Upgrading of biomass-derived solar hydrothermal bio-oils through catalytic hydrodeoxygenation in supercritical ethanol

5 figures, 3 tables.

Detalles Bibliográficos
Autores: Ayala Cortés, Alejandro, Torres Gamarra, Daniel, Frecha, Esther, Arcelus-Arrillaga, Pedro, Villafán, Heidi Isabel, Longoria, Adriana, Pinilla Ibarz, José Luis, Suelves Laiglesia, Isabel
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2023
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/347438
Acceso en línea:http://hdl.handle.net/10261/347438
Access Level:acceso abierto
Palabra clave:Catalytic hydrodeoxygenation
Bio-oil upgrading
Supercritical ethanol
Solar hydrothermal processing
http://metadata.un.org/sdg/7
http://metadata.un.org/sdg/12
Ensure access to affordable, reliable, sustainable and modern energy for all
Ensure sustainable consumption and production patterns
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oai_identifier_str oai:digital.csic.es:10261/347438
network_acronym_str ES
network_name_str España
repository_id_str
dc.title.none.fl_str_mv Upgrading of biomass-derived solar hydrothermal bio-oils through catalytic hydrodeoxygenation in supercritical ethanol
title Upgrading of biomass-derived solar hydrothermal bio-oils through catalytic hydrodeoxygenation in supercritical ethanol
spellingShingle Upgrading of biomass-derived solar hydrothermal bio-oils through catalytic hydrodeoxygenation in supercritical ethanol
Ayala Cortés, Alejandro
Catalytic hydrodeoxygenation
Bio-oil upgrading
Supercritical ethanol
Solar hydrothermal processing
http://metadata.un.org/sdg/7
http://metadata.un.org/sdg/12
Ensure access to affordable, reliable, sustainable and modern energy for all
Ensure sustainable consumption and production patterns
title_short Upgrading of biomass-derived solar hydrothermal bio-oils through catalytic hydrodeoxygenation in supercritical ethanol
title_full Upgrading of biomass-derived solar hydrothermal bio-oils through catalytic hydrodeoxygenation in supercritical ethanol
title_fullStr Upgrading of biomass-derived solar hydrothermal bio-oils through catalytic hydrodeoxygenation in supercritical ethanol
title_full_unstemmed Upgrading of biomass-derived solar hydrothermal bio-oils through catalytic hydrodeoxygenation in supercritical ethanol
title_sort Upgrading of biomass-derived solar hydrothermal bio-oils through catalytic hydrodeoxygenation in supercritical ethanol
dc.creator.none.fl_str_mv Ayala Cortés, Alejandro
Torres Gamarra, Daniel
Frecha, Esther
Arcelus-Arrillaga, Pedro
Villafán, Heidi Isabel
Longoria, Adriana
Pinilla Ibarz, José Luis
Suelves Laiglesia, Isabel
author Ayala Cortés, Alejandro
author_facet Ayala Cortés, Alejandro
Torres Gamarra, Daniel
Frecha, Esther
Arcelus-Arrillaga, Pedro
Villafán, Heidi Isabel
Longoria, Adriana
Pinilla Ibarz, José Luis
Suelves Laiglesia, Isabel
author_role author
author2 Torres Gamarra, Daniel
Frecha, Esther
Arcelus-Arrillaga, Pedro
Villafán, Heidi Isabel
Longoria, Adriana
Pinilla Ibarz, José Luis
Suelves Laiglesia, Isabel
author2_role author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Ministerio de Ciencia e Innovación (España)
European Commission
Agencia Estatal de Investigación (España)
Universidad Nacional Autónoma de México
Consejo Nacional de Ciencia y Tecnología (México)
Secretaría de Energía (México)
Centro Mexicano de Innovación en Energía Solar
CSIC - Plataforma Temática Interdisciplinar del CSIC Transición energética (PTI TransEner +)
Ayala Cortés, Alejandro [0000-0003-3933-5820]
Torres Gamarra, Daniel [0000-0002-7843-6141]
Arcelus-Arrillaga, Pedro [0000-0003-3890-0154]
Villafán, Heidi Isabel [0000-0002-0798-1361]
Longoria, Adriana [0000-0002-9879-0885]
Pinilla Ibarz, José Luis [0000-0002-8304-9656]
Suelves Laiglesia, Isabel [0000-0001-8437-2204]
Pinilla Ibarz, José Luis [jlpinilla@icb.csic.es]
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Catalytic hydrodeoxygenation
Bio-oil upgrading
Supercritical ethanol
Solar hydrothermal processing
http://metadata.un.org/sdg/7
http://metadata.un.org/sdg/12
Ensure access to affordable, reliable, sustainable and modern energy for all
Ensure sustainable consumption and production patterns
topic Catalytic hydrodeoxygenation
Bio-oil upgrading
Supercritical ethanol
Solar hydrothermal processing
http://metadata.un.org/sdg/7
http://metadata.un.org/sdg/12
Ensure access to affordable, reliable, sustainable and modern energy for all
Ensure sustainable consumption and production patterns
description 5 figures, 3 tables.
publishDate 2023
dc.date.none.fl_str_mv 2023
2024
2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Postprint
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/347438
url http://hdl.handle.net/10261/347438
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-115053RB-I00
