both isomers provide upper limits for the abundances of these species.CC and JC thank European Research Council for funding support under Synergy Grant ERC-2013-SyG, GA 610256 (NANOCOSMOS) and Ministerio de Ciencia e Innovacion´ through the PID2019-107115GB-C21 project. IP acknowledges Ministerio de Ciencia e Innovacion´ (Grant PID2020-117925GA-I00) and Junta de Castilla y Leon (Grant INFRARED-FEDER IR2020-1-UVa02).Peer reviewedRoyal Astronomical SocietyEuropean CommissionMinisterio de Ciencia e Innovación (España)Junta de Castilla y LeónCabezas, Carlos [0000-0002-1254-7738]Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202320232022info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/332696http://arxiv.org/abs/2212.06876v1reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/EC/FP7/610256info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-107115GB-C21info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-117925GA-I00Monthly Notices of the Royal Astronomical Societyhttps://doi.org/10.1093/mnras/stac3698Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3326962026-05-22T06:33:51Z
dc.title.none.fl_str_mv Laboratory rotational spectroscopy and astronomical search of ethynyl substituted naphthalene
title Laboratory rotational spectroscopy and astronomical search of ethynyl substituted naphthalene
spellingShingle Laboratory rotational spectroscopy and astronomical search of ethynyl substituted naphthalene
Cabezas, Carlos
Astrochemistry
ISM: molecules
Methods: laboratory: molecular
Astro-ph.GA
title_short Laboratory rotational spectroscopy and astronomical search of ethynyl substituted naphthalene
title_full Laboratory rotational spectroscopy and astronomical search of ethynyl substituted naphthalene
title_fullStr Laboratory rotational spectroscopy and astronomical search of ethynyl substituted naphthalene
title_full_unstemmed Laboratory rotational spectroscopy and astronomical search of ethynyl substituted naphthalene
title_sort Laboratory rotational spectroscopy and astronomical search of ethynyl substituted naphthalene
dc.creator.none.fl_str_mv Cabezas, Carlos
Peña, Isabel
Cernicharo, José
author Cabezas, Carlos
author_facet Cabezas, Carlos
Peña, Isabel
Cernicharo, José
author_role author
author2 Peña, Isabel
Cernicharo, José
author2_role author
author
dc.contributor.none.fl_str_mv European Commission
Ministerio de Ciencia e Innovación (España)
Junta de Castilla y León
Cabezas, Carlos [0000-0002-1254-7738]
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Astrochemistry
ISM: molecules
Methods: laboratory: molecular
Astro-ph.GA
topic Astrochemistry
ISM: molecules
Methods: laboratory: molecular
Astro-ph.GA
description 8 pags., 5 figs, 4 tabs.
publishDate 2022
dc.date.none.fl_str_mv 2022
2023
2023
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/332696
http://arxiv.org/abs/2212.06876v1
url http://hdl.handle.net/10261/332696
http://arxiv.org/abs/2212.06876v1
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/EC/FP7/610256
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-107115GB-C21
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-117925GA-I00
Monthly Notices of the Royal Astronomical Society
https://doi.org/10.1093/mnras/stac3698

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publisher.none.fl_str_mv Royal Astronomical Society
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instname:Consejo Superior de Investigaciones Científicas (CSIC)
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