Energy partitioning for "fuzzy" atoms

The total energy of molecule in terms of 'fuzzy atoms' presented as sum of one- and two-atomic energy components is described. The divisions of three-dimensional physical space into atomic regions exhibit continuous transition from one to another. The energy components are on chemical ener...

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Detalles Bibliográficos
Autores: Salvador Sedano, Pedro, Mayer, István
Tipo de recurso: artículo
Fecha de publicación:2004
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:10256/3292
Acceso en línea:http://hdl.handle.net/10256/3292
Access Level:acceso abierto
Palabra clave:Àtoms
Conjunts borrosos
Dinàmica molecular
Física nuclear
Funcional de densitat, Teoria del
Hilbert, Espais de
Orbitals moleculars
Atoms
Density functionals
Fuzzy sets
Hilbert space
Molecular dynamics
Molecular orbitals
Nuclear physics
Descripción
Sumario:The total energy of molecule in terms of 'fuzzy atoms' presented as sum of one- and two-atomic energy components is described. The divisions of three-dimensional physical space into atomic regions exhibit continuous transition from one to another. The energy components are on chemical energy scale according to proper definitions. The Becke's integration scheme and weight function determines realization of method which permits effective numerical integrations