Interfacial engineering of metal oxides for highly stable halide perovskite solar cells

Oxides employed in halide perovskite solar cells (PSCs) have already demonstrated to deliver enhanced stability, low cost, and the ease of fabrication required for the commercialization of the technology. The most stable PSCs configuration, the carbon-based hole transport layer-free PSC (HTL-free PS...

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Autores: Mingorance, Alba, Xie, Haibing|||0000-0002-5070-2882, Kim, Hui-Seon|||0000-0002-9928-3033, Wang, Zaiwei, Balsells, Marc|||0000-0001-6475-1514, Morales Melgares, Anna, Domingo Marimon, Neus|||0000-0002-5229-6638, Kazuteru, Nonomura, Tress, Wolfgang, Fraxedas, Jordi|||0000-0002-2821-4831, Vlachopoulos, Nick, Hagfeldt, Anders|||0000-0001-6725-8856, Lira-Cantu, Monica|||0000-0002-3393-7436
Tipo de recurso: artículo
Fecha de publicación:2018
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:239270
Acceso en línea:https://ddd.uab.cat/record/239270
https://dx.doi.org/urn:doi:10.1002/admi.201800367
Access Level:acceso abierto
Palabra clave:Functionalization
Halide perovskite solar cells
Interfacial engineering
Metal oxides
Self-assembly monolayers
Stability
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spelling Interfacial engineering of metal oxides for highly stable halide perovskite solar cellsMingorance, AlbaXie, Haibing|||0000-0002-5070-2882Kim, Hui-Seon|||0000-0002-9928-3033Wang, ZaiweiBalsells, Marc|||0000-0001-6475-1514Morales Melgares, AnnaDomingo Marimon, Neus|||0000-0002-5229-6638Kazuteru, NonomuraTress, WolfgangFraxedas, Jordi|||0000-0002-2821-4831Vlachopoulos, NickHagfeldt, Anders|||0000-0001-6725-8856Lira-Cantu, Monica|||0000-0002-3393-7436FunctionalizationHalide perovskite solar cellsInterfacial engineeringMetal oxidesSelf-assembly monolayersStabilityOxides employed in halide perovskite solar cells (PSCs) have already demonstrated to deliver enhanced stability, low cost, and the ease of fabrication required for the commercialization of the technology. The most stable PSCs configuration, the carbon-based hole transport layer-free PSC (HTL-free PSC), has demonstrated a stability of more than one year of continuous operation partially due to the dual presence of insulating oxide scaffolds and conductive oxides. Despite these advances, the stability of PSCs is still a concern and a strong limiting factor for their industrial implementation. The engineering of oxide interfaces functionalized with molecules (like self-assembly monolayers) or polymers results in the passivation of defects (traps), providing numerous advantages such as the elimination of hysteresis and the enhancement of solar cell efficiency. But most important is the beneficial effect of interfacial engineering on the lifetime and stability of PSCs. In this work, the authors provide a brief insight into the recent developments reported on the surface functionalization of oxide interfaces in PSCs with emphasis on the effect of device stability. This paper also discusses the different binding modes, their effect on defect passivation, band alignment or dipole formation, and how these parameters influence device lifetime. 22018-01-0120182018-01-01Articlehttp://purl.org/coar/resource_type/c_6501SMURhttp://purl.org/coar/version/c_71e4c1898caa6e32info:eu-repo/semantics/articleapplication/pdfhttps://ddd.uab.cat/record/239270https://dx.doi.org/urn:doi:10.1002/admi.201800367reponame:Dipòsit Digital de Documents de la UABinstname:Universitat Autònoma de BarcelonaInglésengMinisterio de Economía y Competitividad https://doi.org/10.13039/501100003329 SEV-2013-0295Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 ENE2016-79282-C5-2-RMinisterio de Economía y Competitividad https://doi.org/10.13039/501100003329 CTQ2016-81911-REDTAgència de Gestió d'Ajuts Universitaris i de Recerca https://doi.org/10.13039/501100003030 2017/SGR-329open accesshttp://purl.org/coar/access_right/c_abf2Aquest material està protegit per drets d'autor i/o drets afins. Podeu utilitzar aquest material en funció del que permet la legislació de drets d'autor i drets afins d'aplicació al vostre cas. Per a d'altres usos heu d'obtenir permís del(s) titular(s) de drets.https://rightsstatements.org/vocab/InC/1.0/info:eu-repo/semantics/openAccessoai:ddd.uab.cat:2392702026-06-06T12:50:31Z
dc.title.none.fl_str_mv Interfacial engineering of metal oxides for highly stable halide perovskite solar cells
title Interfacial engineering of metal oxides for highly stable halide perovskite solar cells
spellingShingle Interfacial engineering of metal oxides for highly stable halide perovskite solar cells
Mingorance, Alba
Functionalization
Halide perovskite solar cells
