Enhanced open-circuit voltage in perovskite solar cells with open-cage [60]fullerene derivatives as electron-transporting materials

The synthesis, characterization, and incorporation of open-cage [60]fullerene derivatives as electron-transporting materials (ETMs) in perovskite solar cells (PSCs) with an inverted planar (p-i-n) structure is reported. Following optical and electrochemical characterization of the open-cage fulleren...

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Autores: Castro, Edison, Artigas Ruf, Albert, Pla i Quintana, Anna, Roglans i Ribas, Anna, Liu, Fang, Pérez, Frank, Lledó Ponsati, Agustí, Zhu, X.Y., Echegoyen, Luis A.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2019
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:10256/16561
Acceso en línea:http://hdl.handle.net/10256/16561
Access Level:acceso abierto
Palabra clave:Ful·lerens
Materials nanoestructurats
Catàlisi
Cèl·lules solars
Fullerenes
Nanostructured materials
Catalysis
Solar cells
Nanotubs
Nanotubes
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spelling Enhanced open-circuit voltage in perovskite solar cells with open-cage [60]fullerene derivatives as electron-transporting materialsCastro, EdisonArtigas Ruf, AlbertPla i Quintana, AnnaRoglans i Ribas, AnnaLiu, FangPérez, FrankLledó Ponsati, AgustíZhu, X.Y.Echegoyen, Luis A.Ful·lerensMaterials nanoestructuratsCatàlisiCèl·lules solarsFullerenesNanostructured materialsCatalysisSolar cellsNanotubsNanotubesCèl·lules solarsSolar cellsThe synthesis, characterization, and incorporation of open-cage [60]fullerene derivatives as electron-transporting materials (ETMs) in perovskite solar cells (PSCs) with an inverted planar (p-i-n) structure is reported. Following optical and electrochemical characterization of the open-cage fullerenes 2a-c, p-i-n PSCs with a indium tin oxide (ITO)/poly(3,4-ethylenedioxythiophene)-polystyrene sulfonate (PEDOT:PSS)/perovskite/fullerene/Ag structure were prepared. The devices obtained from 2a-b exhibit competitive power conversion efficiencies (PCEs) and improved open-circuit voltage (Voc) values (>1.0 V) in comparison to a reference cell based on phenyl-C61-butyric-acid methyl-ester (PC61BM). These results are rationalized in terms of a) the higher passivation ability of the open-cage fullerenes with respect to the other fullerenes, and b) a good overlap between the highest occupied molecular orbital/lowest unoccupied molecular orbital (HOMO/LUMO) levels of 2a-b and the conduction band of the perovskiteMDPI (Multidisciplinary Digital Publishing Institute)Ministerio de Economía y Competitividad (Espanya)2019info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionpeer-reviewedapplication/pdfhttp://hdl.handle.net/10256/16561http://hdl.handle.net/10256/16561Materials, 2019, vol. 12, núm. 8, p. 1314Articles publicats (D-Q)Castro, Edison Artigas Ruf, Albert Pla i Quintana, Anna Roglans i Ribas, Anna Liu, Fang Pérez, Frank Lledó Ponsati, Agustí Zhu, X.Y. Echegoyen, Luis A. 2019 Enhanced open-circuit voltage in perovskite solar cells with open-cage [60]fullerene derivatives as electron-transporting materials Materials 12 8 1314reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)Inglésinfo:eu-repo/semantics/altIdentifier/doi/10.3390/ma12081314info:eu-repo/semantics/altIdentifier/issn/1996-1944info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2017-85341-Pinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2017-83587-PReconeixement 4.0 Internacionalhttp://creativecommons.org/licenses/by/4.0info:eu-repo/semantics/openAccessoai:recercat.cat:10256/165612026-05-29T05:05:01Z
dc.title.none.fl_str_mv Enhanced open-circuit voltage in perovskite solar cells with open-cage [60]fullerene derivatives as electron-transporting materials
title Enhanced open-circuit voltage in perovskite solar cells with open-cage [60]fullerene derivatives as electron-transporting materials
spellingShingle Enhanced open-circuit voltage in perovskite solar cells with open-cage [60]fullerene derivatives as electron-transporting materials
Castro, Edison
Ful·lerens
Materials nanoestructurats
Catàlisi
Cèl·lules solars
Fullerenes
Nanostructured materials
Catalysis
Solar cells
Nanotubs
Nanotubes
Cèl·lules solars
Solar cells
