Supercritical fluid extraction of emulsions to nanoencapsulate vitamin E in polycaprolactone

Supercritical fluid extraction of emulsions (SFEE) was used to encapsulate a liquid lipophilic compound, concretely vitamin E in polycaprolactone. The influence of the initial formulation on the characteristics of the nanoparticles (encapsulation efficiency, particle size distribution, and morpholog...

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Detalles Bibliográficos
Autores: Prieto López, Cristina, Calvo, Lourdes
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2016
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/378952
Acceso en línea:http://hdl.handle.net/10261/378952
https://api.elsevier.com/content/abstract/scopus_id/84992695914
Access Level:acceso abierto
Palabra clave:Encapsulation
Nanocapsules
Polycaprolactone
Supercritical fluid extraction of emulsions
Vitamin E
Descripción
Sumario:Supercritical fluid extraction of emulsions (SFEE) was used to encapsulate a liquid lipophilic compound, concretely vitamin E in polycaprolactone. The influence of the initial formulation on the characteristics of the nanoparticles (encapsulation efficiency, particle size distribution, and morphology) was studied. The obtained particles exhibited a high encapsulation efficiency (around 90%), narrow particle size distribution (polydispersity index between 0.24 and 0.54), and nanoscale particle sizes (between 8 and 276 nm). The morphological analysis indicated that the particles were spherical, with a core-shell structure, and non-aggregated. Operating at 8 MPa and 313 K, with a CO2 flow rate of 7.2 kg h−1 kg emulsion−1, a low residual concentration of organic solvent (50 ppm) was obtained in 240 min at a CO2 consumption of 101 kg CO2 kg acetone−1. Stability tests indicated that the capsules remained unchanged over long storage periods (6 and 12 months).