Microbial mediation and climatic control on dolomiteprecipitation in a hypersaline lake: Insights from SalinasLake, southern Iberia

This study examines the climatic controls on dolomite precipitation through a multiproxy investigation of a carbonate-rich sediment core from Salinas Lake, a hypersaline playa in Alicante, south-eastern Iberia. The ~120,000 year record captures depositional cycles and palaeoenvironmental changes dri...

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Autores: Li, Guolai, Naim, Zeina, Gibert Beotas, Lluís, Stuut, Jan-Berend, Waajen, Annemiek C., Jimenez-Moreno, Gonzalo, Sánchez-Román, Mónica
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2025
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2445/226526
Acceso en línea:https://hdl.handle.net/2445/226526
Access Level:acceso abierto
Palabra clave:Dolomia
Sedimentologia
Sediments lacustres
Paleoclimatologia
Geoquímica
Geomicrobiologia
Dolomite
Sedimentology
Lake sediments
Paleoclimatology
Geochemistry
Geomicrobiology
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spelling Microbial mediation and climatic control on dolomiteprecipitation in a hypersaline lake: Insights from SalinasLake, southern IberiaLi, GuolaiNaim, ZeinaGibert Beotas, LluísStuut, Jan-BerendWaajen, Annemiek C.Jimenez-Moreno, GonzaloSánchez-Román, MónicaDolomiaSedimentologiaSediments lacustresPaleoclimatologiaGeoquímicaGeomicrobiologiaDolomiteSedimentologyLake sedimentsPaleoclimatologyGeochemistryGeomicrobiologyThis study examines the climatic controls on dolomite precipitation through a multiproxy investigation of a carbonate-rich sediment core from Salinas Lake, a hypersaline playa in Alicante, south-eastern Iberia. The ~120,000 year record captures depositional cycles and palaeoenvironmental changes driven by late Pleistocene to Holocene climate variability. Integrated analyses of sedimentology, lithology, geochemistry (elemental concentrations, total organic carbon, stable carbon and oxygen isotopes), scanning electron microscopy, microbial community characterisation and palynology reconstruct lake hydrology and its influence on carbonate mineralogy. The sediment succession is marked by alternating calcite- and dolomite-rich intervals, with dolomite crystals displaying morphological evolution from spherical to rhombohedral forms with depth. Stable isotope signatures (δ13C: −6.5‰ to −2.4‰ VPDB; δ18O: −2.3‰ to +4.9‰ VPDB), alongside microbial structures such as extracellular polymeric substances (EPS) and internal crystal voids, suggest a biologically mediated precipitation mechanism. These mineralogical shifts closely correspond to rapid hydrological changes driven by Dansgaard–Oeschger climate oscillations, with dolomite formation favoured under arid, evaporative conditions that concentrate Mg and Ca ions and promote microbial mat development. Halophilic microbial communities, capable of catalysing carbonate precipitation, probably enhance dolomite nucleation and growth through EPS production and geochemical modulation. This work underscores the complex interplay between climate, hydrology, microbial activity and sedimentary mineral formation, providing new insights into the longstanding ‘dolomite problem’ within sedimentary environments.John Wiley & Sons2026202620252026info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersion20 p.application/pdfhttps://hdl.handle.net/2445/226526Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)InglésReproducció del document publicat a: https://doi.org/10.1002/dep2.70058The Depositional Record, 2025, vol. 12, num.1https://doi.org/10.1002/dep2.70058cc-by (c) Guolai Li et al., 2025http://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessoai:recercat.cat:2445/2265262026-05-29T05:05:01Z
dc.title.none.fl_str_mv Microbial mediation and climatic control on dolomiteprecipitation in a hypersaline lake: Insights from SalinasLake, southern Iberia
title Microbial mediation and climatic control on dolomiteprecipitation in a hypersaline lake: Insights from SalinasLake, southern Iberia
spellingShingle Microbial mediation and climatic control on dolomiteprecipitation in a hypersaline lake: Insights from SalinasLake, southern Iberia
Li, Guolai
Dolomia
Sedimentologia
Sediments lacustres
Paleoclimatologia
Geoquímica
Geomicrobiologia
Dolomite
Sedimentology
Lake sediments
Paleoclimatology
Geochemistry
Geomicrobiology
title_short Microbial mediation and climatic control on dolomiteprecipitation in a hypersaline lake: Insights from SalinasLake, southern Iberia
title_full Microbial mediation and climatic control on dolomiteprecipitation in a hypersaline lake: Insights from SalinasLake, southern Iberia
title_fullStr Microbial mediation and climatic control on dolomiteprecipitation in a hypersaline lake: Insights from SalinasLake, southern Iberia
title_full_unstemmed Microbial mediation and climatic control on dolomiteprecipitation in a hypersaline lake: Insights from SalinasLake, southern Iberia
title_sort Microbial mediation and climatic control on dolomiteprecipitation in a hypersaline lake: Insights from SalinasLake, southern Iberia
dc.creator.none.fl_str_mv Li, Guolai
Naim, Zeina
Gibert Beotas, Lluís
Stuut, Jan-Berend
Waajen, Annemiek C.