title_short Enhanced open-circuit voltage in perovskite solar cells with open-cage [60]fullerene derivatives as electron-transporting materials
title_full Enhanced open-circuit voltage in perovskite solar cells with open-cage [60]fullerene derivatives as electron-transporting materials
title_fullStr Enhanced open-circuit voltage in perovskite solar cells with open-cage [60]fullerene derivatives as electron-transporting materials
title_full_unstemmed Enhanced open-circuit voltage in perovskite solar cells with open-cage [60]fullerene derivatives as electron-transporting materials
title_sort Enhanced open-circuit voltage in perovskite solar cells with open-cage [60]fullerene derivatives as electron-transporting materials
dc.creator.none.fl_str_mv Castro, Edison
Artigas Ruf, Albert
Pla i Quintana, Anna
Roglans i Ribas, Anna
Liu, Fang
Pérez, Frank
Lledó Ponsati, Agustí
Zhu, X.Y.
Echegoyen, Luis A.
author Castro, Edison
author_facet Castro, Edison
Artigas Ruf, Albert
Pla i Quintana, Anna
Roglans i Ribas, Anna
Liu, Fang
Pérez, Frank
Lledó Ponsati, Agustí
Zhu, X.Y.
Echegoyen, Luis A.
author_role author
author2 Artigas Ruf, Albert
Pla i Quintana, Anna
Roglans i Ribas, Anna
Liu, Fang
Pérez, Frank
Lledó Ponsati, Agustí
Zhu, X.Y.
Echegoyen, Luis A.
author2_role author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Ministerio de Economía y Competitividad (Espanya)
dc.subject.none.fl_str_mv Ful·lerens
Materials nanoestructurats
Catàlisi
Cèl·lules solars
Fullerenes
Nanostructured materials
Catalysis
Solar cells
Nanotubs
Nanotubes
Cèl·lules solars
Solar cells
topic Ful·lerens
Materials nanoestructurats
Catàlisi
Cèl·lules solars
Fullerenes
Nanostructured materials
Catalysis
Solar cells
Nanotubs
Nanotubes
Cèl·lules solars
Solar cells
description The synthesis, characterization, and incorporation of open-cage [60]fullerene derivatives as electron-transporting materials (ETMs) in perovskite solar cells (PSCs) with an inverted planar (p-i-n) structure is reported. Following optical and electrochemical characterization of the open-cage fullerenes 2a-c, p-i-n PSCs with a indium tin oxide (ITO)/poly(3,4-ethylenedioxythiophene)-polystyrene sulfonate (PEDOT:PSS)/perovskite/fullerene/Ag structure were prepared. The devices obtained from 2a-b exhibit competitive power conversion efficiencies (PCEs) and improved open-circuit voltage (Voc) values (>1.0 V) in comparison to a reference cell based on phenyl-C61-butyric-acid methyl-ester (PC61BM). These results are rationalized in terms of a) the higher passivation ability of the open-cage fullerenes with respect to the other fullerenes, and b) a good overlap between the highest occupied molecular orbital/lowest unoccupied molecular orbital (HOMO/LUMO) levels of 2a-b and the conduction band of the perovskite
publishDate 2019
dc.date.none.fl_str_mv 2019
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
peer-reviewed
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10256/16561
http://hdl.handle.net/10256/16561
url http://hdl.handle.net/10256/16561
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.3390/ma12081314
info:eu-repo/semantics/altIdentifier/issn/1996-1944
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2017-85341-P
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2017-83587-P
dc.rights.none.fl_str_mv Reconeixement 4.0 Internacional
http://creativecommons.org/licenses/by/4.0
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Reconeixement 4.0 Internacional
http://creativecommons.org/licenses/by/4.0
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv MDPI (Multidisciplinary Digital Publishing Institute)
publisher.none.fl_str_mv MDPI (Multidisciplinary Digital Publishing Institute)
dc.source.none.fl_str_mv Materials, 2019, vol. 12, núm. 8, p. 1314
Articles publicats (D-Q)
Castro, Edison Artigas Ruf, Albert Pla i Quintana, Anna Roglans i Ribas, Anna Liu, Fang Pérez, Frank Lledó Ponsati, Agustí Zhu, X.Y. Echegoyen, Luis A. 2019 Enhanced open-circuit voltage in perovskite solar cells with open-cage [60]fullerene derivatives as electron-transporting materials Materials 12 8 1314
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869417973421178880
score 15,812429

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