Interfacial engineering
Metal oxides
Self-assembly monolayers
Stability
title_short Interfacial engineering of metal oxides for highly stable halide perovskite solar cells
title_full Interfacial engineering of metal oxides for highly stable halide perovskite solar cells
title_fullStr Interfacial engineering of metal oxides for highly stable halide perovskite solar cells
title_full_unstemmed Interfacial engineering of metal oxides for highly stable halide perovskite solar cells
title_sort Interfacial engineering of metal oxides for highly stable halide perovskite solar cells
dc.creator.none.fl_str_mv Mingorance, Alba
Xie, Haibing|||0000-0002-5070-2882
Kim, Hui-Seon|||0000-0002-9928-3033
Wang, Zaiwei
Balsells, Marc|||0000-0001-6475-1514
Morales Melgares, Anna
Domingo Marimon, Neus|||0000-0002-5229-6638
Kazuteru, Nonomura
Tress, Wolfgang
Fraxedas, Jordi|||0000-0002-2821-4831
Vlachopoulos, Nick
Hagfeldt, Anders|||0000-0001-6725-8856
Lira-Cantu, Monica|||0000-0002-3393-7436
author Mingorance, Alba
author_facet Mingorance, Alba
Xie, Haibing|||0000-0002-5070-2882
Kim, Hui-Seon|||0000-0002-9928-3033
Wang, Zaiwei
Balsells, Marc|||0000-0001-6475-1514
Morales Melgares, Anna
Domingo Marimon, Neus|||0000-0002-5229-6638
Kazuteru, Nonomura
Tress, Wolfgang
Fraxedas, Jordi|||0000-0002-2821-4831
Vlachopoulos, Nick
Hagfeldt, Anders|||0000-0001-6725-8856
Lira-Cantu, Monica|||0000-0002-3393-7436
author_role author
author2 Xie, Haibing|||0000-0002-5070-2882
Kim, Hui-Seon|||0000-0002-9928-3033
Wang, Zaiwei
Balsells, Marc|||0000-0001-6475-1514
Morales Melgares, Anna
Domingo Marimon, Neus|||0000-0002-5229-6638
Kazuteru, Nonomura
Tress, Wolfgang
Fraxedas, Jordi|||0000-0002-2821-4831
Vlachopoulos, Nick
Hagfeldt, Anders|||0000-0001-6725-8856
Lira-Cantu, Monica|||0000-0002-3393-7436
author2_role author
author
author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Functionalization
Halide perovskite solar cells
Interfacial engineering
Metal oxides
Self-assembly monolayers
Stability
topic Functionalization
Halide perovskite solar cells
Interfacial engineering
Metal oxides
Self-assembly monolayers
Stability
description Oxides employed in halide perovskite solar cells (PSCs) have already demonstrated to deliver enhanced stability, low cost, and the ease of fabrication required for the commercialization of the technology. The most stable PSCs configuration, the carbon-based hole transport layer-free PSC (HTL-free PSC), has demonstrated a stability of more than one year of continuous operation partially due to the dual presence of insulating oxide scaffolds and conductive oxides. Despite these advances, the stability of PSCs is still a concern and a strong limiting factor for their industrial implementation. The engineering of oxide interfaces functionalized with molecules (like self-assembly monolayers) or polymers results in the passivation of defects (traps), providing numerous advantages such as the elimination of hysteresis and the enhancement of solar cell efficiency. But most important is the beneficial effect of interfacial engineering on the lifetime and stability of PSCs. In this work, the authors provide a brief insight into the recent developments reported on the surface functionalization of oxide interfaces in PSCs with emphasis on the effect of device stability. This paper also discusses the different binding modes, their effect on defect passivation, band alignment or dipole formation, and how these parameters influence device lifetime.
publishDate 2018
dc.date.none.fl_str_mv 2
2018-01-01
2018
2018-01-01
dc.type.none.fl_str_mv Article
http://purl.org/coar/resource_type/c_6501
SMUR
http://purl.org/coar/version/c_71e4c1898caa6e32
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://ddd.uab.cat/record/239270
https://dx.doi.org/urn:doi:10.1002/admi.201800367
url https://ddd.uab.cat/record/239270
https://dx.doi.org/urn:doi:10.1002/admi.201800367
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 SEV-2013-0295
Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 ENE2016-79282-C5-2-R
Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 CTQ2016-81911-REDT
Agència de Gestió d'Ajuts Universitaris i de Recerca https://doi.org/10.13039/501100003030 2017/SGR-329
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://rightsstatements.org/vocab/InC/1.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://rightsstatements.org/vocab/InC/1.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Dipòsit Digital de Documents de la UAB
instname:Universitat Autònoma de Barcelona
instname_str Universitat Autònoma de Barcelona
reponame_str Dipòsit Digital de Documents de la UAB
collection Dipòsit Digital de Documents de la UAB
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