Jimenez-Moreno, Gonzalo
Sánchez-Román, Mónica
author Li, Guolai
author_facet Li, Guolai
Naim, Zeina
Gibert Beotas, Lluís
Stuut, Jan-Berend
Waajen, Annemiek C.
Jimenez-Moreno, Gonzalo
Sánchez-Román, Mónica
author_role author
author2 Naim, Zeina
Gibert Beotas, Lluís
Stuut, Jan-Berend
Waajen, Annemiek C.
Jimenez-Moreno, Gonzalo
Sánchez-Román, Mónica
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Dolomia
Sedimentologia
Sediments lacustres
Paleoclimatologia
Geoquímica
Geomicrobiologia
Dolomite
Sedimentology
Lake sediments
Paleoclimatology
Geochemistry
Geomicrobiology
topic Dolomia
Sedimentologia
Sediments lacustres
Paleoclimatologia
Geoquímica
Geomicrobiologia
Dolomite
Sedimentology
Lake sediments
Paleoclimatology
Geochemistry
Geomicrobiology
description This study examines the climatic controls on dolomite precipitation through a multiproxy investigation of a carbonate-rich sediment core from Salinas Lake, a hypersaline playa in Alicante, south-eastern Iberia. The ~120,000 year record captures depositional cycles and palaeoenvironmental changes driven by late Pleistocene to Holocene climate variability. Integrated analyses of sedimentology, lithology, geochemistry (elemental concentrations, total organic carbon, stable carbon and oxygen isotopes), scanning electron microscopy, microbial community characterisation and palynology reconstruct lake hydrology and its influence on carbonate mineralogy. The sediment succession is marked by alternating calcite- and dolomite-rich intervals, with dolomite crystals displaying morphological evolution from spherical to rhombohedral forms with depth. Stable isotope signatures (δ13C: −6.5‰ to −2.4‰ VPDB; δ18O: −2.3‰ to +4.9‰ VPDB), alongside microbial structures such as extracellular polymeric substances (EPS) and internal crystal voids, suggest a biologically mediated precipitation mechanism. These mineralogical shifts closely correspond to rapid hydrological changes driven by Dansgaard–Oeschger climate oscillations, with dolomite formation favoured under arid, evaporative conditions that concentrate Mg and Ca ions and promote microbial mat development. Halophilic microbial communities, capable of catalysing carbonate precipitation, probably enhance dolomite nucleation and growth through EPS production and geochemical modulation. This work underscores the complex interplay between climate, hydrology, microbial activity and sedimentary mineral formation, providing new insights into the longstanding ‘dolomite problem’ within sedimentary environments.
publishDate 2025
dc.date.none.fl_str_mv 2025
2026
2026
2026
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/2445/226526
url https://hdl.handle.net/2445/226526
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Reproducció del document publicat a: https://doi.org/10.1002/dep2.70058
The Depositional Record, 2025, vol. 12, num.1
https://doi.org/10.1002/dep2.70058
dc.rights.none.fl_str_mv cc-by (c) Guolai Li et al., 2025
http://creativecommons.org/licenses/by/4.0/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv cc-by (c) Guolai Li et al., 2025
http://creativecommons.org/licenses/by/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 20 p.
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons
publisher.none.fl_str_mv John Wiley & Sons
dc.source.none.fl_str_mv Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
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