Testing the ability to reduce the leaching of pesticides in soil amended with agro-industrial and composted waste

The retention potential of composted sewage sludge, orujillo (a solid residue from olive oil production), sawdust and sunflower seed shell to prevent soil leaching of atrazine, chlorfenvinphos, and chlorpyrifos was studied in open systems using fixed-bed adsorption columns. The columns were construc...

Descripción completa

Detalles Bibliográficos
Autores: Rojas Rodríguez, Raquel, Morillo Aguado, José, Usero García, José, Álvarez Herrera, C., Repetto, Guillermo
Tipo de recurso: artículo
Fecha de publicación:2026
País:España
Institución:Universidad Pablo de Olavide (UPO)
Repositorio:RIO. Repositorio Institucional Olavide
Idioma:inglés
OAI Identifier:oai:dnet:rio_________::2cfcf6a99d35984f4456b2359f242a8a
Acceso en línea:https://hdl.handle.net/10433/26419
Access Level:acceso abierto
Palabra clave:Pesticides
Leaching of pesticides
Organic amendment
Organic waste
id ES_bb4658ec00aea1c7d1c4a20455b6cb9c
oai_identifier_str oai:dnet:rio_________::2cfcf6a99d35984f4456b2359f242a8a
network_acronym_str ES
network_name_str España
repository_id_str
spelling Testing the ability to reduce the leaching of pesticides in soil amended with agro-industrial and composted wasteRojas Rodríguez, RaquelMorillo Aguado, JoséUsero García, JoséÁlvarez Herrera, C.Repetto, GuillermoPesticidesLeaching of pesticidesOrganic amendmentOrganic wasteThe retention potential of composted sewage sludge, orujillo (a solid residue from olive oil production), sawdust and sunflower seed shell to prevent soil leaching of atrazine, chlorfenvinphos, and chlorpyrifos was studied in open systems using fixed-bed adsorption columns. The columns were constructed from soil and the soil was amended with 10% of the organic waste cited. Pesticides were applied, and columns were subjected to simulated rainfall. Breakthrough and cumulative curves were built from pesticides detected each day in leachates, as % of applied. Our analysis reveals that the effectiveness of these amendments is not universal; it depends critically on the molecular structure of the pesticides and how it interacts with the physicochemical properties of the amendments and the soil. Orujillo emerged as the most broadly effective amendment, reducing elution peaks by up to 7.6-fold for chlorfenvinphos and significantly delaying atrazine breakthrough via lignin partitioning. Exploratory multiparametric and LASSO regression analyses identified oxygen content (%) and calcium (%) as the most influential properties controlling distribution coefficients and cumulative leaching. Furthermore, we found that amended soils require significantly greater irrigation volumes to reach equilibrium, providing a “resilience factor” against extreme rainfall events. Discrepancies between batch and column results highlight that laboratory-derived constants often fail to predict leaching under dynamic flow conditions.Elsevier Ltd20262026-03-3120262026-03-1520262026-03-15journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/10433/26419reponame:RIO. Repositorio Institucional Olavideinstname:Universidad Pablo de Olavide (UPO)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Attribution 4.0 Internationalhttp://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessoai:dnet:rio_________::2cfcf6a99d35984f4456b2359f242a8a2026-06-13T12:46:27Z
dc.title.none.fl_str_mv Testing the ability to reduce the leaching of pesticides in soil amended with agro-industrial and composted waste
title Testing the ability to reduce the leaching of pesticides in soil amended with agro-industrial and composted waste
spellingShingle Testing the ability to reduce the leaching of pesticides in soil amended with agro-industrial and composted waste
Rojas Rodríguez, Raquel
Pesticides
Leaching of pesticides
Organic amendment
Organic waste
title_short Testing the ability to reduce the leaching of pesticides in soil amended with agro-industrial and composted waste
title_full Testing the ability to reduce the leaching of pesticides in soil amended with agro-industrial and composted waste
title_fullStr Testing the ability to reduce the leaching of pesticides in soil amended with agro-industrial and composted waste
title_full_unstemmed Testing the ability to reduce the leaching of pesticides in soil amended with agro-industrial and composted waste
title_sort Testing the ability to reduce the leaching of pesticides in soil amended with agro-industrial and composted waste
dc.creator.none.fl_str_mv Rojas Rodríguez, Raquel
Morillo Aguado, José
Usero García, José
Álvarez Herrera, C.
Repetto, Guillermo
author Rojas Rodríguez, Raquel
author_facet Rojas Rodríguez, Raquel
Morillo Aguado, José
Usero García, José
Álvarez Herrera, C.
Repetto, Guillermo
author_role author
author2 Morillo Aguado, José
Usero García, José
Álvarez Herrera, C.
Repetto, Guillermo
author2_role author
author
author
author
dc.contributor.none.fl_str_mv
dc.subject.none.fl_str_mv Pesticides
Leaching of pesticides
Organic amendment
Organic waste
topic Pesticides
Leaching of pesticides
Organic amendment
Organic waste
description The retention potential of composted sewage sludge, orujillo (a solid residue from olive oil production), sawdust and sunflower seed shell to prevent soil leaching of atrazine, chlorfenvinphos, and chlorpyrifos was studied in open systems using fixed-bed adsorption columns. The columns were constructed from soil and the soil was amended with 10% of the organic waste cited. Pesticides were applied, and columns were subjected to simulated rainfall. Breakthrough and cumulative curves were built from pesticides detected each day in leachates, as % of applied. Our analysis reveals that the effectiveness of these amendments is not universal; it depends critically on the molecular structure of the pesticides and how it interacts with the physicochemical properties of the amendments and the soil. Orujillo emerged as the most broadly effective amendment, reducing elution peaks by up to 7.6-fold for chlorfenvinphos and significantly delaying atrazine breakthrough via lignin partitioning. Exploratory multiparametric and LASSO regression analyses identified oxygen content (%) and calcium (%) as the most influential properties controlling distribution coefficients and cumulative leaching. Furthermore, we found that amended soils require significantly greater irrigation volumes to reach equilibrium, providing a “resilience factor” against extreme rainfall events. Discrepancies between batch and column results highlight that laboratory-derived constants often fail to predict leaching under dynamic flow conditions.
publishDate 2026
dc.date.none.fl_str_mv 2026
2026-03-31
2026
2026-03-15
2026
2026-03-15
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/10433/26419
url https://hdl.handle.net/10433/26419
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution 4.0 International
http://creativecommons.org/licenses/by/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution 4.0 International
http://creativecommons.org/licenses/by/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier Ltd
publisher.none.fl_str_mv Elsevier Ltd
dc.source.none.fl_str_mv reponame:RIO. Repositorio Institucional Olavide
instname:Universidad Pablo de Olavide (UPO)
instname_str Universidad Pablo de Olavide (UPO)
reponame_str RIO. Repositorio Institucional Olavide
collection RIO. Repositorio Institucional Olavide
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869418011133214720
score 15,811543

Similares en LA Referencia