Mechanical characterization of sol–gel epoxy-silylatedhyperbranched poly(ethyleneimine) coatings by meansof Depth Sensing Indentation methods
A series of hybrid epoxy-silica coatings were prepared from a synthesized hyperbranched poly(ethyleneimine) with ethoxysilyl groups at the chain ends and diglycidylether of bisphenol A in different proportions. The curing procedure was based in a first sol-gel reaction performed at 80 °C in a humid...
| Autores: | , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2016 |
| País: | España |
| Institución: | Universitat Politècnica de Catalunya (UPC) |
| Repositorio: | UPCommons. Portal del coneixement obert de la UPC |
| Idioma: | inglés |
| OAI Identifier: | oai:upcommons.upc.edu:2117/101142 |
| Acceso en línea: | https://hdl.handle.net/2117/101142 https://dx.doi.org/10.1016/j.porgcoat.2015.11.017 |
| Access Level: | acceso abierto |
| Palabra clave: | Epoxy resins Sol–gel Hybrids Hyperbranched Epoxy coatings Indentation Mechanical properties Resines epoxídiques Àrees temàtiques de la UPC::Enginyeria dels materials::Materials plàstics i polímers |
| Sumario: | A series of hybrid epoxy-silica coatings were prepared from a synthesized hyperbranched poly(ethyleneimine) with ethoxysilyl groups at the chain ends and diglycidylether of bisphenol A in different proportions. The curing procedure was based in a first sol-gel reaction performed at 80 °C in a humid chamber followed by the anionic homopolymerization of epoxides initiated by 1-methylimidazole in an oven at 180 °C. The prepared coatings were characterized mechanically by means of Depth Sensing Indentation technique. The influence of physical ageing on indentation hardness has been evaluated. The kinetic of the delayed depth recovery has been analyzed using the phenomenological so-called Kohlrausch-Williams-Watts relaxation function. It has been found that silylated hyperbranched poly(ethyleneimine) improves simultaneously the mechanical coating performance and the elastic recovery. |
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