Tailoring the physical properties of hybrid magnetic quinuclidine-based plastic compounds via weak interactions

Herein we explore the opportunities arising from combining bicyclic amine cations with halometallate anions to build organic-inorganic hybrid materials. We will use the crystal engineering approach in these materials, focusing on the tuning of the organic cation, which is mainly responsible for obta...

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Autores: González Izquierdo, Palmerina, Pedro del Valle, Imanol de|||0000-0002-5581-2220, Cañadillas-Delgado, Laura, Beobide, Garikoitz, Vallcorba, Oriol, Sánchez-Andújar, Manuel, Fernández-Díaz, María Teresa, Rodríguez Fernández, Jesús|||0000-0002-4046-2969, Fabelo, Oscar
Tipo de recurso: artículo
Fecha de publicación:2022
País:España
Institución:Universidad de Cantabria (UC)
Repositorio:UCrea Repositorio Abierto de la Universidad de Cantabria
Idioma:inglés
OAI Identifier:oai:repositorio.unican.es:10902/31976
Acceso en línea:https://hdl.handle.net/10902/31976
Access Level:acceso abierto
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spelling Tailoring the physical properties of hybrid magnetic quinuclidine-based plastic compounds via weak interactionsGonzález Izquierdo, PalmerinaPedro del Valle, Imanol de|||0000-0002-5581-2220Cañadillas-Delgado, LauraBeobide, GarikoitzVallcorba, OriolSánchez-Andújar, ManuelFernández-Díaz, María TeresaRodríguez Fernández, Jesús|||0000-0002-4046-2969Fabelo, OscarHerein we explore the opportunities arising from combining bicyclic amine cations with halometallate anions to build organic-inorganic hybrid materials. We will use the crystal engineering approach in these materials, focusing on the tuning of the organic cation, which is mainly responsible for obtaining both new plastic states at high temperature and electrical behaviour below the plastic temperature. Precisely, this work explores the influence of the ketonization of the bicyclic quinuclidine molecule (C7H13N)+, which, combined with the tetrachloroferrate(1-) anion, gives the compound (3-oxoquinuclidinium)[FeCl4]. Interestingly, crystallization in the presence of humidity is enough to obtain an isostructural hydrate phase of formula (3-oxoquinuclidinium)[FeCl4]·H2O. Although the organic-inorganic layered structure is the same in both compounds, the three-dimensional magnetic ordering disappears after the intercalation of crystallization water molecules. A heat treatment above 400 K allows the removal of water obtaining the non-hydrate phase. Finally, the temperature evolution of the electric and magnetic behaviour will be compared with other previously reported hybrid organic-inorganic materials built with tetrachloroferrate ions and quinuclidinium-based cations.Financial support from Universidad de Cantabria (Proyecto Puente convocatoria 2018 funded by SODERCAN_FEDER), Universidad del País Vasco/Euskal Herriko Unibertsitatea (GIU17/50 and PPG17/37) and Ministerio de Economia y Competividad (MAT2017-89239-C2-(1,2)-P, MAT2017-83631-C3-3-R and MAT2017-86453-R) is acknowledged.Royal Society of ChemistryUniversidad de Cantabria20222022-12-01journal articlehttp://purl.org/coar/resource_type/c_6501NAhttp://purl.org/coar/version/c_be7fb7dd8ff6fe43info:eu-repo/semantics/articlehttps://hdl.handle.net/10902/31976CrystEngComm, 2022, 25(4), 579-592reponame:UCrea Repositorio Abierto de la Universidad de Cantabriainstname:Universidad de Cantabria (UC)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial 4.0 Internationalhttp://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccessoai:repositorio.unican.es:10902/319762026-06-02T12:39:31Z
dc.title.none.fl_str_mv Tailoring the physical properties of hybrid magnetic quinuclidine-based plastic compounds via weak interactions
title Tailoring the physical properties of hybrid magnetic quinuclidine-based plastic compounds via weak interactions
