Fabrication of Al2O3-Y3Al5O12-ZrO2 composites by single-step spark plasma sintering

Fabricating Al2O3-Y3Al5O12-ZrO2 ceramic composites with a eutectic microstructure is challenging and costly, as it requires high-temperature melting of precursor materials. Here, we report on the successful production of Al2O3-Y3Al5O12- 5 mol% ZrO2 composites with lamellar eutectic microstructure th...

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Detalhes bibliográficos
Autores: Vakhshouri, Maryam, Talimian, Ali, Najafzadehkhoee, Aliasghar, Gallardo López, Ángela María, Poyato, Rosalía, Gutiérrez Mora, Felipe, Galusek, Dušan
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2025
País:España
Recursos:Universidad de Sevilla (US)
Repositorio:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/174026
Acesso em linha:https://hdl.handle.net/11441/174026
https://doi.org/10.1016/j.jeurceramsoc.2025.117358
Access Level:acceso abierto
Palavra-chave:Al2O3-YAGZrO2
Microstructure
Spark plasma sintering
Descrição
Resumo:Fabricating Al2O3-Y3Al5O12-ZrO2 ceramic composites with a eutectic microstructure is challenging and costly, as it requires high-temperature melting of precursor materials. Here, we report on the successful production of Al2O3-Y3Al5O12- 5 mol% ZrO2 composites with lamellar eutectic microstructure through single-step spark plasma sintering (SPS) of sol-gel synthesized powder. The release of volatile species from partially calcined powders, due to limited calcination at 1000°C for 2 h, as well as their fine particle size, were used to create the conditions for local electric discharge and plasma formation during SPS; this resulted in the local formation of eutectic liquids, enabling the formation of lamellar microstructures. The microstructural features can be tailored by modifying the calcination process.