A Luminescent heteronuclear cluster featuring an unusual Cu6 boat-shaped core assembled by two dialkynylcycloplatinated units

The synthesis and the structure of a luminescent octanuclear 2-pyridylethynyl cluster [Pt2Cu6(bzq)2(C=C- C5H4N-2)6I2] (1) is reported. An X-ray diffraction study of 1 reveals an unusual Pt2Cu6 species formed by a central dicationic hexanuclear copper(I) core [Cu 6(C=C-C5H4N-2)2I2] 2+ assembled by tw...

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Detalhes bibliográficos
Autores: Díez, Á., García, A. [0000-0002-8792-872X], Lalinde, E. [0000-0001-7402-1742], Moreno, M.T. [0000-0002-7744-9805]
Tipo de documento: artigo
Estado:Versão publicada
Data de publicação:2009
País:España
Recursos:Universidad de La Rioja (UR)
Repositório:RIUR. Repositorio Institucional de la Universidad de La Rioja
OAI Identifier:oai:portal.dialnet.es:doc/5bbc694fb750603269e818cd
Acesso em linha:https://investigacion.unirioja.es/documentos/5bbc694fb750603269e818cd
Access Level:Acceso aberto
Palavra-chave:Alkynyl ligands
Cluster compounds
Copper
Luminescence
Metal-metal interactions
Platinum
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repository_id_str
spelling A Luminescent heteronuclear cluster featuring an unusual Cu6 boat-shaped core assembled by two dialkynylcycloplatinated unitsDíez, Á.García, A. [0000-0002-8792-872X]Lalinde, E. [0000-0001-7402-1742]Moreno, M.T. [0000-0002-7744-9805]Alkynyl ligandsCluster compoundsCopperLuminescenceMetal-metal interactionsPlatinumThe synthesis and the structure of a luminescent octanuclear 2-pyridylethynyl cluster [Pt2Cu6(bzq)2(C=C- C5H4N-2)6I2] (1) is reported. An X-ray diffraction study of 1 reveals an unusual Pt2Cu6 species formed by a central dicationic hexanuclear copper(I) core [Cu 6(C=C-C5H4N-2)2I2] 2+ assembled by two monoanionic benzoquinolinate dialkynylplatinate(II) [Pt(bzq)(C=C-C5H4N-2) 2]- fragments. Solid-state and solution photoluminescence properties at 298 K and at 77 K are discussed in the context of the structure. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.2009info:eu-repo/semantics/articleSubtype: Articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://investigacion.unirioja.es/documentos/5bbc694fb750603269e818cdreponame:RIUR. Repositorio Institucional de la Universidad de La Riojainstname:Universidad de La Rioja (UR)Inglésinfo:eu-repo/semantics/altIdentifier/doi/10.1002/EJIC.200900413info:eu-repo/semantics/altIdentifier/wos/WOS:000268627500003info:eu-repo/semantics/altIdentifier/pissn/1434-1948A Luminescent heteronuclear cluster featuring an unusual Cu6 boat-shaped core assembled by two dialkynylcycloplatinated units, 2009, vol. 21, pág. 3060-3066info:eu-repo/semantics/openAccessoai:portal.dialnet.es:doc/5bbc694fb750603269e818cd2026-06-14T12:47:17Z
dc.title.none.fl_str_mv A Luminescent heteronuclear cluster featuring an unusual Cu6 boat-shaped core assembled by two dialkynylcycloplatinated units
title A Luminescent heteronuclear cluster featuring an unusual Cu6 boat-shaped core assembled by two dialkynylcycloplatinated units
spellingShingle A Luminescent heteronuclear cluster featuring an unusual Cu6 boat-shaped core assembled by two dialkynylcycloplatinated units
Díez, Á.
Alkynyl ligands
Cluster compounds
Copper
Luminescence
Metal-metal interactions
Platinum
title_short A Luminescent heteronuclear cluster featuring an unusual Cu6 boat-shaped core assembled by two dialkynylcycloplatinated units
title_full A Luminescent heteronuclear cluster featuring an unusual Cu6 boat-shaped core assembled by two dialkynylcycloplatinated units
title_fullStr A Luminescent heteronuclear cluster featuring an unusual Cu6 boat-shaped core assembled by two dialkynylcycloplatinated units
title_full_unstemmed A Luminescent heteronuclear cluster featuring an unusual Cu6 boat-shaped core assembled by two dialkynylcycloplatinated units
title_sort A Luminescent heteronuclear cluster featuring an unusual Cu6 boat-shaped core assembled by two dialkynylcycloplatinated units
dc.creator.none.fl_str_mv Díez, Á.
García, A. [0000-0002-8792-872X]
Lalinde, E. [0000-0001-7402-1742]
Moreno, M.T. [0000-0002-7744-9805]
author Díez, Á.
author_facet Díez, Á.
García, A. [0000-0002-8792-872X]
Lalinde, E. [0000-0001-7402-1742]
Moreno, M.T. [0000-0002-7744-9805]
author_role author
author2 García, A. [0000-0002-8792-872X]
Lalinde, E. [0000-0001-7402-1742]
Moreno, M.T. [0000-0002-7744-9805]
author2_role author
author
author
dc.subject.none.fl_str_mv Alkynyl ligands
Cluster compounds
Copper
Luminescence
Metal-metal interactions
Platinum
topic Alkynyl ligands
Cluster compounds
Copper
Luminescence
Metal-metal interactions
Platinum
description The synthesis and the structure of a luminescent octanuclear 2-pyridylethynyl cluster [Pt2Cu6(bzq)2(C=C- C5H4N-2)6I2] (1) is reported. An X-ray diffraction study of 1 reveals an unusual Pt2Cu6 species formed by a central dicationic hexanuclear copper(I) core [Cu 6(C=C-C5H4N-2)2I2] 2+ assembled by two monoanionic benzoquinolinate dialkynylplatinate(II) [Pt(bzq)(C=C-C5H4N-2) 2]- fragments. Solid-state and solution photoluminescence properties at 298 K and at 77 K are discussed in the context of the structure. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
publishDate 2009
dc.date.none.fl_str_mv 2009
dc.type.none.fl_str_mv info:eu-repo/semantics/article
Subtype: Article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://investigacion.unirioja.es/documentos/5bbc694fb750603269e818cd
url https://investigacion.unirioja.es/documentos/5bbc694fb750603269e818cd
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/EJIC.200900413
info:eu-repo/semantics/altIdentifier/wos/WOS:000268627500003
info:eu-repo/semantics/altIdentifier/pissn/1434-1948
A Luminescent heteronuclear cluster featuring an unusual Cu6 boat-shaped core assembled by two dialkynylcycloplatinated units, 2009, vol. 21, pág. 3060-3066
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:RIUR. Repositorio Institucional de la Universidad de La Rioja
instname:Universidad de La Rioja (UR)
instname_str Universidad de La Rioja (UR)
reponame_str RIUR. Repositorio Institucional de la Universidad de La Rioja
collection RIUR. Repositorio Institucional de la Universidad de La Rioja
repository.name.fl_str_mv
repository.mail.fl_str_mv
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