Group 10 Metal Benzene-1,2-dithiolate Derivatives in the Synthesis of Coordination Polymers Containing Potassium Countercations

This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/abs/10.1...

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Autores: Castillo, Oscar, Delgado, Esther, Gómez-García, Carlos J., Hernández, Diego, Hernández, Elisa, Martín, Avelino, Martínez, José I., Zamora Abanades, Félix Juan
Tipo de recurso: artículo
Fecha de publicación:2017
País:España
Institución:Universidad Autónoma de Madrid
Repositorio:Biblos-e Archivo. Repositorio Institucional de la UAM
Idioma:inglés
OAI Identifier:oai:repositorio.uam.es:10486/688871
Acceso en línea:http://hdl.handle.net/10486/688871
https://dx.doi.org/10.1021/acs.inorgchem.7b01775
Access Level:acceso abierto
Palabra clave:Coordination polymers
Metal-dithiolene polymers
Coordination compounds
First-principles calculations
Química
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spelling Group 10 Metal Benzene-1,2-dithiolate Derivatives in the Synthesis of Coordination Polymers Containing Potassium CountercationsCastillo, OscarDelgado, EstherGómez-García, Carlos J.Hernández, DiegoHernández, ElisaMartín, AvelinoMartínez, José I.Zamora Abanades, Félix JuanCoordination polymersMetal-dithiolene polymersCoordination compoundsFirst-principles calculationsQuímicaThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.7b01775The use of theoretical calculations has allowed us to predict the coordination behavior of dithiolene [M(SC6H4S)2]2- (M = Ni, Pd, Pt) entities, giving rise to the first organometallic polymers {[K2(μ-H2O)2][Ni(SC6H4S)2]}n and {[K2(μ-H2O)2(thf)]2[K2(μ-H2O)2(thf)2][Pd3(SC6H4S)6]}n by one-pot reactions of the corresponding d10 metal salts, 1,2-benzenedithiolene, and KOH. The polymers are based on σ,π interactions between potassium atoms and [M(SC6H4S)2]2- (M = Ni, Pd) entities. In contrast, only σ interactions are observed when the analogous platinum derivative is used instead, yielding the coordination polymer {[K2(μ-thf)2][Pt(SC6H4S)2]}nThis work was supported in part by the MICINN (grants MAT2016-77608-C3-1-P and MAT2016-75883-C2-1-P), Generalitat Valenciana (PrometeoII/2014/076), and ISIC. J.I.M. acknowledges financial support by the “Ramon y Cajal ́ ” Program of MINECO (RYC-2015-17730)American Chemical SocietyDepartamento de Química InorgánicaFacultad de Ciencias20172017-10-02research articlehttp://purl.org/coar/resource_type/c_2df8fbb1AMhttp://purl.org/coar/version/c_ab4af688f83e57aainfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10486/688871https://dx.doi.org/10.1021/acs.inorgchem.7b01775reponame:Biblos-e Archivo. Repositorio Institucional de la UAMinstname:Universidad Autónoma de MadridInglésengopen accesshttp://purl.org/coar/access_right/c_abf2info:eu-repo/semantics/openAccessoai:repositorio.uam.es:10486/6888712026-06-23T12:46:27Z
dc.title.none.fl_str_mv Group 10 Metal Benzene-1,2-dithiolate Derivatives in the Synthesis of Coordination Polymers Containing Potassium Countercations
title Group 10 Metal Benzene-1,2-dithiolate Derivatives in the Synthesis of Coordination Polymers Containing Potassium Countercations
spellingShingle Group 10 Metal Benzene-1,2-dithiolate Derivatives in the Synthesis of Coordination Polymers Containing Potassium Countercations
Castillo, Oscar
Coordination polymers
Metal-dithiolene polymers
Coordination compounds
First-principles calculations
Química
title_short Group 10 Metal Benzene-1,2-dithiolate Derivatives in the Synthesis of Coordination Polymers Containing Potassium Countercations
title_full Group 10 Metal Benzene-1,2-dithiolate Derivatives in the Synthesis of Coordination Polymers Containing Potassium Countercations
title_fullStr Group 10 Metal Benzene-1,2-dithiolate Derivatives in the Synthesis of Coordination Polymers Containing Potassium Countercations
title_full_unstemmed Group 10 Metal Benzene-1,2-dithiolate Derivatives in the Synthesis of Coordination Polymers Containing Potassium Countercations
title_sort Group 10 Metal Benzene-1,2-dithiolate Derivatives in the Synthesis of Coordination Polymers Containing Potassium Countercations
dc.creator.none.fl_str_mv Castillo, Oscar
Delgado, Esther
Gómez-García, Carlos J.
Hernández, Diego
Hernández, Elisa
Martín, Avelino
Martínez, José I.
Zamora Abanades, Félix Juan
author Castillo, Oscar
author_facet Castillo, Oscar
Delgado, Esther
Gómez-García, Carlos J.
Hernández, Diego
Hernández, Elisa
Martín, Avelino
Martínez, José I.
Zamora Abanades, Félix Juan
author_role author
author2 Delgado, Esther
Gómez-García, Carlos J.
Hernández, Diego
Hernández, Elisa
Martín, Avelino
Martínez, José I.
Zamora Abanades, Félix Juan
author2_role author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Departamento de Química Inorgánica
Facultad de Ciencias
dc.subject.none.fl_str_mv Coordination polymers
Metal-dithiolene polymers
Coordination compounds
First-principles calculations
Química
topic Coordination polymers
Metal-dithiolene polymers
Coordination compounds
First-principles calculations
Química
description This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.7b01775
publishDate 2017
dc.date.none.fl_str_mv 2017
2017-10-02
dc.type.none.fl_str_mv research article
http://purl.org/coar/resource_type/c_2df8fbb1
AM
http://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10486/688871
https://dx.doi.org/10.1021/acs.inorgchem.7b01775
url http://hdl.handle.net/10486/688871
https://dx.doi.org/10.1021/acs.inorgchem.7b01775
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:Biblos-e Archivo. Repositorio Institucional de la UAM
instname:Universidad Autónoma de Madrid
instname_str Universidad Autónoma de Madrid
reponame_str Biblos-e Archivo. Repositorio Institucional de la UAM
collection Biblos-e Archivo. Repositorio Institucional de la UAM
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,300719

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