Further development of polyepichlorohydrin based anion exchange membranes for reverse electrodialysis by tuning cast solution properties
Recently, there have been several studies done regarding anion exchange membranes (AEMs) based on polyepichlorohydrin (PECH), an attractive polymer enabling safe membrane fabrication due to its inherent chloromethyl groups. However, there are still undiscovered properties of these membranes emerging...
| Autores: | , , , , , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2022 |
| País: | España |
| Institución: | Universidad de Cantabria (UC) |
| Repositorio: | UCrea Repositorio Abierto de la Universidad de Cantabria |
| Idioma: | inglés |
| OAI Identifier: | oai:repositorio.unican.es:10902/27113 |
| Acceso en línea: | https://hdl.handle.net/10902/27113 |
| Access Level: | acceso abierto |
| Palabra clave: | Salinity gradient Blue energy Reverse electrodialysis Anion exchange membrane Polyepichlorohydrin |
| Sumario: | Recently, there have been several studies done regarding anion exchange membranes (AEMs) based on polyepichlorohydrin (PECH), an attractive polymer enabling safe membrane fabrication due to its inherent chloromethyl groups. However, there are still undiscovered properties of these membranes emerging from different compositions of cast solutions. Thus, it is vital to explore new membrane properties for sustainable energy generation by reverse electrodialysis (RED). In this study, the cast solution composition was easily tuned by varying the ratio of active polymer (i.e., blend ratio) and quaternary agent (i.e., excess diamine ratio) in the range of 1.07–2.00, and 1.00–4.00, respectively. The membrane synthesized with excess diamine ratio of 4.00 and blend ratio of 1.07 provided the best results in terms of ion exchange capacity, 3.47 mmol/g, with satisfactory conductive properties (area resistance: 2.4 Ω·cm2, electrical conductivity: 6.44 mS/cm) and high hydrophilicity. RED tests were performed by AEMs coupled with the commercially available Neosepta CMX cation exchange membrane (CEMs). |
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