Electrodialysis for the tertiary treatment of municipal wastewater: Efficiency of ion removal and ageing of ion exchange membranes

[EN] Electrodialysis was applied as a tertiary treatment for effluents from a Brazilian sewage treatment plant, and the results are discussed in terms of membrane ageing and process efficiency. Current-voltage analysis and electrodialysis (ED) treatment were performed in a bench cell. The treatment...

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Detalles Bibliográficos
Autores: Rodrigues Gally, Caline, Benvenuti, Tatiane, da Trinidade, Carolina de Moraes, Siqueira Rodrigues, Marco Antonio, Zoppas Ferreira, Jane, Moura Bernardes, Andréa, Pérez-Herranz, Valentín|||0000-0002-4010-0888
Tipo de recurso: artículo
Fecha de publicación:2018
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/146162
Acceso en línea:https://riunet.upv.es/handle/10251/146162
Access Level:acceso abierto
Palabra clave:Electrodialysis
Sewage treatment
Ion-exchange membranes
Water reuse
INGENIERIA QUIMICA
Descripción
Sumario:[EN] Electrodialysis was applied as a tertiary treatment for effluents from a Brazilian sewage treatment plant, and the results are discussed in terms of membrane ageing and process efficiency. Current-voltage analysis and electrodialysis (ED) treatment were performed in a bench cell. The treatment was discontinuously carried out for 930 h within one year. During the experiments, samples were collected for evaluation, and the pH, conductivity and ion concentration were monitored. Thermogravimetric analyses of the membrane were also performed. A reduction in electrical conductivity and the high ion percentage extraction demonstrated the efficiency of the ED treatment, confirming the possibility of using ED as a tertiary treatment for sewage. ED showed 100% effectiveness in terms of meeting the quality standards established by Brazilian legislation on the discharge of effluents. Additionally, important corrosive (Cl-) and encrusting ions (Ca-2 +/- and Mg-2 +/- ) that limit certain industrial uses of water were satisfactorily removed, giving the treated effluent a suitable quality for industrial purposes. The treatment did not suffer harmful fouling effects in terms of ion extraction in the membrane ageing study, indicating the possibility of long-term treatment without requiring cleaning for the membranes; however, this needs to be validated by scaling up the process.