Organic solvent-free fabrication of thin film polyamide/zeolitic imidazolate framework membranes for removal of dyes from water

Thin film composite (TFC) polyamide (PA) membranes in combination with zeolitic imidazolate frameworks (ZIF), such as ZIF-8 and ZIF-93, have been fabricated using a novel approach based on vapor phase interfacial polymerization (VIP). These membranes have been investigated for nanofiltration (NF) of...

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Autores: Luque-Alled, José Miguel, Martínez-Izquierdo, Lidia, Gorgojo, Patricia, Téllez, Carlos, Coronas, Joaquín
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2023
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/337744
Acceso en línea:http://hdl.handle.net/10261/337744
Access Level:acceso abierto
Palabra clave:Thin film nanocomposite membrane
Polyamide
Zeolitic imidazolate framework
Water nanofiltration
Dye removal
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spelling Organic solvent-free fabrication of thin film polyamide/zeolitic imidazolate framework membranes for removal of dyes from waterLuque-Alled, José MiguelMartínez-Izquierdo, LidiaGorgojo, PatriciaTéllez, CarlosCoronas, JoaquínThin film nanocomposite membranePolyamideZeolitic imidazolate frameworkWater nanofiltrationDye removalThin film composite (TFC) polyamide (PA) membranes in combination with zeolitic imidazolate frameworks (ZIF), such as ZIF-8 and ZIF-93, have been fabricated using a novel approach based on vapor phase interfacial polymerization (VIP). These membranes have been investigated for nanofiltration (NF) of aqueous solutions of organic dyes, such as Rose Bengal (RB, 1017 Da), Sunset Yellow (SY, 452 Da) and Acridine Orange (AO, 265 Da). The preparation of the PA layer by VIP technique avoids the use of any organic solvent that is typically required in the conventional PA synthesis. Both ZIF-8 and ZIF-93 were initially synthesized using conventional procedures (methanol-based route) and incorporated to the PA layer in two different configurations: i) thin film nanocomposite with ZIF embedded within the PA film, and ii) bilayer membranes with a layer of ZIF between the support and the PA layer. The synthesis of ZIF-93 using a water-based route was developed for the bilayer configuration allowing for an organic solvent-free fabrication of PA/ZIF-93 bilayer VIP-TFC. These membranes showed the highest water permeances of 2.6, 3.4 and 2.2 L m-2h−1 bar−1 for RB, SY and AO, respectively. As compared to the control membrane VIP-TFC, this represents permeance increases of 69–117% and maintains high (greater than 99%) rejection of all the organic dyes. Membrane characterization demonstrated that the permeance enhancement for bilayer PA/ZIF-93 VIP-TFCs is related to an improved hydrophilicity, higher surface roughness and thinner selective layers. The prepared membranes demonstrated excellent cycle stability, maintaining their initial water permeance and dye rejection throughout 34 h of long-term operation, and being able to operate across the entire pH range studied (pH 3 to 9) without any detrimental effects on performance.This work was supported by Grant PID2019-104009RB-I00 funded by MCIN/AEI/10.13039/501100011033 («Agencia Estatal de Investigación» (AEI) and «Ministerio de Ciencia e Innovación» (MCIN), Spain); Margarita Salas and Juan de la Cierva programmes funded by Spanish Ministerio de Universidades and the European Union-NextGenerationEU Fund; Grant RYC2019-027060-I funded by MICIN/AEI/10.13039/501100011033 and by “ESF Investing in your future”; and financial support from the Aragón Government (Grant T68-23R).Peer reviewedElsevierMinisterio de Ciencia, Innovación y Universidades (España)Agencia Estatal de Investigación (España)Ministerio de Universidades (España)European CommissionGobierno de AragónConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202320232023info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://hdl.handle.net/10261/337744reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-104009RB-I00info:eu-repo/grantAgreement/AEI//RYC2019-027060-IThe underlying dataset has been published as supplementary material of the article in the publisher platform at DOI 10.1016/j.cej.2023.144233https://doi.org/10.1016/j.cej.2023.144233Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3377442026-05-22T06:33:51Z
dc.title.none.fl_str_mv Organic solvent-free fabrication of thin film polyamide/zeolitic imidazolate framework membranes for removal of dyes from water
