A track record of Au-Ag nanomelt generation during fuid‑mineral interactions

Recent studies have reported the signifcant role of Au-bearing nanoparticles in the formation of hydrothermal gold deposits. Despite the ever-increasing understanding of the genesis and stability of Au-bearing nanoparticles, it is still unknown how they behave when exposed to hydrothermal fuids. Her...

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Detalles Bibliográficos
Autores: Domínguez-Carretero, Diego, González Jiménez, José María, Proenza Fernández, Joaquín Antonio, Villanova de Benavent, Cristina, Llovet Ximenes, Xavier, Garcia-Casco, Antonio
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2023
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2445/208247
Acceso en línea:https://hdl.handle.net/2445/208247
Access Level:acceso abierto
Palabra clave:Or
Jaciments hidrotermals
Jaciments minerals
Gold
Hydrothermal deposits
Mineral deposits
Descripción
Sumario:Recent studies have reported the signifcant role of Au-bearing nanoparticles in the formation of hydrothermal gold deposits. Despite the ever-increasing understanding of the genesis and stability of Au-bearing nanoparticles, it is still unknown how they behave when exposed to hydrothermal fuids. Here, we study the nanostructural evolution of Au–Ag nanoparticles hosted within Co-rich diarsenides and sulfarsenides of a natural hydrothermal deposit. We use high-resolution transmission electron microscopy to provide a singular glimpse of the complete melting sequence of Au–Ag nanoparticles exposed to the hydrothermal fuid during coupled dissolution–precipitation reactions of their host minerals. The interaction of Au–Ag nanoparticles with hydrothermal fuids at temperatures (400– 500 ºC) common to most hydrothermal gold deposits may promote melting and generation of Au–Ag nanomelts. This process has important implications in noble metal remobilization and accumulation during the formation of these deposits.