Chromo-fluorogenic probes for carbon monoxide detection

[EN] The sensing of carbon monoxide (CO) using electrochemical cells or semiconducting metal oxides has led to inexpensive alarms for the home and workplace. It is now recognised that chronic exposure to low levels of CO also poses a significant health risk. It is perhaps surprising therefore that t...

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Detalles Bibliográficos
Autores: Marín-Hernández, Cristina, Toscani, Anita, Wilton-Ely, James D. E. T, Sancenón Galarza, Félix|||0000-0002-5205-7135, Martínez-Máñez, Ramón|||0000-0001-5873-9674
Tipo de recurso: artículo
Fecha de publicación:2016
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/87888
Acceso en línea:https://riunet.upv.es/handle/10251/87888
Access Level:acceso abierto
Palabra clave:BINUCLEAR RHODIUM COMPLEXES
CARBENE COORDINATION CHEMISTRY
TRANSITION-METAL-COMPLEXES
LIVING CELLS
FLUORESCENT-PROBE
CO DETECTION
LIGAND
RUTHENIUM(II)
SENSORS
ETHER
QUIMICA INORGANICA
QUIMICA ORGANICA
QUIMICA ANALITICA
Descripción
Sumario:[EN] The sensing of carbon monoxide (CO) using electrochemical cells or semiconducting metal oxides has led to inexpensive alarms for the home and workplace. It is now recognised that chronic exposure to low levels of CO also poses a significant health risk. It is perhaps surprising therefore that the CO is used in cell-signalling pathways and plays a growing role in therapy. However, the selective monitoring of low levels of CO remains challenging, and it is this area that has benefited from the development of probes which give a colour or fluorescence response. This feature article covers the design of chromofluorogenic probes and their application to CO sensing in air, solution and in cells.