Spectroscopically Characterized Synthetic Mononuclear Nickel–Oxygen Species

KGaA, WeinheimIron, copper, and manganese are the predominant metals found in oxygenases that perform efficient and selective hydrocarbon oxidations and for this reason, a large number of the corresponding metal–oxygen species has been described. However, in recent years nickel has been found in the...

ver descrição completa

Detalhes bibliográficos
Autores: Corona Prieto, Teresa, Company Casadevall, Anna
Tipo de documento: artigo
Estado:Versão publicada
Data de publicação:2016
País:España
Recursos:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositório:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:10256/13281
Acesso em linha:http://hdl.handle.net/10256/13281
Access Level:Acesso embargado
Palavra-chave:Catàlisi
Catalysis
Reaccions químiques
Chemical reactions
Níquel -- Oxidació
Nickel -- Oxidation
id ES_b74edaa05695d5c8a3bc55c60375bedf
oai_identifier_str oai:recercat.cat:10256/13281
network_acronym_str ES
network_name_str España
repository_id_str
spelling Spectroscopically Characterized Synthetic Mononuclear Nickel–Oxygen SpeciesCorona Prieto, TeresaCompany Casadevall, AnnaCatàlisiCatalysisReaccions químiquesChemical reactionsNíquel -- OxidacióNickel -- OxidationKGaA, WeinheimIron, copper, and manganese are the predominant metals found in oxygenases that perform efficient and selective hydrocarbon oxidations and for this reason, a large number of the corresponding metal–oxygen species has been described. However, in recent years nickel has been found in the active site of enzymes involved in oxidation processes, in which nickel–dioxygen species are proposed to play a key role. Owing to this biological relevance and to the existence of different catalytic protocols that involve the use of nickel catalysts in oxidation reactions, there is a growing interest in the detection and characterization of nickel–oxygen species relevant to these processes. In this Minireview the spectroscopically/structurally characterized synthetic superoxo, peroxo, and oxonickel species that have been reported to date are described. From these studies it becomes clear that nickel is a very promising metal in the field of oxidation chemistry with still unexplored possibilitiesThe authors acknowledge financial support from the European Commission (2011-CIG-303522 to A.C.) and the MINECO of Spain (“Ramón y Cajal” contract and CTQ2013-43012-P to A.C.).WileyMinisterio de Economía y Competitividad (Espanya)infoinfo2016info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://hdl.handle.net/10256/13281http://hdl.handle.net/10256/13281© Chemistry - A European Journal, 2016, vol. 22, núm. 38, p. 13422-13429Articles publicats (D-Q)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)Inglésinfo:eu-repo/semantics/altIdentifier/doi/10.1002/chem.201602414info:eu-repo/semantics/altIdentifier/issn/0947-6539info:eu-repo/semantics/altIdentifier/eissn/1521-3765info:eu-repo/grantAgreement/MINECO//CTQ2013-43012-Pinfo:eu-repo/grantAgreement/EC/FP7/303522Tots els drets reservatsinfo:eu-repo/semantics/embargoedAccessoai:recercat.cat:10256/132812026-05-29T05:05:01Z
dc.title.none.fl_str_mv Spectroscopically Characterized Synthetic Mononuclear Nickel–Oxygen Species
title Spectroscopically Characterized Synthetic Mononuclear Nickel–Oxygen Species
spellingShingle Spectroscopically Characterized Synthetic Mononuclear Nickel–Oxygen Species
Corona Prieto, Teresa
Catàlisi
Catalysis
Reaccions químiques
Chemical reactions
Níquel -- Oxidació
Nickel -- Oxidation
title_short Spectroscopically Characterized Synthetic Mononuclear Nickel–Oxygen Species
title_full Spectroscopically Characterized Synthetic Mononuclear Nickel–Oxygen Species
title_fullStr Spectroscopically Characterized Synthetic Mononuclear Nickel–Oxygen Species
title_full_unstemmed Spectroscopically Characterized Synthetic Mononuclear Nickel–Oxygen Species
title_sort Spectroscopically Characterized Synthetic Mononuclear Nickel–Oxygen Species
dc.creator.none.fl_str_mv Corona Prieto, Teresa
Company Casadevall, Anna
author Corona Prieto, Teresa
author_facet Corona Prieto, Teresa
Company Casadevall, Anna
author_role author
author2 Company Casadevall, Anna
author2_role author
dc.contributor.none.fl_str_mv Ministerio de Economía y Competitividad (Espanya)
dc.subject.none.fl_str_mv Catàlisi
Catalysis
Reaccions químiques
Chemical reactions
Níquel -- Oxidació
Nickel -- Oxidation
topic Catàlisi
Catalysis
Reaccions químiques
Chemical reactions
Níquel -- Oxidació
Nickel -- Oxidation
description KGaA, WeinheimIron, copper, and manganese are the predominant metals found in oxygenases that perform efficient and selective hydrocarbon oxidations and for this reason, a large number of the corresponding metal–oxygen species has been described. However, in recent years nickel has been found in the active site of enzymes involved in oxidation processes, in which nickel–dioxygen species are proposed to play a key role. Owing to this biological relevance and to the existence of different catalytic protocols that involve the use of nickel catalysts in oxidation reactions, there is a growing interest in the detection and characterization of nickel–oxygen species relevant to these processes. In this Minireview the spectroscopically/structurally characterized synthetic superoxo, peroxo, and oxonickel species that have been reported to date are described. From these studies it becomes clear that nickel is a very promising metal in the field of oxidation chemistry with still unexplored possibilities
publishDate 2016
dc.date.none.fl_str_mv 2016
info
info
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10256/13281
http://hdl.handle.net/10256/13281
url http://hdl.handle.net/10256/13281
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/chem.201602414
info:eu-repo/semantics/altIdentifier/issn/0947-6539
info:eu-repo/semantics/altIdentifier/eissn/1521-3765
info:eu-repo/grantAgreement/MINECO//CTQ2013-43012-P
info:eu-repo/grantAgreement/EC/FP7/303522
dc.rights.none.fl_str_mv Tots els drets reservats
info:eu-repo/semantics/embargoedAccess
rights_invalid_str_mv Tots els drets reservats
eu_rights_str_mv embargoedAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv © Chemistry - A European Journal, 2016, vol. 22, núm. 38, p. 13422-13429
Articles publicats (D-Q)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869417518662156288
score 15,812429

Registros relacionados