Palladium-Nanoparticles Biohybrids in Applied Chemistry
Applied nanotechnology has experienced tremendous advance over the last decade. In this study, the efficient synthesis of highly stable palladium-nanoparticles (PdNPs) biohybrids based on the application of an enzyme, which induces in situ the generation of spherical nanoparticles on the protein net...
| Autores: | , , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2020 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/227841 |
| Acceso en línea: | http://hdl.handle.net/10261/227841 |
| Access Level: | acceso abierto |
| Palabra clave: | Palladium-nanoparticles Biohybrids Heterogeneus catalysis |
| Sumario: | Applied nanotechnology has experienced tremendous advance over the last decade. In this study, the efficient synthesis of highly stable palladium-nanoparticles (PdNPs) biohybrids based on the application of an enzyme, which induces in situ the generation of spherical nanoparticles on the protein network, has been described. A heterogeneous material was synthesized formed with PdNPs with average sizes between 1.5 to 5 nm. These Pd nanocatalysts were successfully applied in different chemical processes: C-C bonding reactions (Suzuki and Heck reactions) and cascade processes combining enzymatic and metallic activities (hydrolysis-reduction, esterification-racemization). |
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