Ayala Cortés, Alejandro; Torres Gamarra, Daniel; Frecha, Esther; Arcelus Arrillaga, Pedro; Villafán, Heidi Isabel; Longoria, Adriana; Pinilla Ibarz, José Luis; Suelves Laiglesia, Isabel; 2023; Supplementary material for Upgrading of biomass-derived solar hydrothermal bio-oils through catalytic hydrodeoxygenation in supercritical ethanol [Dataset]; Elsevier; http://dx.doi.org/10.1016/j.jece.2023.111395
http://dx.doi.org/10.1016/j.jece.2023.111395
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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spelling Upgrading of biomass-derived solar hydrothermal bio-oils through catalytic hydrodeoxygenation in supercritical ethanolAyala Cortés, AlejandroTorres Gamarra, DanielFrecha, EstherArcelus-Arrillaga, PedroVillafán, Heidi IsabelLongoria, AdrianaPinilla Ibarz, José LuisSuelves Laiglesia, IsabelCatalytic hydrodeoxygenationBio-oil upgradingSupercritical ethanolSolar hydrothermal processinghttp://metadata.un.org/sdg/7http://metadata.un.org/sdg/12Ensure access to affordable, reliable, sustainable and modern energy for allEnsure sustainable consumption and production patterns5 figures, 3 tables.The use of concentrated solar energy as the heat source to perform hydrothermal liquefaction (HTL) of biomass is a promising alternative to improve the thermal efficiency of the process and reduce the environmental impact of the use of fossil fuels. However, the HTL of lignocellulosic biomass produces a bio-oil that still requires an upgrading treatment to improve its properties as fuel. In the present work, bio-oils obtained from solar hydrothermal liquefaction of Agave and corncob were upgraded for the first time by hydrodeoxygenation (HDO) in supercritical ethanol using a Mo2C catalyst supported in carbon nanofibers. The main results showed yields up to 69% of the upgraded bio-oil and a deoxygenation grade of 71%, with HHV values around 35 MJ/kg for most of the upgraded bio-oils. Moreover, it was observed that HDO treatment of the solar bio-oils can produce upgraded bio-oils with chemical properties and yields similar to those produced by conventional thermochemical methods, which opens the door to extend the use of concentrated solar technologies for the whole process: from biomass thermochemical conversion to its upgrading into drop-in fuels.This study was supported by MCIN with funding from European Union NextGenerationEU (PRTR-C17. I1) within the Green Hydrogen and Energy Program- CSIC, as part of the CSIC Interdisciplinary Thematic Platform (PTI+) Transición Energética Sostenible+(PTI-TRANSENER+), and the financial support of the I+D+i project PID2020–115053RB-I00, funded by MCIN/ AEI/10.13039/501100011033. Authors also acknowledge the financial support of DGAPA-PAPIIT UNAM through grant IN107923 “Licuefacción hidrotérmica de biomasa residual” and Fondo Sectorial CONACYT-SENER-Sustentabilidad Energética through Grant 207450 and Centro Mexicano de Innovación en Energía Solar (CeMIE-Sol), within strategic project No. 120. DT is grateful for the Juan de la Cierva Incorporación (JdC-I) fellowship (Grant Number: IJC2020–045553-I) funded by MCIN/AEI/ 10.13039/501100011033 and by “European Union NextGenerationEU/PRTR”.Peer reviewedElsevierMinisterio de Ciencia e Innovación (España)European CommissionAgencia Estatal de Investigación (España)Universidad Nacional Autónoma de MéxicoConsejo Nacional de Ciencia y Tecnología (México)Secretaría de Energía (México)Centro Mexicano de Innovación en Energía SolarCSIC - Plataforma Temática Interdisciplinar del CSIC Transición energética (PTI TransEner +)Ayala Cortés, Alejandro [0000-0003-3933-5820]Torres Gamarra, Daniel [0000-0002-7843-6141]Arcelus-Arrillaga, Pedro [0000-0003-3890-0154]Villafán, Heidi Isabel [0000-0002-0798-1361]Longoria, Adriana [0000-0002-9879-0885]Pinilla Ibarz, José Luis [0000-0002-8304-9656]Suelves Laiglesia, Isabel [0000-0001-8437-2204]Pinilla Ibarz, José Luis [jlpinilla@icb.csic.es]Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202420242023info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Postprintinfo:eu-repo/semantics/acceptedVersionapplication/pdfhttp://hdl.handle.net/10261/347438reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-115053RB-I00Ayala Cortés, Alejandro; Torres Gamarra, Daniel; Frecha, Esther; Arcelus Arrillaga, Pedro; Villafán, Heidi Isabel; Longoria, Adriana; Pinilla Ibarz, José Luis; Suelves Laiglesia, Isabel; 2023; Supplementary material for Upgrading of biomass-derived solar hydrothermal bio-oils through catalytic hydrodeoxygenation in supercritical ethanol [Dataset]; Elsevier; http://dx.doi.org/10.1016/j.jece.2023.111395http://dx.doi.org/10.1016/j.jece.2023.111395Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3474382026-05-22T06:33:51Z
score 15,81155

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