title Organic solvent-free fabrication of thin film polyamide/zeolitic imidazolate framework membranes for removal of dyes from water
spellingShingle Organic solvent-free fabrication of thin film polyamide/zeolitic imidazolate framework membranes for removal of dyes from water
Luque-Alled, José Miguel
Thin film nanocomposite membrane
Polyamide
Zeolitic imidazolate framework
Water nanofiltration
Dye removal
title_short Organic solvent-free fabrication of thin film polyamide/zeolitic imidazolate framework membranes for removal of dyes from water
title_full Organic solvent-free fabrication of thin film polyamide/zeolitic imidazolate framework membranes for removal of dyes from water
title_fullStr Organic solvent-free fabrication of thin film polyamide/zeolitic imidazolate framework membranes for removal of dyes from water
title_full_unstemmed Organic solvent-free fabrication of thin film polyamide/zeolitic imidazolate framework membranes for removal of dyes from water
title_sort Organic solvent-free fabrication of thin film polyamide/zeolitic imidazolate framework membranes for removal of dyes from water
dc.creator.none.fl_str_mv Luque-Alled, José Miguel
Martínez-Izquierdo, Lidia
Gorgojo, Patricia
Téllez, Carlos
Coronas, Joaquín
author Luque-Alled, José Miguel
author_facet Luque-Alled, José Miguel
Martínez-Izquierdo, Lidia
Gorgojo, Patricia
Téllez, Carlos
Coronas, Joaquín
author_role author
author2 Martínez-Izquierdo, Lidia
Gorgojo, Patricia
Téllez, Carlos
Coronas, Joaquín
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Ministerio de Ciencia, Innovación y Universidades (España)
Agencia Estatal de Investigación (España)
Ministerio de Universidades (España)
European Commission
Gobierno de Aragón
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Thin film nanocomposite membrane
Polyamide
Zeolitic imidazolate framework
Water nanofiltration
Dye removal
topic Thin film nanocomposite membrane
Polyamide
Zeolitic imidazolate framework
Water nanofiltration
Dye removal
description Thin film composite (TFC) polyamide (PA) membranes in combination with zeolitic imidazolate frameworks (ZIF), such as ZIF-8 and ZIF-93, have been fabricated using a novel approach based on vapor phase interfacial polymerization (VIP). These membranes have been investigated for nanofiltration (NF) of aqueous solutions of organic dyes, such as Rose Bengal (RB, 1017 Da), Sunset Yellow (SY, 452 Da) and Acridine Orange (AO, 265 Da). The preparation of the PA layer by VIP technique avoids the use of any organic solvent that is typically required in the conventional PA synthesis. Both ZIF-8 and ZIF-93 were initially synthesized using conventional procedures (methanol-based route) and incorporated to the PA layer in two different configurations: i) thin film nanocomposite with ZIF embedded within the PA film, and ii) bilayer membranes with a layer of ZIF between the support and the PA layer. The synthesis of ZIF-93 using a water-based route was developed for the bilayer configuration allowing for an organic solvent-free fabrication of PA/ZIF-93 bilayer VIP-TFC. These membranes showed the highest water permeances of 2.6, 3.4 and 2.2 L m-2h−1 bar−1 for RB, SY and AO, respectively. As compared to the control membrane VIP-TFC, this represents permeance increases of 69–117% and maintains high (greater than 99%) rejection of all the organic dyes. Membrane characterization demonstrated that the permeance enhancement for bilayer PA/ZIF-93 VIP-TFCs is related to an improved hydrophilicity, higher surface roughness and thinner selective layers. The prepared membranes demonstrated excellent cycle stability, maintaining their initial water permeance and dye rejection throughout 34 h of long-term operation, and being able to operate across the entire pH range studied (pH 3 to 9) without any detrimental effects on performance.
publishDate 2023
dc.date.none.fl_str_mv 2023
2023
2023
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/337744
url http://hdl.handle.net/10261/337744
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-104009RB-I00
info:eu-repo/grantAgreement/AEI//RYC2019-027060-I
The underlying dataset has been published as supplementary material of the article in the publisher platform at DOI 10.1016/j.cej.2023.144233
https://doi.org/10.1016/j.cej.2023.144233
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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