spellingShingle Tailoring the physical properties of hybrid magnetic quinuclidine-based plastic compounds via weak interactions
González Izquierdo, Palmerina
title_short Tailoring the physical properties of hybrid magnetic quinuclidine-based plastic compounds via weak interactions
title_full Tailoring the physical properties of hybrid magnetic quinuclidine-based plastic compounds via weak interactions
title_fullStr Tailoring the physical properties of hybrid magnetic quinuclidine-based plastic compounds via weak interactions
title_full_unstemmed Tailoring the physical properties of hybrid magnetic quinuclidine-based plastic compounds via weak interactions
title_sort Tailoring the physical properties of hybrid magnetic quinuclidine-based plastic compounds via weak interactions
dc.creator.none.fl_str_mv González Izquierdo, Palmerina
Pedro del Valle, Imanol de|||0000-0002-5581-2220
Cañadillas-Delgado, Laura
Beobide, Garikoitz
Vallcorba, Oriol
Sánchez-Andújar, Manuel
Fernández-Díaz, María Teresa
Rodríguez Fernández, Jesús|||0000-0002-4046-2969
Fabelo, Oscar
author González Izquierdo, Palmerina
author_facet González Izquierdo, Palmerina
Pedro del Valle, Imanol de|||0000-0002-5581-2220
Cañadillas-Delgado, Laura
Beobide, Garikoitz
Vallcorba, Oriol
Sánchez-Andújar, Manuel
Fernández-Díaz, María Teresa
Rodríguez Fernández, Jesús|||0000-0002-4046-2969
Fabelo, Oscar
author_role author
author2 Pedro del Valle, Imanol de|||0000-0002-5581-2220
Cañadillas-Delgado, Laura
Beobide, Garikoitz
Vallcorba, Oriol
Sánchez-Andújar, Manuel
Fernández-Díaz, María Teresa
Rodríguez Fernández, Jesús|||0000-0002-4046-2969
Fabelo, Oscar
author2_role author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Universidad de Cantabria
description Herein we explore the opportunities arising from combining bicyclic amine cations with halometallate anions to build organic-inorganic hybrid materials. We will use the crystal engineering approach in these materials, focusing on the tuning of the organic cation, which is mainly responsible for obtaining both new plastic states at high temperature and electrical behaviour below the plastic temperature. Precisely, this work explores the influence of the ketonization of the bicyclic quinuclidine molecule (C7H13N)+, which, combined with the tetrachloroferrate(1-) anion, gives the compound (3-oxoquinuclidinium)[FeCl4]. Interestingly, crystallization in the presence of humidity is enough to obtain an isostructural hydrate phase of formula (3-oxoquinuclidinium)[FeCl4]·H2O. Although the organic-inorganic layered structure is the same in both compounds, the three-dimensional magnetic ordering disappears after the intercalation of crystallization water molecules. A heat treatment above 400 K allows the removal of water obtaining the non-hydrate phase. Finally, the temperature evolution of the electric and magnetic behaviour will be compared with other previously reported hybrid organic-inorganic materials built with tetrachloroferrate ions and quinuclidinium-based cations.
publishDate 2022
dc.date.none.fl_str_mv 2022
2022-12-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
NA
http://purl.org/coar/version/c_be7fb7dd8ff6fe43
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/10902/31976
url https://hdl.handle.net/10902/31976
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial 4.0 International
http://creativecommons.org/licenses/by-nc/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial 4.0 International
http://creativecommons.org/licenses/by-nc/4.0/
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv CrystEngComm, 2022, 25(4), 579-592
reponame:UCrea Repositorio Abierto de la Universidad de Cantabria
instname:Universidad de Cantabria (UC)
instname_str Universidad de Cantabria (UC)
reponame_str UCrea Repositorio Abierto de la Universidad de Cantabria
collection UCrea Repositorio Abierto de la Universidad de Cantabria
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,300719

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