Electrochemical detection of the L-cysteine using a carbon paste electrode modified with a conjugate of tetraamino cobalt (II) pthalocyanine and gold nanoparticles

Gold nanoparticles protected with a mixture of hexanothiol and MUA (11-mercaptoundecanoic acid) (AuNP1) were reacted with Co(II) tetraaminophtalocyanine (CoTAPc). The resulting nanoparticles formed via covalent bonds, AuNP2, were characterized by absorption spectra, infrared spectroscopy and transmi...

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Detalles Bibliográficos
Autores: Friederici, Mario, Angurell Purroy, Inmaculada, Rosell, Oriol, Seco García, Miquel Angel, Muller, Carlos, Llorca Piqué, Jordi|||0000-0002-7447-9582
Tipo de recurso: artículo
Fecha de publicación:2015
País:España
Institución:Universitat Politècnica de Catalunya (UPC)
Repositorio:UPCommons. Portal del coneixement obert de la UPC
Idioma:inglés
OAI Identifier:oai:upcommons.upc.edu:2117/83131
Acceso en línea:https://hdl.handle.net/2117/83131
Access Level:acceso abierto
Palabra clave:Electrochemistry
Nanoparticles
Electroquímica
Nanopartícules
Àrees temàtiques de la UPC::Enginyeria química::Química física::Electroquímica
Descripción
Sumario:Gold nanoparticles protected with a mixture of hexanothiol and MUA (11-mercaptoundecanoic acid) (AuNP1) were reacted with Co(II) tetraaminophtalocyanine (CoTAPc). The resulting nanoparticles formed via covalent bonds, AuNP2, were characterized by absorption spectra, infrared spectroscopy and transmission electron microscopy. Modified carbon paste electrodes were prepared with AuNP1, CoTAPc and AuNP2 and evaluated for electrochemical detection of L-cysteine by cyclic voltammetry. Sensing of L-cysteine was uniquely observed with the electrode modified with AuNP2